Citation: Shuchang Wu, Guodong Wen, Bingwei Zhong, Bingsen Zhang, Xianmo Gu, Ning Wang, Dangsheng Su. Reduction of nitrobenzene catalyzed by carbon materials[J]. Chinese Journal of Catalysis, ;2014, 35(6): 914-921. doi: 10.1016/S1872-2067(14)60102-9 shu

Reduction of nitrobenzene catalyzed by carbon materials

1.
a Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, Liaoning, China;

Corresponding author: Dangsheng Su,
Received Date: 15 March 2014
Available Online: 27 March 2014
Fund Project: 国家重点基础研究发展计划(973计划，2011CBA00504)；国家自然科学基金(21133010，51221264，21261160487，21203215)；中国科学院战略先导项目(XDA09030103)；辽宁省博士启动基金(20121068). (973计划，2011CBA00504)；国家自然科学基金(21133010，51221264，21261160487，21203215)；中国科学院战略先导项目(XDA09030103)；辽宁省博士启动基金(20121068)

The reduction of nitrobenzene catalyzed by different carbon materials (mainly carbon nanotubes) was studied. TGA, TPD, TEM, N₂ adsorption-desorption, and Raman spectroscopy were used to show that it was oxygenated groups that gave catalytic activity, while the surface area, pore structure, morphology, structural defects and Fe impurities in the catalysts did not have a significant influence on the activity. The carbonyl group played an important role, but the carboxylic group and anhydride adversely affected the reaction. The conjugated π system, which was necessary for electron transfer and nitrobenzene adsorption, was another critical factor. The reaction proceeded through the direct route in which the intermediate nitrosobenzene was converted directly to aniline quickly.
- Carbon materials,
- Oxygenated groups,
- Active sites,
- Nitrobenzene,
- Reduction
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