Citation: Anas Benyounes, Mohamed Kacimi, Mahfoud Ziyad, Philippe Serp. Conversion of isopropyl alcohol over Ru and Pd loaded N-doped carbon nanotubes[J]. Chinese Journal of Catalysis, ;2014, 35(6): 970-978. doi: 10.1016/S1872-2067(14)60121-2 shu

Conversion of isopropyl alcohol over Ru and Pd loaded N-doped carbon nanotubes

1.
a Laboratory of Coordination Chemistry UPR CNRS 8241, ENSIACET Group, Toulouse University, 4 allée Emile Monso-CS 44362, Toulouse Cedex 4, France;

Corresponding author: Mohamed Kacimi,
Received Date: 31 March 2014
Available Online: 25 April 2014

Ru and Pd (2 wt%) loaded on pure and on N-doped carbon nanotubes (N-CNTs) were prepared and tested using the isopropyl alcohol decomposition reaction as probe reaction. The presence of nitrogen functionalities (pyridinic, pyrrolic, and quaternary nitrogen) on the nitrogen doped support induced a higher metal dispersion: Pd/N-CNT (1.8 nm) < Pd/CNT (4.9 nm), and Ru/N-CNT (2.4 nm) < Ru/CNT (3.0 nm). The catalytic activity of the supports was determined first. Isopropyl alcohol conversion produces acetone on CNTs while on N-CNTs it led to both dehydration and dehydrogenation products. At 210℃ and in the presence of air, the isopropyl alcohol conversion was higher on the N-CNTs (25%) than on the CNTs (11%). The Pd loaded catalysts were more active and more selective than the Ru ones. At 115℃, the Pd catalysts were 100% selective towards acetone for a conversion of 100%, whereas the Ru catalysts led to dehydration and dehydrogenation products. The nitrogen doping induced the appearance of redox properties when oxygen is present in the reaction mixture.
- Ruthenium,
- Palladium,
- Nitrogen-doped carbon nanotubes,
- Isopropyl alcohol,
- Decomposition,
- Acetone
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