Citation: Fanlu Meng, Lin Li, Zhong Wu, Haixia Zhong, Jianchen Li, Junmin Yan. Facile preparation of N-doped carbon nanofiber aerogels from bacterial cellulose as an efficient oxygen reduction reaction electrocatalyst[J]. Chinese Journal of Catalysis, ;2014, 35(6): 877-883. doi: 10.1016/S1872-2067(14)60126-1 shu

Facile preparation of N-doped carbon nanofiber aerogels from bacterial cellulose as an efficient oxygen reduction reaction electrocatalyst

Fanlu Meng ^a,b ,
Lin Li ^a,b ,
Zhong Wu ^b,c ,
Haixia Zhong ^b,c ,
Jianchen Li ^a ,
Junmin Yan ^a,,

1.
a Key Laboratory of Automobile Materials, Ministry of Education, and College of Materials Science and Engineering, Jilin University, Changchun 130012, Jilin, China;

Corresponding author: Junmin Yan,
Received Date: 31 March 2014
Available Online: 28 April 2014
Fund Project: 中国科学院“百人计划”；国家重点基础研究发展计划(973计划，2014CB932300，2012CB215500)；国家自然科学基金(20921002，21101147，21203176). (973计划，2014CB932300，2012CB215500)；国家自然科学基金(20921002，21101147，21203176)

Carbon aerogels have attracted considerable attention over the past few decades as promising materials for catalyst supports, electrodes for supercapacitors and lithium-ion batteries, and adsorbents. However, expensive and toxic precursors as well as complicated synthetic methods dramatically limit their large-scale production and application. In this work, we developed a facile and effective route to prepare a N-doped carbon nanofiber aerogel (N-CNFA) with low mass density, continuous porosity, high specific surface area, and electrical conductivity from a bacterial cellulose precursor. Because of the highly porous and interconnected 3D structure, the obtained N-doped carbon aerogel was used directly as a catalyst for the oxygen reduction reaction (ORR), and it exhibited superior catalytic activity. This activity was much higher than that obtained without N-doping, and it can potentially be applied to high-performance fuel cells.
- Carbon nanofiber aerogels,
- N-doped carbon,
- Oxygen reduction reaction,
- Bacterial cellulose
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