Citation: Shoufeng Wang, Chengxia Miao, Wenfang Wang, Ziqiang Lei, Wei Sun. Hydration of terminal alkynes catalyzed by a water-soluble salen-Co(Ⅲ) complex[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1695-1700. doi: 10.1016/S1872-2067(14)60105-4 shu

Hydration of terminal alkynes catalyzed by a water-soluble salen-Co(Ⅲ) complex

1.
a Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China;

Corresponding author: Ziqiang Lei, Wei Sun,
Received Date: 20 March 2014
Available Online: 11 April 2014
Fund Project:

A water-soluble salen-Co(Ⅲ) complex was studied as catalyst for hydration of terminal alkynes to methyl ketones in the presence of H₂SO₄ as a co-catalyst. The products were obtained with excellent yields using relatively low catalyst loadings and a simple protocol. Notably, the products were easily separated from the catalyst after reaction by extraction, and the catalyst could be recovered and reused with only a slight loss of activity.
- Hydration,
- Alkynes,
- Water-solubility,
- Cobalt,
- Salen complex
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沈阳化工大学材料科学与工程学院沈阳 110142