Citation: Jing Liu, anqi Wang, Huanwang Jing. TiO₂-based green heterogeneous catalysts for the cycloaddition of CO₂ to epoxides[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1669-1675. doi: 10.1016/S1872-2067(14)60110-8 shu

TiO₂-based green heterogeneous catalysts for the cycloaddition of CO₂ to epoxides

1.
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 73000, Gansu, China

Corresponding author: Huanwang Jing,
Received Date: 14 March 2014
Available Online: 9 April 2014
Fund Project:

TiO₂ doped with metal ions (M-TiO₂, M = Zn²⁺, Cu²⁺, CO²⁺, Mn²⁺, or Ni²⁺) was investigated as a heterogeneous catalyst for the coupling reaction of CO₂ and epoxides, using tetrabutylammonium iodide (TBAI) as a co-catalyst under solvent-free conditions. These compounds were found to exhibit high catalytic activities. The effects of reaction temperature, reaction time, and CO₂ pressure on the effectiveness of a Zn-TiO₂/TBAI catalyst system were also examined. Zn-TiO₂ represents a nontoxic, heterogeneous catalyst that can be reutilized up to five times without a significant loss of catalytic activity.
- Carbon dioxide,
- Epoxide,
- Cyclic carbonate,
- Heterogeneous catalyst,
- Doped titanium dioxide
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沈阳化工大学材料科学与工程学院沈阳 110142

TiO2-based green heterogeneous catalysts for the cycloaddition of CO2 to epoxides

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通讯作者: 陈斌, bchen63@163.com

TiO₂-based green heterogeneous catalysts for the cycloaddition of CO₂ to epoxides