Citation: Xiang-Li Meng, Gen-Hua Yu, Jian Ma. Preparation and Properties of Poly(aryl ether sulfone ketone) Ultrafiltration Membrane Containing Fluorene Group for High Temperature Condensed Water Treatment[J]. Chinese Journal of Polymer Science, ;2018, 36(8): 970-978. doi: 10.1007/s10118-018-2142-7 shu

Preparation and Properties of Poly(aryl ether sulfone ketone) Ultrafiltration Membrane Containing Fluorene Group for High Temperature Condensed Water Treatment

School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

Corresponding author: Xiang-Li Meng, mengxl2009@hit.edu.cn
Received Date: 13 March 2017
Revised Date: 5 April 2018
Accepted Date: 7 April 2018
Available Online: 11 May 2018

Novel poly(aryl ether sulfone ketone)s (PAESK) were synthesized from bisphenol A (BPA), 9,9′-bis(4-hydroxyphenyl) fluorene (BHPF), 4,4′-dichlorodiphenylsulfone (DCS) and 4,4′-difluorobenzophenone (DFB) via nucleophilic substitution polymerization, which were subsequently used to fabricate ultrafiltration membrane by phase-inversion method for high temperature condensed water treatment. The obtained high molecular weight co-polymers with fluorene group with good solubility and good thermal stability, can be easily cast into flexible, white and non-transparent flat films. The influence of molar ratio of BPA and BHPF on the properties of the prepared co-polymers and membranes was investigated in detail. SEM study of the morphology of the membranes indicated that the prepared membranes possessed homogeneous pores on the top surface and were sponge-like or finger-like in cross-section. Pure water flux of the membranes increased from 71.87 L·m⁻²·h⁻¹ to 247.65 L·m⁻²·h⁻¹, while the retention of BSA decreased slightly, and the water contact angle decreased from 82.1° to 55.6° with the PVP concentration from 0 wt% to 10 wt%. With increasing concentration of PVP, the mechanical properties of membranes decreased, while the thermal stability increased. The permeate flux measurement showed that the PAESK membrane had the potential for high temperature condensed water treatment.
- Poly(aryl ether sulfone ketone),
- Fluorene group,
- Thermal stability,
- Ultrafiltration membrane
1. [1]
  Zhao, S. S.; Wang, P.; Wang, C.; Sun, X.; Zhang, L. H. Thermostable PPESK/TiO₂ nanocomposite ultrafiltration membrane for high temperature condensed water treatment. Desalination 2012, 299, 35−43 doi: 10.1016/j.desal.2012.05.013
2. [2]
  Leng, S. Purifying techniques of condensed water. Ind. Water Treat. 2010, 30, 64−67
3. [3]
  Caissie, D. The thermal regime of rivers: a review. Freshw. Biol. 2006, 51, 1389−1406 doi: 10.1111/fwb.2006.51.issue-8
4. [4]
  Verones, F.; Hanafish, M. M.; Pfister, S.; Huijbregts, M. A. J.; Pelletier G. J.; Koehler, A. Characterization factors for thermal pollution in freshwater aquatic environments. Environ. Sci. Technol. 2010, 44, 9364−9369 doi: 10.1021/es102260c
5. [5]
  Arieli, R. N.; Labin, A. A.; Abramovich, S.; Herut, B. The effect of thermal pollution on benthic foraminiferal assemblages in the mediterranean shoreface adjacent to Hadera power plant (Israel). Mar. Pollut. Bull. 2011, 62, 1002−1012 doi: 10.1016/j.marpolbul.2011.02.036
6. [6]
  Zhai, J. W.; Luo, M.; Wang, D.; Wu, Z. Z.; Wu, D. W. Application of high-temperature tolerance membrane in condensation water deep purification and treatment. Chem. Ind. Eng. Prog. 2009, 28, 69−71
7. [7]
  Yeon, K. H.; Song, J. H.; Moon, S. H. A study on stack configuration of continuous electrodeionization for removal of heavy metal ions from the primary coolant of nuclear power plant. Water Res. 2004, 38, 1911−1921 doi: 10.1016/j.watres.2004.01.003
8. [8]
  Lim, T. T.; Huang, X. F. Evaluation of hydrophobicity/ oleophilicity of kapok and its performance in oily water filtration: Comparison of raw and solvent-treated fivers. Ind. Crops Prod. 2007, 26, 125−134 doi: 10.1016/j.indcrop.2007.02.007
9. [9]
  Strathmann, H. Synthetic membranes and their preparation. Noyes Publications, New Jersey, 1990
10. [10]
  Coutinho, C. M.; Chiu, M. C.; Basso, R. C.; Ribeiro, A. P. B.; Goncalves, L. A. G.; Viotto, L.A. State of art of the application of membrane technology to vegetable oils: A review. Food Res. Int. 2009, 42, 536−550 doi: 10.1016/j.foodres.2009.02.010
11. [11]
  Yang, D. L.; Jin, Z.; Zhang, S. H.; Jian, X. G. Preparation and characterazition of poly(phthalazinone ether sulfone ketone) hollow fiber ultrafiltration membrane with high-molecular weight cut-off. J. Membr. Sci. 2007, 306, 253−260 doi: 10.1016/j.memsci.2007.08.044
12. [12]
  Yun, Y. B.; Tian, Y. H.; Shi, G. L.; Li, J. D.; Chen, C. X. Preparation, morphologies and properties for flat sheet PPESK ultrafiltration membranes. J. Membr. Sci. 2006, 270, 146−153 doi: 10.1016/j.memsci.2005.06.050
13. [13]
  Jian, X. G.; Yan, C.; Zhang, H. M.; Zhang, S. H.; Liu, C.; Zhao, P. Syethesis and characterization of quaternized poly(phthalazinone ether sulfone ketone) for anion exchange membrane. Chin. Chem. Lett. 2007, 18, 1269−1272 doi: 10.1016/j.cclet.2007.08.022
14. [14]
  Sun, W. N.; Chen, C. X.; Li, J. D.; Lin, Y. Z. Ultrafiltration membrane formation of PES-C, PES and PPESK polymers with different solvents. Chinese J. Polym. Sci. 2009, 27, 165−172 doi: 10.1142/S0256767909003790
15. [15]
  Zhu, L. P.; Xu, Y. Y.; Wei, X. Z.; Zhu, B. K. Hydrophilic modification of poly(phthalazine ether sulfone ketone) ultrafiltration membranes by the surface immobilization of poly(ethylene glycol) acrylates. Desalination 2009, 242, 96−109 doi: 10.1016/j.desal.2008.03.034
16. [16]
  Shimura, T.; Miyatake, K.; Watanabe, M. Poly(arylene ether) ionomers containing sulfofluorenyl groups: Effect of electron-withdrawing groups on the properties. Eur. Polym. J. 2008, 44, 4054−4062 doi: 10.1016/j.eurpolymj.2008.09.017
17. [17]
  Harrison, W. L.; Wang, F.; Mecham, J. B.; Bhanu, V. A.; Hill, M.; Kim, Y. S.; McGrath, J. E. Influence of the bisphenol structure on the direct synthesis of sulfonated poly(arylene ether) copolymers. I. J. Polym. Sci., Part A: Polym. Chem. 2003, 41, 2264−2276
18. [18]
  Zhu, L. P.; Du, C. H.; Xu, L.; Feng, Y. X.; Zhu, B. K.; Xu, Y. Y. Amphiphilic PPESK-g-PEG graft copolymers for hydrophilic modification of PPESK microporous membranes. Eur. Polym. J. 2007, 43, 1383−1393 doi: 10.1016/j.eurpolymj.2007.01.037
19. [19]
  Palaniappan, S. Benzoyl peroxide as a novel oxidizing agent in polyaniline dispersion: Synthesis and characterization of a pure polyaniline−poly(vinyl pyrrolidone) composite. J. Appl. Polym. Sci. 2008, 108, 825−832 doi: 10.1002/(ISSN)1097-4628
20. [20]
  Chakrabarty, B.; Ghoshal, A. K.; Purkait, A. K. Preparation, Characterization and performance studies of polysulfone membranes using PVP as an additive. J. Membr. Sci. 2008, 315, 36−47 doi: 10.1016/j.memsci.2008.02.027
21. [21]
  Han, M. J.; Nam, S. T. Thermodynamic and rheological variation in polysulfone solution by PVP and its effect in the preparation of phase inversion membrane. J. Membr. Sci. 2002, 202, 55−61 doi: 10.1016/S0376-7388(01)00718-9
22. [22]
  Smolders, C. A.; Reuvers, A. J.; Boom, R. M.; Wienk, I. M. Microstructures in phase inversion membranes. Part 1. Formation of macrovoids. J. Membr. Sci. 1992, 73, 259−275 doi: 10.1016/0376-7388(92)80134-6
23. [23]
  Liu, H. Y.; Zhang, G. Q.; Zhao, C. Q.; Liu, J. D.; Yang, F. L. Hydraulic power and electric field combined antifouling effect of a novel conductive poly(aminoanthraquinone)/reduced grapheme oxide nanohybrid blended PVDF ultrafiltration membrane. J. Mater. Chem. A 2015, 3, 20277−20287 doi: 10.1039/C5TA05306D
1. [1]
  Shunshun Jiang , Ji Zhang , Jing Wang , Shan-Tao Zhang . Excellent energy storage properties in non-stoichiometric Bi_0.5Na_0.5TiO₃-based relaxor ferroelectric ceramics. Chinese Chemical Letters, 2024, 35(7): 108955-. doi: 10.1016/j.cclet.2023.108955
2. [2]
  Bo Yang , Pu-An Lin , Tingwei Zhou , Xiaojia Zheng , Bing Cai , Wen-Hua Zhang . Facile surface regulation for highly efficient and thermally stable perovskite solar cells via chlormequat chloride. Chinese Chemical Letters, 2024, 35(10): 109425-. doi: 10.1016/j.cclet.2023.109425
3. [3]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
4. [4]
  Mei Peng , Wei-Min He . Photochemical synthesis and group transfer reactions of azoxy compounds. Chinese Chemical Letters, 2024, 35(8): 109899-. doi: 10.1016/j.cclet.2024.109899
5. [5]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
6. [6]
  Yixin Zhang , Ting Wang , Jixiang Zhang , Pengyu Lu , Neng Shi , Liqiang Zhang , Weiran Zhu , Nongyue He . Formation mechanism for stable system of nanoparticle/protein corona and phospholipid membrane. Chinese Chemical Letters, 2024, 35(4): 108619-. doi: 10.1016/j.cclet.2023.108619
7. [7]
  Xinzhi Ding , Chong Liu , Jing Niu , Nan Chen , Shutao Xu , Yingxu Wei , Zhongmin Liu . Solid-state NMR study of the stability of MOR framework aluminum. Chinese Journal of Structural Chemistry, 2024, 43(4): 100247-100247. doi: 10.1016/j.cjsc.2024.100247
8. [8]
  Jingyuan Yang , Xinyu Tian , Liuzhong Yuan , Yu Liu , Yue Wang , Chuandong Dou . Enhancing stability of diradical polycyclic hydrocarbons via P=O-attaching. Chinese Chemical Letters, 2024, 35(8): 109745-. doi: 10.1016/j.cclet.2024.109745
9. [9]
  Ting Wang , Xin Yu , Yaqiang Xie . Unlocking stability: Preserving activity of biomimetic catalysts with covalent organic framework cladding. Chinese Chemical Letters, 2024, 35(6): 109320-. doi: 10.1016/j.cclet.2023.109320
10. [10]
  Tao LIU , Yuting TIAN , Ke GAO , Xuwei HAN , Ru'nan MIN , Wenjing ZHAO , Xueyi SUN , Caixia YIN . A photothermal agent with high photothermal conversion efficiency and high stability for tumor therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1622-1632. doi: 10.11862/CJIC.20240107
11. [11]
  Ruizhi Yang , Xia Li , Weiping Guo , Zixuan Chen , Hongwei Ming , Zhong-Zhen Luo , Zhigang Zou . New thermoelectric semiconductors Pb5Sb12+xBi6-xSe32 with ultralow thermal conductivity. Chinese Journal of Structural Chemistry, 2024, 43(3): 100268-100268. doi: 10.1016/j.cjsc.2024.100268
12. [12]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
13. [13]
  Yuqing Wang , Zhemin Li , Qingjun Lu , Qizhao Li , Jiaxin Luo , Chengjie Li , Yongshu Xie . Solar cells based on doubly concerted companion dyes with the efficiencies modulated by inserting an ethynyl group at different positions. Chinese Chemical Letters, 2024, 35(5): 109093-. doi: 10.1016/j.cclet.2023.109093
14. [14]
  Run-Han Li , Tian-Yi Dang , Wei Guan , Jiang Liu , Ya-Qian Lan , Zhong-Min Su . Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters. Chinese Chemical Letters, 2024, 35(5): 108805-. doi: 10.1016/j.cclet.2023.108805
15. [15]
  Junchen Peng , Xue Yin , Dandan Dong , Zhongyuan Guo , Qinqin Wang , Minmin Liu , Fei He , Bin Dai , Chaofeng Huang . Promotion effect of epoxy group neighboring single-atom Cu site on acetylene hydrochlorination. Chinese Chemical Letters, 2024, 35(6): 109508-. doi: 10.1016/j.cclet.2024.109508
16. [16]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
17. [17]
  Wenyu Gao , Liming Zhang , Chuang Zhao , Lixiang Liu , Xingran Yang , Jinbo Zhao . Controlled semi-Pinacol rearrangement on a strained ring: Efficient access to multi-substituted cyclopropanes by group migration strategy. Chinese Chemical Letters, 2024, 35(9): 109447-. doi: 10.1016/j.cclet.2023.109447
18. [18]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
19. [19]
  Kexin Yuan , Yulei Liu , Haoran Feng , Yi Liu , Jun Cheng , Beiyang Luo , Qinglian Wu , Xinyu Zhang , Ying Wang , Xian Bao , Wanqian Guo , Jun Ma . Unlocking the potential of thin-film composite reverse osmosis membrane performance: Insights from mass transfer modeling. Chinese Chemical Letters, 2024, 35(5): 109022-. doi: 10.1016/j.cclet.2023.109022
20. [20]
  Yan Zou , Yin-Shuang Hu , Deng-Hui Tian , Hong Wu , Xiaoshu Lv , Guangming Jiang , Yu-Xi Huang . Tuning the membrane rejection behavior by surface wettability engineering for an effective water-in-oil emulsion separation. Chinese Chemical Letters, 2024, 35(6): 109090-. doi: 10.1016/j.cclet.2023.109090

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(626)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142