Citation: Abdol R. Hajipour, Hirbod Karimi. Selective oxidation of alcohols over copper zirconium phosphate[J]. Chinese Journal of Catalysis, ;2014, 35(9): 1529-1533. doi: 10.1016/S1872-2067(14)60096-6 shu

Selective oxidation of alcohols over copper zirconium phosphate

Abdol R. Hajipour ^a,b,, ,
Hirbod Karimi ^a

1.
a Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran;

Corresponding author: Abdol R. Hajipour,
Received Date: 21 February 2014
Available Online: 31 March 2014
Fund Project:

The catalytic activity of copper zirconium phosphate (ZPCu) in the selective oxidation of alcohols to their corresponding ketones or aldehydes, using H₂O₂ as an oxidizing agent, was studied. The oxidation reaction was performed without any organic solvent, phase-transfer catalyst, or additive. Steric factors associated with the substrates influenced the reaction. The catalyst was characterized using X-ray diffraction, inductively coupled plasma atomic emission spectroscopy, energy-dispersive X-ray spectroscopy, and scanning electron microscopy. It was shown that the interlayer distance increased from 0.74 to 0.80 nm and the crystallinity was reduced after Cu²⁺ intercalation into the layers. This catalyst can be recovered and reused three times without significant loss of activity and selectivity.
- Copper zirconium phosphate,
- Selective oxidation,
- Solid catalyst,
- Alcohol
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沈阳化工大学材料科学与工程学院沈阳 110142