Citation: Tiago P. Braga, Regina C. R. Santos, Barbara M. C. Sales, Bruno R. da Silva, Antônio N. Pinheiro, Edson R. Leite, Antoninho Valentini. CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology[J]. Chinese Journal of Catalysis, ;2014, 35(4): 514-523. doi: 10.1016/S1872-2067(14)60018-8 shu

CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology

1.
a Department of Analytical Chemistry and Physical Chemistry, Federal University of Ceara, Fortaleza, CE, CEP:60440-554, Brazil;

Corresponding author: Antoninho Valentini,
Received Date: 19 September 2013
Available Online: 30 December 2013

A factorial experimental design was combined with response surface methodology (RSM) to optimize the catalyzed CO₂ consumption by coke deposition and syngas production during the dry reforming of CH₄. The CH₄/CO₂ feed ratio and the reaction temperature were chosen as the variables, and the selected responses were CH₄ and CO₂conversion, the H₂/CO ratio, and coke deposition. The optimal reaction conditions were found to be a CH₄/CO₂ feed ratio of approximately 3 at 700 ℃, producing a large quantity of coke and realizing high CO₂ conversion. Furthermore, Raman results showed that the CH₄/CO₂ ratio and reaction temperature affect the system's response, particularly the characteristics of the coke produced, which indicates the formation of carbon nanotubes and amorphous carbon.
- Factorial design,
- Carbon dioxide,
- Reforming,
- Methane,
- Carbon nanotube
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沈阳化工大学材料科学与工程学院沈阳 110142

CO2 mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology

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通讯作者: 陈斌, bchen63@163.com

CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology