Citation: Lifeng Chen, Weilin Song, Yahong Zhang, Weimin Yang, Lianghua Wu, Yi Tang. Nanowire accumulated Fe₂O₃/SiO₂ spherical catalyst for Fischer-Tropsch synthesis[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1661-1668. doi: 10.1016/S1872-2067(14)60135-2 shu

Nanowire accumulated Fe₂O₃/SiO₂ spherical catalyst for Fischer-Tropsch synthesis

Lifeng Chen ^a ,
Weilin Song ^a,b ,
Yahong Zhang ^a ,
Weimin Yang ^b ,
Lianghua Wu ^b ,
Yi Tang ^a,,

1.
a Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis, Fudan University, Shanghai 200433, China;

Corresponding author: Yi Tang,
Received Date: 17 March 2014
Available Online: 8 April 2014
Fund Project:

A catalyst consisting of SiO₂ nanowires and highly dispersed Fe₂O₃ (denoted NW-FS) was synthesized in situ by iron-assisted amine-vapor-transport treatment. NW-FS was prepared by the direct transformation of an industrial spherical Fe₂O₃/SiO₂ catalyst (denoted indus-FS). NW-FS was characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, N₂-sorption measurements, X-ray photoelectron spectroscopy, and temperature-programmed reduction. NW-FS exhibited a high selectivity for light olefins, especially for ethene in the Fischer-Tropsch synthesis. This was because of the highly dispersed Fe₂O₃ and low diffusion resistance of its open structure. The C₂-C₄ olefin/paraffin ratio was 3.3, which was higher than that of indus-FS at 1.9.
- Nanowire,
- Nanometal catalyst,
- Fischer-Tropsch synthesis,
- Coal chemistry,
- Secondary reaction
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沈阳化工大学材料科学与工程学院沈阳 110142

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Nanowire accumulated Fe₂O₃/SiO₂ spherical catalyst for Fischer-Tropsch synthesis