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Citation: ZHOU Yong-Ning, WU Chang-Liang, ZHANG Hua, WU Xiao-Jing, FU Zheng-Wen. The Electrochemical Properties of LiF-Ni Nanocomposite Thin Film[J]. Acta Physico-Chimica Sinica, ;2006, 22(09): 1111-1115. doi: 10.1016/S1872-1508(06)60051-X shu

The Electrochemical Properties of LiF-Ni Nanocomposite Thin Film

1.
(Department of Chemistry and Laser Chemistry Institute, Department of Materials Science, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai 200433, P. R. China)

Received Date: 3 March 2006
Available Online: 4 September 2006

Nanocomposite of LiF-Ni with a highly heterogeneous mixture was fabricated using pulsed laser deposition (PLD) method, and it exhibited remarkable electrochemical activity. The electrochemical reaction of LiF-Ni nanocomposite thin-film electrode with Li was firstly investigated by the discharge/charge and cyclic voltammetry. The initial charge capacity of the LiF-Ni/Li cell was found to be 107 mAh•g−1. The process of releasing Li from the as-deposited LiF-Ni nanocomposite thin films was confirmed by ex-situ high-resolution transmission electron microscopy and by the selected area electron diffraction measurements. These results provided a direct experimental evidence to support the electrochemical decomposition of LiF driven by the transition metal Ni in the potential range from 1.0 V to 4.0 V. LiF-Ni nanocomposite electrodes could be a novel candidate that could be used as an appropriate for Li storage material.
- LiF-Ni;Nanocomposite thin film;Pulsed laser deposition;Electrochemical reaction
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