Citation: Tao Zhang, . Rh(Ⅲ)-catalyzed synthesis of (dihydro)quinolines via the annulation of N-sulfonyl 2-aminobenzaldehydes with olefins[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1840-1845. doi: 10.1016/S1872-2067(14)60160-1 shu

Rh(Ⅲ)-catalyzed synthesis of (dihydro)quinolines via the annulation of N-sulfonyl 2-aminobenzaldehydes with olefins

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Tao Zhang ^b,c ,
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1.
a Chemical Synthesis and pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637009, Sichuan, China;

Corresponding author: , ,
Received Date: 28 April 2014
Available Online: 23 May 2014
Fund Project: 国家自然科学基金(21272231). (21272231)

We developed a new synthetic method for the production of 1,2-dihydroquinolines and quinolines via the Rh(Ⅲ)-catalyzed annulation of N-sulfonyl 2-aminobenzaldehydes with olefins. Various functionalities were found to be compatible under the operationally simple conditions. This study provides the first example of a Rh(Ⅲ)-catalyzed synthesis of 1,2-dihydroquinolines.
- Rhodium(Ⅲ),
- N-sulfonyl 2-aminobenzaldehyde,
- Olefin,
- Quinoline
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