Citation: Sheng-Qing Yang, Jin-Nan Zhao, Jing-Bo Zhao, Zhi-Yuan Zhang, Jun-Ying Zhang. Cross-linked Polyamides Prepared through Direct Bulk Michael Addition and Polycondensation from 1,6-Hexanediamine and Methyl Acrylate[J]. Chinese Journal of Polymer Science, ;2020, 38(2): 143-150. doi: 10.1007/s10118-019-2332-y shu

Cross-linked Polyamides Prepared through Direct Bulk Michael Addition and Polycondensation from 1,6-Hexanediamine and Methyl Acrylate

Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Jing-Bo Zhao, zhaojb@mail.buct.edu.cn Jun-Ying Zhang, zhangjy@mail.buct.edu.cn
Received Date: 22 April 2019
Revised Date: 5 July 2019
Available Online: 12 October 2019

Cross-linked polyamides (cPAs) were prepared through direct bulk Michael addition and subsequent polycondensation. Several mixed hexanediamine multi-esters (HDAMEs) were generated through the Michael addition of 1,6-hexanediamine (HDA) and methyl acrylate (MA) at 50 °C with different HDA/MA molar ratios. Melt polycondensation of HDAMEs then proceeded at 150 or 170 °C in flasks to obtain viscous fluids, and curing was continued in tetrafluoroethylene molds to obtain cPA films. The Michael addition was monitored on the basis of FTIR and ESI-MS spectra. The cPA films were characterized by DSC, TGA, dynamic mechanical analysis, and tensile test. These directly prepared cPAs exhibited T_g of 1–39 °C, tensile strength of up to 45 MPa, and strain at break from 18% to 40%. The cPAs with high tensile strength and good toughness were successfully synthesized through the direct bulk Michael addition from HDA and MA followed with polycondensation.
- Michael addition,
- Polycondensation,
- Mechanical properties
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