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Citation: Bumei Zheng, Yufeng Wan, Weiya Yang, Fengxiang Ling, Hong Xie, Xiangchen Fang, Hongchen Guo. Mechanism of seeding in hydrothermal synthesis of zeolite Beta with organic structure-directing agent-free gel[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1800-1810. doi: 10.1016/S1872-2067(14)60089-9 shu

Mechanism of seeding in hydrothermal synthesis of zeolite Beta with organic structure-directing agent-free gel

  • 1.

    a State Key Laboratory of Fine Chemicals, Department of Catalytical Chemistry and Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;

  • Corresponding author: Hongchen Guo, 
  • Received Date: 1 March 2014
    Available Online: 21 March 2014

  • The organic structure-directing agent-free synthesis of zeolite Beta was carried out using several zeolite Beta seeds that differed in SiO2/Al2O3 ratio and crystal size. The synthesis was studied using X-ray diffraction, X-ray fluorescence, scanning electron microscopy, transmission electron microscopy, ultraviolet-Raman spectroscopy, infrared spectroscopy, and N2 physisorption. Synthesis was successful using different zeolite Beta seeds including pure silica seeds. During the induction period, the seeds underwent dissolution. The SiO2/Al2O3 ratio and crystal size, pretreatment (calcination), and seed addition time had a significant influence on seed dissolution behavior, crystallization process, and product. Morphological studies revealed that the seed residues produced by dissolution (except for pure silica) resulted in the formation of "immobilized" surface nuclei, which allowed for the dense growth of fresh small zeolite Beta crystals. The dissolved small seed fragments yielded dispersed nuclei, which formed relatively scattered small zeolite Beta crystals thought to be the main nuclei source of the pure silica seed. It is suggested that the use of an appropriately high SiO2/Al2O3 ratio, small size, and precalcined zeolite Beta seed is helpful for the synthesis of highly crystalline and pure zeolite Beta from the organic structure-directing agent-free gel.
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