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Citation: MA Yu-Chao, ZHANG Li-Min, ZHUANG Xiu-Juan, WANG Jin-Ting, YANG Mao-Ping, YU Shu-Qin. Calculation of the Franck-Condon Factors for the C²Σ_g⁺←B²Σ_u⁺ Transitions of CS₂+ Ions and Comparison with Related Photodissociation Spectra[J]. Acta Physico-Chimica Sinica, ;2006, 22(12): 1532-1536. doi: 10.1016/S1872-1508(06)60078-8 shu

Calculation of the Franck-Condon Factors for the C²Σ_g⁺←B²Σ_u⁺ Transitions of CS₂+ Ions and Comparison with Related Photodissociation Spectra

1.
(Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China)

Received Date: 12 June 2006
Available Online: 6 December 2006

On the basis of the approximation of harmonic oscillation between SC and S for the symmetric stretching vibration of the CS2+ ions, the Franck-Condon factors for the C2Σg+←B2Σu+ transitions of CS2+ ions have been calculated using the potential curves and wavefunctions of the harmonic oscillator. The calculation results have been used for comparison with the photodissociation spectra via the C2Σg+←B2Σu+ transition, and to estimate the validity of the rotation constants and the bond length of C2Σg+ state given in the previous studies. The photodissociation mechanism via the C2Σg+←B2Σu+transitions of CS2+ ions has also been discussed.
- CS2+ ions;Franck-Condon factors;Photodissociation spectra
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沈阳化工大学材料科学与工程学院沈阳 110142

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Calculation of the Franck-Condon Factors for the C2Σg+←B2Σu+ Transitions of CS2+ Ions and Comparison with Related Photodissociation Spectra

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通讯作者: 陈斌, bchen63@163.com

Calculation of the Franck-Condon Factors for the C²Σ_g⁺←B²Σ_u⁺ Transitions of CS₂+ Ions and Comparison with Related Photodissociation Spectra