Citation: Robab Abbasi, Khalil Farhadi, Sepideh Banisaeid, Nader Nowroozi Pesyan, Arezu Jamali, Fatemeh Rahmani. Electrosynthesized polytyramine-copper oxalate nanocomposite on copper electrode for electrocatalytic oxidation of methanol in alkaline medium[J]. Chinese Journal of Catalysis, ;2014, 35(7): 1098-1104. doi: 10.1016/S1872-2067(14)60049-8 shu

Electrosynthesized polytyramine-copper oxalate nanocomposite on copper electrode for electrocatalytic oxidation of methanol in alkaline medium

1.
a. Department of Analytical Chemistry, Faculty of Chemistry, Urmia University, Urmia, Iran;

Corresponding author: Khalil Farhadi,
Received Date: 5 December 2013
Available Online: 26 January 2014

A polytyramine-copper oxalate nanocomposite modified copper (PTCOxNMC) electrode prepared by electropolymerization was examined for electrocatalytic activity towards the oxidation of methanol in alkaline solution using cyclic voltammetry and impedance spectroscopy. The prepared PTCOxNMC electrode showed a significantly high response for adsorbed methanol oxidation. The effects of various parameters such as potential scan rate and methanol concentration on the electrocatalytic oxidation at the surface of the PTCOxNMC electrode were investigated. Spectrometry techniques such as Fourier transform infrared spectroscopy and scanning electron microscopy were used to determine the surface physical characteristics of the modified electrode and revealed that the polytyramine-copper oxalate nanocomposite particles were highly dispersed on the surface of the copper electrode with a narrow size up to 40 nm. The very high current density obtained for the catalytic oxidation may have resulted from the high electrode surface area caused by modification with the poly-tyramine-copper oxalate nanocomposite.
- Polytyramine,
- Copper oxalate,
- Nanocomposite,
- Electropolymerization,
- Copper modified electrode,
- Electrocatalytic oxidation,
- Methanol
1. [1]
  [1] Yao S K, Feng L, Zhao X, Liu C P, Xing W. J Power Sources, 2012, 217: 280
2. [2]
  [2] Heli H, Jafarian M, Mahjani M G, Gobal F. Electrochim Acta, 2004, 49: 4999
3. [3]
  [3] Nonaka H, Matsumura Y. J Electroanal Chem, 2002, 520: 101
4. [4]
  [4] Zeng J H, Shu T, Liao S J, Liang Z X. Chin J Catal (曾建皇, 舒婷, 廖世军, 梁振兴. 催化学报), 2011, 32: 86
5. [5]
  [5] Chen Y G, Zhuang L, Lu J T. Chin J Catal (陈酉贵, 庄林, 陆君涛. 催化学报), 2007, 28: 870
6. [6]
  [6] Green C L, Kucernak A. J Phys Chem B, 2002, 106: 1036
7. [7]
  [7] Arico A S, Poltarzewski Z, Kim H, Morana A, Giordano N, Antonucci V. J Power Sources, 1995, 55: 159
8. [8]
  [8] Danaee I, Jafarian M, Mirzapoor A, Gobal F, Mahjani M G. Electrochim Acta, 2010, 55: 2093
9. [9]
  [9] Soszko M, Łukaszewski M, Mianowska Z, Czerwinski A. J Power Sources, 2011, 196: 3513
10. [10]
  [10] Cai S F, Wang D S, Niu Z Q, Li Y D. Chin J Catal (蔡双飞, 王定胜, 牛志强, 李亚栋. 催化学报), 2013, 34: 1964
11. [11]
  [11] Jafarian M, Mahjani M G, Heli H, Gobal F, Khajesharifi H, Hamedi M H. Electrochim Acta, 2003, 48: 3423
12. [12]
  [12] Golabi S M, Nozad A. Electroanalysis, 2003, 15: 278
13. [13]
  [13] Yin S B, Zhu Q Q, Qiang Y H, Luo L. Chin J Catal (尹诗斌, 朱强强, 强颖怀, 罗林. 催化学报), 2012, 33: 290
14. [14]
  [14] Karim-Nezhad G, Pashazadeh S, Pashazadeh A. Chin J Catal (催化学报), 2012, 33: 1809
15. [15]
  [15] Jones F E III, Milen S B, Gurau B, Smotkin E S, Stock S R, Lukehart C M. J Nanosci Nanotechnol, 2002, 2: 81
16. [16]
  [16] Luo J, Maye M M, Lou Y B, Han L, Hepel M, Zhong C J. Catal Today, 2002, 77: 127
17. [17]
  [17] Lu X F, Zhang W J, Wang C, Wen T C, Wei Y. Prog Polym Sci, 2011, 36: 671
18. [18]
  [18] Awasthi R, Singh R N. Int J Hydrogen Energy, 2012, 37: 2103
19. [19]
  [19] El-Shafei A A. J Electroanal Chem, 1999, 471: 89
20. [20]
  [20] Kim M S, Hwang T S, Kim K B. J Electrochem Soc, 1997, 144: 151
21. [21]
  [21] Ojani R, Raoof J B, Hosseini Zavvarmahalleh S R. Electrochim Acta, 2008, 53: 2402
22. [22]
  [22] Abdel Rahim M A, Abdel Hameed R M, Khalil M W. J Power Sources, 2004, 134: 160
23. [23]
  [23] Hosseini M G, Abdolmaleki M, Ashrafpoor S. Chin J Catal (催化学报), 2013, 34: 1712
24. [24]
  [24] Karim-Nezhad Gh, Zare Dizajdizi B, Seyed Dorraji P. Catal Commun, 2011, 12: 906
25. [25]
  [25] Ojani R, Raoof J B, Ahmady-Khanghah Y. Electrochim Acta, 2011, 56: 3380
26. [26]
  [26] Li Z, Meng F H, Ren J, Zheng H Y, Xie K C. Chin J Catal (李忠, 孟凡会, 任军, 郑华艳, 谢克昌. 催化学报), 2008, 29: 643
27. [27]
  [27] Hasanzadeh M, Karim-Nezhad G, Mahjani M G, Jafarian M, Shadjou N, Khalilzadeh B, Saghatforoush L A. Catal Commun, 2008, 10: 295
28. [28]
  [28] Nagy L, Nagy G, Hajos P. Sensor Actuat B, 2001, 76: 494
29. [29]
  [29] Paixão T R L C, Bertotti M. J Electroanal Chem, 2004, 571: 101
30. [30]
  [30] Cubeiro M L, Fierro J L G. Appl Catal A, 1998, 168: 307
31. [31]
  [31] Fleischmann M, Korinek K, Pletcher D. J Electroanal Chem Interfacial Electrochem, 1971, 31: 39
32. [32]
  [32] Iguchi K, Tachibana A. Appl Surf Sci, 2000, 159-160: 167
33. [33]
  [33] Karim-Nezhad Gh, Seyed Dorraji P. Electrochim Acta, 2010, 55: 3414
34. [34]
  [34] Jadhav R S, Hundiwale D G, Mahulikar P P. J Coat Technol Res, 2010, 7: 449
35. [35]
  [35] Duran B, Turhan M C, Bereket G, Sezai Sarac A. Electrochim Acta, 2009, 55: 104
36. [36]
  [36] Martins dos Santos L M, Lacroix J C, Chane-Ching K I, Adenier A, Abrantes L M, Lacaze P C. J Electroanal Chem, 2006, 587: 67
37. [37]
  [37] Camalet J L, Lacroix J C, Aeiyach S, Chane-Ching K, Lacaze P C. Synth Met, 1998, 93: 133
38. [38]
  [38] Herrasti P, del Rio A I, Recio J. Electrochim Acta, 2007, 52: 6496
39. [39]
  [39] Situmorang M, Gooding J J, Hibbert D B, Barnet D. Biosensors Bioelectron, 1998, 13: 953
40. [40]
  [40] Luo M Z, Baldwin R P. J Electroanal Chem, 1995, 387: 87
41. [41]
  [41] Marioli J M, Kuwana T. Electrochim Acta, 1992, 37: 1187
42. [42]
  [42] Wels B, Johnson D C. J Electrochem Soc, 1990, 137: 2785
43. [43]
  [43] Burke L D, O'Dwyer K J. Electrochim Acta, 1991, 36: 1937
44. [44]
  [44] Yoshizawa K, Kagawa Y. J Phys Chem A, 2000, 104: 9347
45. [45]
  [45] Roslonek G, Taraszewska J. J Electroanal Soc, 1992, 325: 285
46. [46]
  [46] Nozad Golikand A, Asgari M, Ghannadi Maragheh M, Shahrokhian S. J Electroanal Chem, 2006, 588: 155
47. [47]
  [47] Ureta-Zanartu M S, Alarcon A, Munoz G, Gutierrez C. Electrochim Acta, 2007, 52: 7857
48. [48]
  [48] Nicholson R S, Shain I. Anal Chem, 1964, 36: 706 Randles J E B. Discuss Faraday Soc, 1947: 11
1. [1]
  Ming Huang , Xiuju Cai , Yan Liu , Zhuofeng Ke . Base-controlled NHC-Ru-catalyzed transfer hydrogenation and α-methylation/transfer hydrogenation of ketones using methanol. Chinese Chemical Letters, 2024, 35(7): 109323-. doi: 10.1016/j.cclet.2023.109323
2. [2]
  Erzhuo Cheng , Yunyi Li , Wei Yuan , Wei Gong , Yanjun Cai , Yuan Gu , Yong Jiang , Yu Chen , Jingxi Zhang , Guangquan Mo , Bin Yang . Galvanostatic method assembled ZIFs nanostructure as novel nanozyme for the glucose oxidation and biosensing. Chinese Chemical Letters, 2024, 35(9): 109386-. doi: 10.1016/j.cclet.2023.109386
3. [3]
  Fereshte Hassanzadeh-Afruzi , Mina Azizi , Iman Zare , Ehsan Nazarzadeh Zare , Anwarul Hasan , Siavash Iravani , Pooyan Makvandi , Yi Xu . Advanced metal-organic frameworks-polymer platforms for accelerated dermal wound healing. Chinese Chemical Letters, 2024, 35(11): 109564-. doi: 10.1016/j.cclet.2024.109564
4. [4]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
5. [5]
  Shaonan Tian , Yu Zhang , Qing Zeng , Junyu Zhong , Hui Liu , Lin Xu , Jun Yang . Core-shell gold-copper nanoparticles: Evolution of copper shells on gold cores at different gold/copper precursor ratios. Chinese Journal of Structural Chemistry, 2023, 42(11): 100160-100160. doi: 10.1016/j.cjsc.2023.100160
6. [6]
  Guoliang Liu , Zhiqiang Liu , Anmin Zheng . Modulation of zeolite surface realizes dynamic copper species redispersion. Chinese Journal of Structural Chemistry, 2024, 43(6): 100308-100308. doi: 10.1016/j.cjsc.2024.100308
7. [7]
  Luyao Lu , Chen Zhu , Fei Li , Pu Wang , Xi Kang , Yong Pei , Manzhou Zhu . Ligand effects on geometric structures and catalytic activities of atomically precise copper nanoclusters. Chinese Journal of Structural Chemistry, 2024, 43(10): 100411-100411. doi: 10.1016/j.cjsc.2024.100411
8. [8]
  Husitu Lin , Shuangkun Zhang , Dianfa Zhao , Yongkang Wang , Wei Liu , Fan Yang , Jianjun Liu , Dongpeng Yan , Zhanpeng Wu . Flexible polyphosphazene nanocomposite films: Enhancing stability and luminescence of CsPbBr₃ perovskite nanocrystals. Chinese Chemical Letters, 2025, 36(4): 109795-. doi: 10.1016/j.cclet.2024.109795
9. [9]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176
10. [10]
  Yuchen Wang , Zhenhao Xu , Kai Yan . Rational design of metal-metal hydroxide interface for efficient electrocatalytic oxidation of biomass-derived platform molecules. Chinese Journal of Structural Chemistry, 2025, 44(1): 100418-100418. doi: 10.1016/j.cjsc.2024.100418
11. [11]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
12. [12]
  Hao Zhang , Haonan Qu , Ehsan Bahojb Noruzi , Haibing Li , Feng Liang . A nanocomposite film with layer-by-layer self-assembled gold nanospheres driven by cucurbit[7]uril for the selective transport of L-tryptophan and lysozyme. Chinese Chemical Letters, 2025, 36(1): 109731-. doi: 10.1016/j.cclet.2024.109731
13. [13]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
14. [14]
  Ting Hu , Yuxuan Guo , Yixuan Meng , Ze Zhang , Ji Yu , Jianxin Cai , Zhenyu Yang . Uniform lithium deposition induced by copper phthalocyanine additive for durable lithium anode in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108603-. doi: 10.1016/j.cclet.2023.108603
15. [15]
  Ruilong Geng , Lingzi Peng , Chang Guo . Dynamic kinetic stereodivergent transformations of propargylic ammonium salts via dual nickel and copper catalysis. Chinese Chemical Letters, 2024, 35(8): 109433-. doi: 10.1016/j.cclet.2023.109433
16. [16]
  Jing-Qi Tao , Shuai Liu , Tian-Yu Zhang , Hong Xin , Xu Yang , Xin-Hua Duan , Li-Na Guo . Photoinduced copper-catalyzed alkoxyl radical-triggered ring-expansion/aminocarbonylation cascade. Chinese Chemical Letters, 2024, 35(6): 109263-. doi: 10.1016/j.cclet.2023.109263
17. [17]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
18. [18]
  Ling Fang , Sha Wang , Shun Lu , Fengjun Yin , Yujie Dai , Lin Chang , Hong Liu . Efficient electroreduction of nitrate via enriched active phases on copper-cobalt oxides. Chinese Chemical Letters, 2024, 35(4): 108864-. doi: 10.1016/j.cclet.2023.108864
19. [19]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
20. [20]
  Xiaotao Jin , Yanlan Wang , Yingping Huang , Di Huang , Xiang Liu . Percarbonate activation catalyzed by nanoblocks of basic copper molybdate for antibiotics degradation: High performance, degradation pathways and mechanism. Chinese Chemical Letters, 2024, 35(10): 109499-. doi: 10.1016/j.cclet.2024.109499

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(343)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142