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Citation: LIU Guo-Qi, LI Guo-Bao, LIAO Fu-Hui, LIN Jian-Hua. Synthesis, Structure and Thermal Property of [(n-C₁₆H₃₃)N(CH₃)₃]₂[TiF₆]·2H₂O[J]. Acta Physico-Chimica Sinica, ;2008, 24(11): 1945-1949. doi: 10.1016/S1872-1508(08)60076-5 shu

Synthesis, Structure and Thermal Property of [(n-C₁₆H₃₃)N(CH₃)₃]₂[TiF₆]·2H₂O

1.
Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 15 July 2008
Available Online: 22 September 2008

A new compound dicetyltrimethylammonium hexafluorotitanium dihydrate, [(n-C16H33)N(CH3)3]2[TiF6]·2H2O (compound 1), was hydrothermally synthesized at 150 ℃ and characterized by single crystal X-ray diffraction, Fourier-transform infrared (FTIR) spectroscopy, elemental analysis, and thermogravimetric analysis. Compound 1 crystallizes in the monoclinic system, space group C2/c. It consists of hexafluorotitanium cations [TiF6]2-, water molecular (H2O), and cetyltrimethylammonium ions [(n-C16H33)N(CH3)3]+, which are connected together by extensive hydrogen bonding.
- Titaniumfluoride,
- Cetyltrimethylammonium,
- Hydrothermal reaction
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Synthesis, Structure and Thermal Property of [(n-C16H33)N(CH3)3]2[TiF6]·2H2O

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Structure and Thermal Property of [(n-C₁₆H₃₃)N(CH₃)₃]₂[TiF₆]·2H₂O