Citation: Jiang-Ping Xu, Jin-Tao Zhu. Block Copolymer Colloidal Particles with Unique Structures through Three-dimensional Confined Assembly and Disassembly[J]. Chinese Journal of Polymer Science, ;2019, 37(8): 744-759. doi: 10.1007/s10118-019-2294-0 shu

Block Copolymer Colloidal Particles with Unique Structures through Three-dimensional Confined Assembly and Disassembly

Jiang-Ping Xu ^1,2 ,
Jin-Tao Zhu ^1,2,,

a.
Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Materials Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China
b.
State Key Laboratory of Materials Processing and Mold Technology, HUST, Wuhan 430074, China

Corresponding author: Jin-Tao Zhu, jtzhu@mail.hust.edu.cn
Received Date: 29 March 2019
Revised Date: 14 May 2019
Available Online: 17 June 2019

Structured block copolymer (BCP) particles have gained increasing attention due to their potential applications in separation, catalysis, controlled release, and other fields. Three-dimensional (3D) confined assembly has been proved as a facile yet robust approach for generating BCP particles with controllable shapes and internal structures. In this feature article, we summarized the preparation of structured polymeric particles through 3D confined self-assembly of BCPs. The effects of interfacial interactions, degree of confinement, and additives on the shape and internal structure of BCP microparticles were comprehensively discussed. In addition, we highlighted the recent progress in using disassembly as a route to synthesize colloidal particles with unique structures. Two strategies were introduced in this part: (a) disassembling the discrete domains resulted in mesoporous microparticles; (b) disassembling the continuous domains led to the dissociation of microparticles into micelle-like nano-objects. The applications of the structured colloidal particles in photonic crystals, controlled release, and directed growth of inorganic materials were also presented. Finally, we discussed the current challenges and future opportunities in this promising area.
- Block copolymers,
- Self-assembly,
- Confinement,
- Polymer particles,
- Nano-objects
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