Citation: Mengxiao Zhang, Cuican Li, Weiming Hua, Yinghong Yue, Zi Gao. Preparation and catalytic performance of perfluorosulfonic acid-functionalized carbon nanotubes[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1874-1882. doi: 10.1016/S1872-2067(14)60167-4 shu

Preparation and catalytic performance of perfluorosulfonic acid-functionalized carbon nanotubes

1.
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Fudan University, Shanghai 200433, China

Corresponding author: Yinghong Yue,
Received Date: 3 May 2014
Available Online: 10 June 2014
Fund Project: 国家自然科学基金(20773027,20773028和21273043) (20773027,20773028和21273043)上海市科学技术委员会(08DZ2270500). (08DZ2270500)

Perfluorosulfonic acid-functionalized carbon nanotubes were prepared by liquid deposition of the perfluorosulfonic acid-polytetrafluoroethylene copolymer and characterized by N₂ adsorption, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, and acid-base titration. The effects of reaction temperature and the type of solvent were investigated. The results showed that these solid acids are very stable in both polar and non-polar solvents and can maintain their acidity up to 300 ℃. Higher activity and better stability were observed over these materials in the alkylation of hydroquinone compared with poly(styrene sulfonic acid)-grafted carbon nanotubes.
- Carbon nanotube,
- Perfluorosulfonic acid,
- Acidity,
- Stability,
- Hydroquinone alkylation,
- tert-butanol,
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沈阳化工大学材料科学与工程学院沈阳 110142