Citation: Jiang-Ping Xu, Jin-Tao Zhu. Block Copolymer Colloidal Particles with Unique Structures through Three-dimensional Confined Assembly and Disassembly[J]. Chinese Journal of Polymer Science, ;2019, 37(8): 744-759. doi: 10.1007/s10118-019-2294-0 shu

Block Copolymer Colloidal Particles with Unique Structures through Three-dimensional Confined Assembly and Disassembly

Jiang-Ping Xu ^1,2 ,
Jin-Tao Zhu ^1,2,,

a.
Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Materials Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China
b.
State Key Laboratory of Materials Processing and Mold Technology, HUST, Wuhan 430074, China

Corresponding author: Jin-Tao Zhu, jtzhu@mail.hust.edu.cn
Received Date: 29 March 2019
Revised Date: 14 May 2019
Available Online: 17 June 2019

Structured block copolymer (BCP) particles have gained increasing attention due to their potential applications in separation, catalysis, controlled release, and other fields. Three-dimensional (3D) confined assembly has been proved as a facile yet robust approach for generating BCP particles with controllable shapes and internal structures. In this feature article, we summarized the preparation of structured polymeric particles through 3D confined self-assembly of BCPs. The effects of interfacial interactions, degree of confinement, and additives on the shape and internal structure of BCP microparticles were comprehensively discussed. In addition, we highlighted the recent progress in using disassembly as a route to synthesize colloidal particles with unique structures. Two strategies were introduced in this part: (a) disassembling the discrete domains resulted in mesoporous microparticles; (b) disassembling the continuous domains led to the dissociation of microparticles into micelle-like nano-objects. The applications of the structured colloidal particles in photonic crystals, controlled release, and directed growth of inorganic materials were also presented. Finally, we discussed the current challenges and future opportunities in this promising area.
- Block copolymers,
- Self-assembly,
- Confinement,
- Polymer particles,
- Nano-objects
1. [1]
  Yu, H.; Qiu, X.; Nunes, S. P.; Peinemann, K. V. Biomimetic block copolymer particles with gated nanopores and ultrahigh protein sorption capacity. Nat. Commun. 2014, 5, 4110. doi: 10.1038/ncomms5110
2. [2]
  Otsuka, H.; Nagasaki, Y.; Kataoka, K. PEGylated nanoparticles for biological and pharmaceutical applications. Adv. Drug Delivery Rev. 2003, 55, 403-419. doi: 10.1016/S0169-409X(02)00226-0
3. [3]
  Pham, H. H.; Gourevich, I.; Oh, J. K.; Jonkman, J. E. N.; Kumacheva, E. A multidye nanostructured material for optical data storage and security data encryption. Adv. Mater. 2004, 16, 516-520. doi: 10.1002/(ISSN)1521-4095
4. [4]
  Yi, Z.; Zhang, P. B.; Liu, C. J.; Zhu, L. P. Symmetrical permeable membranes consisting of overlapped block copolymer cylindrical micelles for nanoparticle size fractionation. Macromolecules 2016, 49, 3343-3351. doi: 10.1021/acs.macromol.6b00166
5. [5]
  Bakshi, M. S. Colloidal micelles of block copolymers as nanoreactors, templates for gold nanoparticles, and vehicles for biomedical applications. Adv. Colloid Interface Sci. 2014, 213, 1-20. doi: 10.1016/j.cis.2014.08.001
6. [6]
  Wang, W. C.; Peng, C.; Shi, K.; Pan, Y. X.; Zhang, H. S.; Ji, X. L. Double emulsion droplets as microreactors for synthesis of magnetic macroporous polymer beads. Chinese J. Polym. Sci. 2014, 32, 1639-1645. doi: 10.1007/s10118-014-1543-5
7. [7]
  Lee, J. H.; Lee, C. S.; Cho, K. Y. Enhanced cell adhesion to the dimpled surfaces of golf-ball-shaped microparticles. ACS Appl. Mater. Interfaces 2014, 6, 16493-16497. doi: 10.1021/am505997s
8. [8]
  Wang, L.; Yamauchi, Y., Facile Synthesis of three-dimensional dendritic platinum nanoelectrocatalyst. Chem. Mater. 2009, 21, 3562-3569. doi: 10.1021/cm901161g
9. [9]
  Champion, J. A.; Mitragotri, S. Role of target geometry in phagocytosis. Proc. Natl. Acad. Sci. U. S. A. 2006, 103, 4930-4934. doi: 10.1073/pnas.0600997103
10. [10]
  Sacanna, S.; Korpics, M.; Rodriguez, K.; Colon-Melendez, L.; Kim, S. H.; Pine, D. J.; Yi, G. R., Shaping colloids for self-assembly. Nat. Commun. 2013, 4, 1688. doi: 10.1038/ncomms2694
11. [11]
  Chen, Q.; Bae, S. C.; Granick, S., Directed self-assembly of a colloidal kagome lattice. Nature 2011, 469, 381-384. doi: 10.1038/nature09713
12. [12]
  Koh, L. B.; Rodriguez, I.; Venkatraman, S. S. The effect of topography of polymer surfaces on platelet adhesion. Biomaterials 2010, 31, 1533-1545. doi: 10.1016/j.biomaterials.2009.11.022
13. [13]
  Shen, L.; Zhu, J. Heterogeneous surfaces to repel proteins. Adv. Colloid Interface Sci. 2016, 228, 40-54. doi: 10.1016/j.cis.2015.11.008
14. [14]
  Shezad, K.; Zhang, K.; Hussain, M.; Dong, H.; He, C.; Gong, X.; Xie, X.; Zhu, J.; Shen, L. Surface roughness modulates diffusion and fibrillation of amyloid-beta peptide. Langmuir 2016, 32, 8238-8244. doi: 10.1021/acs.langmuir.6b01756
15. [15]
  Wang, K.; Liu, L.; Xie, J.; Shen, L.; Tao, J.; Zhu, J. facile strategy to generate aligned polymer nanofibers: effects on cell adhesion. ACS Appl. Mater. Interfaces 2018, 10, 1566-1574. doi: 10.1021/acsami.7b16057
16. [16]
  Kawaguchi, H., Functional polymer microspheres. Prog. Polym. Sci. 2000, 25, 1171-1210. doi: 10.1016/S0079-6700(00)00024-1
17. [17]
  Riess, G.; Labbe, C. Block copolymers in emulsion and dispersion polymerization. Macromol. Rapid Commun. 2004, 25, 401-435. doi: 10.1002/(ISSN)1521-3927
18. [18]
  Tanaka, T.; Komatsu, Y.; Fujibayashi, T.; Minami, H.; Okubo, M., A novel approach for preparation of micrometer-sized, monodisperse dimple and hemispherical polystyrene particles. Langmuir 2010, 26, 3848-3853. doi: 10.1021/la903309t
19. [19]
  Kim, S. H.; Hollingsworth, A. D.; Sacanna, S.; Chang, S. J.; Lee, G.; Pine, D. J.; Yi, G. R. Synthesis and assembly of colloidal particles with sticky dimples. J. Am. Chem. Soc. 2012, 134, 16115-16118. doi: 10.1021/ja305865w
20. [20]
  Andala, D. M.; Shin, S. H. R.; Lee, H. Y.; Bishop, K. J. M. Templated synthesis of amphiphilic nanoparticles at the liquid-liquid interface. ACS Nano 2012, 6, 1044-1050. doi: 10.1021/nn202556b
21. [21]
  Luo, Z.; Liu, B. Shape-tunable colloids from structured liquid droplet templates. Angew. Chem., Int. Ed. 2018, 57, 4940-4945. doi: 10.1002/anie.201800587
22. [22]
  Wang, W.; Zhang, M. J.; Chu, L. Y. Functional polymeric microparticles engineered from controllable microfluidic emulsions. Acc. Chem. Res. 2014, 47, 373-384. doi: 10.1021/ar4001263
23. [23]
  Zhu, J.; Hayward, R. C. Spontaneous generation of amphiphilic block copolymer micelles with multiple morphologies through interfacial instabilities. J. Am. Chem. Soc. 2008, 130, 7496-7502. doi: 10.1021/ja801268e
24. [24]
  Zhu, J.; Hayward, R. C. Hierarchically structured microparticles formed by interfacial instabilities of emulsion droplets containing amphiphilic block copolymers. Angew. Chem., Int. Ed. 2008, 47, 2113-2116. doi: 10.1002/(ISSN)1521-3773
25. [25]
  Shi, A. C.; Li, B. Self-assembly of diblock copolymers under confinement. Soft Matter 2013, 9, 1398-1413. doi: 10.1039/C2SM27031E
26. [26]
  Yan, N.; Zhu, Y.; Jiang, W. Recent progress in the self-assembly of block copolymers confined in emulsion droplets. Chem. Commun. 2018, 54, 13183-13195. doi: 10.1039/C8CC05812A
27. [27]
  Zhang, L. B.; Wang, K.; Zhu, J. T. Research progress on confined assembly of block copolymers in china. Acta Polymerica Sinica (in Chinese) 2017, 1261-1276.
28. [28]
  Jeon, S. J.; Yi, G. R.; Yang, S. M. Cooperative assembly of block copolymers with deformable interfaces: toward nanostructured particles. Adv. Mater. 2008, 20, 4103-4108. doi: 10.1002/adma.v20:21
29. [29]
  Klinger, D.; Wang, C. X.; Connal, L. A.; Audus, D. J.; Jang, S. G.; Kraemer, S.; Killops, K. L.; Fredrickson, G. H.; Kramer, E. J.; Hawker, C. J. A facile synthesis of dynamic, shape-changing polymer particles. Angew. Chem. Int. Ed. 2014, 53, 7018-7022. doi: 10.1002/anie.201400183
30. [30]
  Ku, K. H.; Shin, J. M.; Kim, M. P.; Lee, C. H.; Seo, M. K.; Yi, G. R.; Jang, S. G.; Kim, B. J. Size-controlled nanoparticle-guided assembly of block copolymers for convex lens-shaped particles. J. Am. Chem. Soc. 2014, 136, 9982-9989. doi: 10.1021/ja502075f
31. [31]
  Jin, Z.; Fan, H. Self-assembly of nanostructured block copolymer nanoparticles. Soft Matter 2014, 10, 9212-9219. doi: 10.1039/C4SM02064B
32. [32]
  Chi, P.; Wang, Z.; Li, B.; Shi, A. C. Soft confinement-induced morphologies of diblock copolymers. Langmuir 2011, 27, 11683-11689. doi: 10.1021/la202448c
33. [33]
  Chen, P.; Liang, H.; Shi, A. C. Origin of microstructures from confined asymmetric diblock copolymers. Macromolecules 2007, 40, 7329-7335. doi: 10.1021/ma0705164
34. [34]
  Xiang, H. Q.; Shin, K.; Kim, T.; Moon, S. I.; McCarthy, T. J.; Russell, T. P. Block copolymers under cylindrical confinement. Macromolecules 2004, 37, 5660-5664. doi: 10.1021/ma049299m
35. [35]
  Yu, B.; Jin, Q.; Ding, D.; Li, B.; Shi, A. C. Confinement-induced morphologies of cylinder-forming asymmetric diblock copolymers. Macromolecules 2008, 41, 4042-4054. doi: 10.1021/ma702430v
36. [36]
  Yu, B.; Li, B.; Jin, Q.; Ding, D.; Shi, A. C. Self-assembly of symmetric diblock copolymers confined in spherical nanopores. Macromolecules 2007, 40, 9133-9142. doi: 10.1021/ma071624t
37. [37]
  Zhu, Y.; Jiang, W. Self-assembly of diblock copolymer mixtures in confined states: A Monte Carlo study. Macromolecules 2007, 40, 2872-2881. doi: 10.1021/ma062022x
38. [38]
  Yu, B.; Sun, P. C.; Chen, T. H.; Jin, Q. H.; Ding, D. T.; Li, B. H.; Shi, A. C. Confinement-induced novel morphologies of block copolymers. Phys. Rev. Lett. 2006, 96, 138306. doi: 10.1103/PhysRevLett.96.138306
39. [39]
  Shin, K.; Xiang, H. Q.; Moon, S. I.; Kim, T.; McCarthy, T. J.; Russell, T. P. Curving and frustrating flatland. Science 2004, 306, 76-76. doi: 10.1126/science.1100090
40. [40]
  Yabu, H.; Higuchi, T.; Jinnai, H. Frustrated phases: polymeric self-assemblies in a 3D confinement. Soft Matter 2014, 10, 2919-2931. doi: 10.1039/c3sm52821a
41. [41]
  Ku, K. H.; Shin, J. M.; Yun, H.; Yi, G. R.; Jang, S. G.; Kim, B. J. Multidimensional design of anisotropic polymer particles from solvent-evaporative emulsion. Adv. Funct. Mater. 2018, 28, 1802961. doi: 10.1002/adfm.201802961
42. [42]
  Cheng, J. Y.; Mayes, A. M.; Ross, C. A. Nanostructure engineering by templated self-assembly of block copolymers. Nat. Mater. 2004, 3, 823-828. doi: 10.1038/nmat1211
43. [43]
  Gentili, D.; Valle, F.; Albonetti, C.; Liscio, F.; Cavallini, M. Self-organization of functional materials in confinement. Acc. Chem. Res. 2014, 47, 2692-2699. doi: 10.1021/ar500210d
44. [44]
  Higuchi, T.; Tajima, A.; Motoyoshi, K.; Yabu, H.; Shimomura, M. Frustrated phases of block copolymers in nanoparticles. Angew. Chem., Int. Ed. 2008, 47, 8044-8046. doi: 10.1002/anie.v47:42
45. [45]
  Jiang, W. B.; Ji, Y. Y.; Lang, W. C.; Li, S. B.; Wang, X. H. Surface-induced morphologies of ABC star triblock copolymer in spherical cavities. Chinese J. Polym. Sci. 2015, 33, 1503-1515. doi: 10.1007/s10118-015-1706-z
46. [46]
  Qiu, W.-J.; Li, S. B.; Ji, Y. Y.; Zhang, L. X. Self-assembly of linear triblock copolymers under cylindrical nanopore confinements. Chinese J. Polym. Sci. 2013, 31, 122-138. doi: 10.1007/s10118-013-1183-1
47. [47]
  He, X. H.; Song, M.; Liang, H. J.; Pan, C. Y. Self-assembly of the symmetric diblock copolymer in a confined state: Monte Carlo simulation. J. Chem. Phys. 2001, 114, 10510-10513. doi: 10.1063/1.1372189
48. [48]
  Arsenault, A. C.; Rider, D. A.; Tétreault, N.; Chen, J. I. L.; Coombs, N.; Ozin, G. A.; Manners, I. Block copolymers under periodic, strong three-dimensional confinement. J. Am. Chem. Soc. 2005, 127, 9954-9955. doi: 10.1021/ja052483i
49. [49]
  Chen, P.; Liang, H.; Shi, A. C. Microstructures of a cylinder-forming diblock copolymer under spherical confinement. Macromolecules 2008, 41, 8938-8943. doi: 10.1021/ma800443h
50. [50]
  Mei, S. L.; Jin, Z. X. Mesoporous block-copolymer nanospheres prepared by selective swelling. Small 2013, 9, 322-329. doi: 10.1002/smll.201201504
51. [51]
  Higuchi, T.; Tajima, A.; Motoyoshi, K.; Yabu, H.; Shimomura, M. Suprapolymer structures from nanostructured polymer particles. Angew. Chem. Int. Ed. 2009, 48, 5125-5128. doi: 10.1002/anie.v48:28
52. [52]
  Yan, X.; Liu, G.; Li, Z. Preparation and phase segregation of block copolymer nanotube multiblocks. J. Am. Chem. Soc. 2004, 126, 10059-10066. doi: 10.1021/ja0479890
53. [53]
  Zhang, K.; Gao, L.; Chen, Y. Organic-inorganic hybrid materials by self-gelation of block copolymer assembly and nanoobjects with controlled shapes thereof. Macromolecules 2007, 40, 5916-5922. doi: 10.1021/ma070780x
54. [54]
  Wang, Y.; Li, F. B. An emerging pore-making strategy: Confined swelling-induced pore generation in block copolymer materials. Adv. Mater. 2011, 23, 2134-2148. doi: 10.1002/adma.v23.19
55. [55]
  Nandan, B.; Horechyy, A. Hairy core-shell polymer nano-objects from self-assembled block copolymer structures. ACS Appl. Mater. Interfaces 2015, 7, 12539-12558. doi: 10.1021/am5075503
56. [56]
  Walther, A.; Mueller, A. H. E. Janus particles: synthesis, self-assembly, physical properties, and applications. Chem. Rev. 2013, 113, 5194-5261. doi: 10.1021/cr300089t
57. [57]
  Walther, A.; Drechsler, M.; Rosenfeldt, S.; Harnau, L.; Ballauff, M.; Abetz, V.; Mueller, A. H. E. Self-assembly of Janus cylinders into hierarchical superstructures. J. Am. Chem. Soc. 2009, 131, 4720-4728. doi: 10.1021/ja808614q
58. [58]
  Chen, Y. Shaped hairy polymer nanoobjects. Macromolecules 2012, 45, 2619-2631. doi: 10.1021/ma201495m
59. [59]
  Liu, S. Q.; Deng, R. H.; Li, W. K.; Zhu, J. T. Polymer microparticles with controllable surface textures generated through interfacial instabilities of emulsion droplets. Adv. Funct. Mater. 2012, 22, 1692-1697. doi: 10.1002/adfm.v22.8
60. [60]
  Jang, S. G.; Audus, D. J.; Klinger, D.; Krogstad, D. V.; Kim, B. J.; Cameron, A.; Kim, S.-W.; Delaney, K. T.; Hur, S. M.; Killops, K. L.; Fredrickson, G. H.; Kramer, E. J.; Hawker, C. J. Striped, ellipsoidal particles by controlled assembly of diblock copolymers. J. Am. Chem. Soc. 2013, 135, 6649-6657. doi: 10.1021/ja4019447
61. [61]
  Deng, R.; Liang, F.; Li, W.; Yang, Z.; Zhu, J. Reversible transformation of nanostructured polymer particles. Macromolecules 2013, 46, 7012-7017. doi: 10.1021/ma401398h
62. [62]
  Deng, R.; Liu, S.; Liang, F.; Wang, K.; Zhu, J.; Yang, Z. Polymeric Janus particles with hierarchical structures. Macromolecules 2014, 47, 3701-3707. doi: 10.1021/ma500331w
63. [63]
  Xu, J.; Wang, K.; Li, J.; Zhou, H.; Xie, X.; Zhu, J. ABC triblock copolymer particles with tunable shape and internal structure through 3D confined assembly. Macromolecules 2015, 48, 2628-2636. doi: 10.1021/acs.macromol.5b00335
64. [64]
  Yan, N.; Liu, H.; Zhu, Y.; Jiang, W.; Dong, Z. Entropy-driven hierarchical nanostructures from cooperative self-assembly of gold nanoparticles/block copolymers under three-dimensional confinement. Macromolecules 2015, 48, 5980-5987. doi: 10.1021/acs.macromol.5b01219
65. [65]
  Yan, N.; Zhang, Y.; He, Y.; Zhu, Y.; Jiang, W. Controllable location of inorganic nanoparticles on block copolymer self-assembled scaffolds by tailoring the entropy and enthalpy contributions. Macromolecules 2017, 50, 6771-6778. doi: 10.1021/acs.macromol.7b01076
66. [66]
  Yan, N.; Zhu, Y.; Jiang, W. Self-assembly of AB diblock copolymer confined in a soft nano-droplet: a combination study by Monte Carlo simulation and experiment. J. Phys. Chem. B 2016, 120, 12023-12029. doi: 10.1021/acs.jpcb.6b10170
67. [67]
  Ku, K. H.; Kim, Y.; Yi, G. R.; Jung, Y. S.; Kim, B. J. Soft patchy particles of block copolymers from interface-engineered emulsions. ACS Nano 2015, 9, 11333-11341. doi: 10.1021/acsnano.5b05058
68. [68]
  Deng, R.; Li, H.; Liang, F.; Zhu, J.; Li, B.; Xie, X.; Yang, Z. Soft colloidal molecules with tunable geometry by 3D confined assembly of block copolymers. Macromolecules 2015, 48, 5855-5860. doi: 10.1021/acs.macromol.5b01261
69. [69]
  Deng, R.; Li, H.; Zhu, J.; Li, B.; Liang, F.; Jia, F.; Qu, X.; Yang, Z. Janus nanoparticles of block copolymers by emulsion solvent evaporation induced assembly. Macromolecules 2016, 49, 1362-1368. doi: 10.1021/acs.macromol.5b02507
70. [70]
  Jeon, S. J.; Yi, G. R.; Koo, C. M.; Yang, S. M. Nanostructures inside colloidal particles of block copolymer/homopolymer blends. Macromolecules 2007, 40, 8430-8439. doi: 10.1021/ma0712302
71. [71]
  Rider, D. A.; Chen, J. I. L.; Eloi, J. C.; Arsenault, A. C.; Russell, T. P.; Ozin, G. A.; Manners, I., Controlling the morphologies of organometallic block copolymers in the 3-dimensional spatial confinement of colloidal and inverse colloidal crystals. Macromolecules 2008, 41, 2250-2259. doi: 10.1021/ma7020248
72. [72]
  Xu, J.; Yang, Y.; Wang, K.; Wu, Y.; Zhu, J. Fabrication of convex lens-shaped polymer particles by tuning the interfacial interaction. Mater. Chem. Front. 2017, 1, 507-511. doi: 10.1039/C6QM00072J
73. [73]
  Ku, K. H.; Yang, H.; Shin, J. M.; Kim, B. J. Aspect ratio effect of nanorod surfactants on the shape and internal morphology of block copolymer particles. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 188-192. doi: 10.1002/pola.27333
74. [74]
  Yang, H.; Ku, K. H.; Shin, J. M.; Lee, J.; Park, C. H.; Cho, H. H.; Jang, S. G.; Kim, B. J. Engineering the shape of block copolymer particles by surface-modulated graphene quantum dots. Chem. Mater. 2016, 28, 830-837. doi: 10.1021/acs.chemmater.5b04222
75. [75]
  Higuchi, T.; Motoyoshi, K.; Sugimori, H.; Jinnai, H.; Yabu, H.; Shimomura, M. Three-dimensional observation of confined phase-separated structures in block copolymer nanoparticles. Soft Matter 2012, 8, 3791-3797. doi: 10.1039/c2sm07139h
76. [76]
  Jo, I. S.; Lee, S.; Zhu, J.; Shim, T. S.; Yi, G. R. Soft patchy micelles. Curr. Opin. Colloid Interface Sci. 2017, 30, 97-105. doi: 10.1016/j.cocis.2017.06.005
77. [77]
  Tung, S. H.; Kalarickal, N. C.; Mays, J. W.; Xu, T. Hierarchical assemblies of block-copolymer-based supramolecules in thin films. Macromolecules 2008, 41, 6453-6462. doi: 10.1021/ma800726r
78. [78]
  Ruokolainen, J.; Makinen, R.; Torkkeli, M.; Makela, T.; Serimaa, R.; ten Brinke, G.; Ikkala, O. Switching supramolecular polymeric materials with multiple length scales. Science 1998, 280, 557-560. doi: 10.1126/science.280.5363.557
79. [79]
  Li, W.; Liu, S.; Deng, R.; Wang, J.; Nie, Z.; Zhu, J. A simple route to improve inorganic nanoparticles loading efficiency in block copolymer micelles. Macromolecules 2013, 46, 2282-2291. doi: 10.1021/ma302515p
80. [80]
  Li, W.; Liu, S.; Deng, R.; Zhu, J. Encapsulation of nanoparticles in block copolymer micellar aggregates by directed supramolecular assembly. Angew. Chem. Int. Ed. 2011, 50, 5865-5868. doi: 10.1002/anie.v50.26
81. [81]
  Li, W.; Zhang, P.; Dai, M.; He, J.; Babu, T.; Xu, Y. L.; Deng, R.; Liang, R.; Lu, M. H.; Nie, Z. Ordering of gold nanorods in confined spaces by directed assembly. Macromolecules 2013, 46, 2241-2248. doi: 10.1021/ma400115z
82. [82]
  Zhao, Y.; Thorkelsson, K.; Mastroianni, A. J.; Schilling, T.; Luther, J. M.; Rancatore, B. J.; Matsunaga, K.; Jinnai, H.; Wu, Y.; Poulsen, D.; Frechet, J. M. J.; Alivisatos, A. P.; Xu, T. Small-molecule-directed nanoparticle assembly towards stimuli-responsive nanocomposites. Nat. Mater. 2009, 8, 979-985. doi: 10.1038/nmat2565
83. [83]
  Deng, R.; Liang, F.; Li, W.; Liu, S.; Liang, R.; Cai, M.; Yang, Z.; Zhu, J. Shaping functional nano-objects by 3D confined supramolecular assembly. Small 2013, 9, 4099-4103. doi: 10.1002/smll.v9.24
84. [84]
  Deng, R.; Liu, S.; Li, J.; Liao, Y.; Tao, J.; Zhu, J. Mesoporous block copolymer nanoparticles with tailored structures by hydrogen-bonding-assisted self-assembly. Adv. Mater. 2012, 24, 1889-1893. doi: 10.1002/adma.v24.14
85. [85]
  Xu, J.; Li, J.; Yang, Y.; Wang, K.; Xu, N.; Li, J.; Liang, R.; Shen, L.; Xie, X.; Tao, J.; Zhu, J. Block copolymer capsules with structure-dependent release behavior. Angew. Chem. Int. Ed. 2016, 55, 14633-14637. doi: 10.1002/anie.201607982
86. [86]
  Xu, J.; Yang, Y.; Wang, K.; Li, J.; Zhou, H.; Xie, X.; Zhu, J. Additives induced structural transformation of ABC triblock copolymer particles. Langmuir 2015, 31, 10975-10982. doi: 10.1021/acs.langmuir.5b02843
87. [87]
  Wu, Y.; Tan, H.; Yang, Y.; Li, Y.; Xu, J.; Zhang, L.; Zhu, J. Regulating block copolymer assembly structures in emulsion droplets through metal ion coordination. Langmuir 2018, 34, 11495-11502. doi: 10.1021/acs.langmuir.8b02135
88. [88]
  Wu, Y.; Wang, K.; Tan, H.; Xu, J.; Zhu, J. Emulsion solvent evaporation-induced self-assembly of block copolymers containing pH-sensitive block. Langmuir 2017, 33, 9889-9896. doi: 10.1021/acs.langmuir.7b02330
89. [89]
  Karimi, M.; Ghasemi, A.; Zangabad, P. S.; Rahighi, R.; Basri, S. M. M.; Mirshekari, H.; Amiri, M.; Pishabad, Z. S.; Aslani, A.; Bozorgomid, M.; Ghosh, D.; Beyzavi, A.; Vaseghi, A.; Aref, A. R.; Haghani, L.; Bahrami, S.; Hamblin, M. R. Smart micro/nanoparticles in stimulus-responsive drug/gene delivery systems. Chem. Soc. Rev. 2016, 45, 1457-1501. doi: 10.1039/C5CS00798D
90. [90]
  Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Yang, H. F.; Li, Z.; Yu, C. Z.; Tu, B.; Zhao, D. Y., Ordered mesoporous polymers and homologous carbon frameworks: Amphiphilic surfactant templating and direct transformation. Angew. Chem. Int. Ed. 2005, 44, 7053-7059. doi: 10.1002/(ISSN)1521-3773
91. [91]
  Wan, Y.; Zhao, D., On the controllable soft-templating approach to mesoporous silicates. Chem. Rev. 2007, 107, 2821-2860. doi: 10.1021/cr068020s
92. [92]
  Deng, Y.; Wei, J.; Sun, Z.; Zhao, D. Large-pore ordered mesoporous materials templated from non-Pluronic amphiphilic block copolymers. Chem. Soc. Rev. 2013, 42, 4054-4070. doi: 10.1039/C2CS35426H
93. [93]
  Wu, Y. Y.; Cheng, G. S.; Katsov, K.; Sides, S. W.; Wang, J. F.; Tang, J.; Fredrickson, G. H.; Moskovits, M.; Stucky, G. D. Composite mesostructures by nano-confinement. Nat. Mater. 2004, 3, 816-822. doi: 10.1038/nmat1230
94. [94]
  He, Y.; Zhang, Y.; Yan, N.; Zhu, Y.; Jiang, W.; Shi, D., Self-assembly of block copolymers into sieve-like particles with arrayed switchable channels and as scaffolds to guide the arrangement of gold nanoparticles. Nanoscale 2017, 9, 15056-15061. doi: 10.1039/C7NR04923D
95. [95]
  Deng, R.; Liang, F.; Zhou, P.; Zhang, C.; Qu, X.; Wang, Q.; Li, J.; Zhu, J.; Yang, Z. Janus nanodisc of diblock copolymers. Adv. Mater. 2014, 26, 4469-4472. doi: 10.1002/adma.v26.26
96. [96]
  Deng, R.; Liang, F.; Qu, X.; Wang, Q.; Zhu, J.; Yang, Z. Diblock copolymer based Janus nanoparticles. Macromolecules 2015, 48, 750-755. doi: 10.1021/ma502339s
97. [97]
  Yang, Y.; Kim, H.; Xu, J.; Hwang, M. S.; Tian, D.; Wang, K.; Zhang, L.; Liao, Y.; Park, H. G.; Yi, G. R.; Xie, X.; Zhu, J. Responsive block copolymer photonic microspheres. Adv. Mater. 2018, 30, 1707344. doi: 10.1002/adma.v30.21
98. [98]
  Pisani, E.; Tsapis, N.; Galaz, B.; Santin, M.; Berti, R.; Taulier, N.; Kurtisovski, E.; Lucidarme, O.; Ourevitch, M.; Doan, B. T.; Beloeil, J. C.; Gillet, B.; Urbach, W.; Bridal, S. L.; Fattal, E. Perfluorooctyl bromide polymeric capsules as dual contrast agents for ultrasonography and magnetic resonance imaging. Adv. Funct. Mater. 2008, 18, 2963-2971. doi: 10.1002/adfm.v18:19
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