Citation: Li-Na Wang, Huan-Huan Zhang, Lin Xu, Bin-Yuan Liu, Tong-Fei Shi, Shi-Chun Jiang, Li-Jia An. Dewetting Kinetics of Thin Polymer Films with Different Architectures: Effect of Polymer Adsorption[J]. Chinese Journal of Polymer Science, ;2018, 36(8): 984-990. doi: 10.1007/s10118-018-2111-1 shu

Dewetting Kinetics of Thin Polymer Films with Different Architectures: Effect of Polymer Adsorption

Li-Na Wang ^1,2 ,
Huan-Huan Zhang ² ,
Lin Xu ^3,, ,
Bin-Yuan Liu ⁴ ,
Tong-Fei Shi ^2,, ,
Shi-Chun Jiang ^1,, ,
Li-Jia An ²

a.
School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
b.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
c.
Laboratory of Surface Physics and Chemistry, Guizhou Education University, Guiyang 550018, China
d.
Department of Polymer Science and Engineering, Hebei University of Technology, Tianjin 300130, China

Corresponding author: Lin Xu, lxu@gznc.edu.cn Tong-Fei Shi, tfshi@ciac.ac.cn Shi-Chun Jiang, scjiang@tju.edu.cn
Received Date: 31 October 2017
Accepted Date: 16 January 2018
Available Online: 13 April 2018

We have investigated the influence of the adsorption process on the dewetting behavior of the linear polystyrene film (LPS), the 3-arm star polystyrene film (3SPS) and the ring polystyrene film (RPS) on the silanized Si substrate. Results show that the adsorption process greatly influences the dewetting behavior of the thin polymer films. On the silanized Si substrate, the 3SPS chains exhibit stronger adsorption compared with the LPS chains and RPS chains; as a result, the wetting layer forms more easily. For LPS films, with the decrease of annealing temperature, the kinetics of polymer film changes from exponential behavior to slip dewetting. As a comparison, the stability of 3SPS and RPS films switches from slip dewetting to unusual dewetting kinetic behavior. The adsorbed nanodroplets on the solid substrate play an important role in the dewetting kinetics by reducing the driving force of dewetting and increase the resistant force of dewetting. Additionally, Brownian dynamics (BD) simulation shows that the absolute values of adsorption energy (ε) gradually increase from linear polymer (−0.3896) to ring polymer (−0.4033) and to star polymer (−0.4264), which is consistent with the results of our adsorption experiments.
- Thin polymer film,
- Star polystyrene,
- Ring polystyrene,
- Dewetting,
- Adsorption
1. [1]
  Cai, X.; Yuan, H.; Blencowe, A.; Qiao, G. G.; Genzer, J.; Spontak, R. J. Film-stabilizing attributes of polymeric core-shell nanoparticles. ACS Nano 2015, 9(8), 7940−7949 doi: 10.1021/acsnano.5b00237
2. [2]
  Roy, S.; Bandyopadhyay, D.; Karim, A.; Mukherjee, R. Interplay of substrate surface energy and nanoparticle concentration in suppressing polymer thin film dewetting. Macromolecules 2015, 48(2), 373−382 doi: 10.1021/ma501262x
3. [3]
  Luo, H.; Gersappe, D. Dewetting dynamics of nanofilled polymer thin films. Macromolecules 2004, 37(15), 5792−5799 doi: 10.1021/ma025691t
4. [4]
  Feng, Y.; Karim, A.; Weiss, R. A.; Douglas, J. F.; Han, C. C. Control of polystyrene film dewetting through sulfonation and metal complexation. Macromolecules 1998, 31(2), 484−493 doi: 10.1021/ma9706541
5. [5]
  Henn, G.; Bucknall, D. G.; Stamm, M.; Vanhoorne, P.; Jérôme, R. Chain end effects and dewetting in thin polymer films. Macromolecules 1996, 29(12), 4305−4313 doi: 10.1021/ma9500392
6. [6]
  Li, S. J.; Zhang, W. X.; Jiang, F.; Lu, Y. Y.; Shi, T. F.; An, L. J. Dynamics of hole growing in polymer thin films during dewetting. Acta Polymerica Sinica (in Chinese) 2014, 24(9), 1174−1182
7. [7]
  Wang, W. C.; Shi, K., Pan, Y. X.; Peng, C.; Zhao, Z. L.; Liu, W.; Liu, Y. G.; Ji, X. L. Fabrication of polymersomes with controllable morphologies through dewetting W/O/W double emulsion droplets. Chinese J. Polym. Sci. 2016, 34(4), 475−482 doi: 10.1007/s10118-016-1769-5
8. [8]
  Zhu, D. S.; Liu, Y. X.; Chen, E. Q.; Li, M.; Cheng, S. Z. D. Pseudo-dewetting behavior of low molecular weight poly(ethylene oxide) melts on mica surface. Acta Polymerica Sinica (in Chinese) 2006, (9), 1125−1128
9. [9]
  Mukherjee, R. Instability, self-organization and pattern formation in thin soft films. Soft Matter 2015, 11(45), 8717−8740 doi: 10.1039/C5SM01724F
10. [10]
  Roy, S.; Bandyopadhyay, D.; Karim, A.; Mukherjee, R. Interplay of substrate surface energy and nanoparticle concentration in suppressing polymer thin film dewetting. Macromolecules 2015, 48(2), 373−382 doi: 10.1021/ma501262x
11. [11]
  Mukherjee, R.; Das, S.; Das, A.; Sharma, S. K.; Raychaudhuri, A. K.; Sharma, A. Stability and dewetting of metal nanoparticle filled thin polymer films: control of instability length scale and dynamics. ACS Nano 2010, 4(7), 3709−3724 doi: 10.1021/nn901912d
12. [12]
  Xie, R.; Karim, A.; Douglas, J. F.; Han, C. C.; Weiss, R. A. Spinodal dewetting of thin polymer films. Phys. Rev. Lett. 1998, 81(6), 1251 doi: 10.1103/PhysRevLett.81.1251
13. [13]
  Gabriele, S.; Sclavons, S.; Reiter, G.; Damman, P. Disentanglement time of polymers determines the onset of rim instabilities in dewetting. Phys. Rev. Lett. 2006, 96(15), 156105 doi: 10.1103/PhysRevLett.96.156105
14. [14]
  Damman, P.; Gabriele, S.; Coppée, S.; Desprez, S.; Villers, D.; Vilmin, T.; Raphaël, E.; Hamieh, M.; Akhrass, S. A.; Reiter, G. Relaxation of residual stress and reentanglement of polymers in spin-coated films. Phys. Rev. Lett. 2007, 99(3), 036101 doi: 10.1103/PhysRevLett.99.036101
15. [15]
  de Silva, J. P.; Geoghegan, M.; Higgins, A. M.; Krausch, G.; David, M. O.; Reiter, G. Switching layer stability in a polymer bilayer by thickness variation. Phys. Rev. Lett. 2007, 98(26), 267802 doi: 10.1103/PhysRevLett.98.267802
16. [16]
  Reiter, G.; Hamieh, M.; Damman, P.; Sclavons, S.; Gabriele, S.; Vilmin, T.; Raphael, E. Residual stresses in thin polymer films cause rupture and dominate early stages of dewetting. Nat. Mater. 2005, 4(10), 754−758 doi: 10.1038/nmat1484
17. [17]
  Reiter, G. Dewetting of thin polymer films. Phys. Rev. Lett. 1992, 68(1), 75 doi: 10.1103/PhysRevLett.68.75
18. [18]
  Reiter, G. Unstable thin polymer films: rupture and dewetting processes. Langmuir 1993, 9(5), 1344−1351 doi: 10.1021/la00029a031
19. [19]
  Redon, C.; Brochard-Wyart, F.; Rondelez, F. Dynamics of dewetting. Phys. Rev. Lett. 1991, 66(6), 715 doi: 10.1103/PhysRevLett.66.715
20. [20]
  Masson, J.; Green, P. F. Hole formation in thin polymer films: a two-stage process. Phys. Rev. Lett. 2002, 88(20), 205504 doi: 10.1103/PhysRevLett.88.205504
21. [21]
  Brochard-Wyart, F.; Debrégeas, G.; Fondecave, R.; Martin, P. Dewetting of supported viscoelastic polymer films: birth of rims. Macromolecules 1997, 30(4), 1211−1213 doi: 10.1021/ma960929x
22. [22]
  Jacobs, K. Growth of holes in liquid films with partial slippage. Langmuir 1998, 14(18), 4961−4963 doi: 10.1021/la9804435
23. [23]
  Reiter, G.;Auroy, P.; Auvray, L. Instabilities of thin polymer films on layers of chemically identical grafted molecules. Macromolecules 1996, 29(6), 2150−2157 doi: 10.1021/ma950297z
24. [24]
  Jiang, N.; Cheung, J.; Guo, Y.; Endoh, M. K.; Koga, T.; Yuan, G.; Satija, S. K. Stability of adsorbed polystyrene nanolayers on silicon substrates. Macromol. Chem. Phys. 2017, 1700326 doi: 10.1002/macp.201700326
25. [25]
  Jiang, N.; Wang, J.; Di, X.; Cheung, J.; Zeng, W.; Endoh, M. K.; Satija, S. K. Nanoscale adsorbed structures as a robust approach for tailoring polymer film stability. Soft Matter 2016, 12(6), 1801−8109 doi: 10.1039/C5SM02435H
26. [26]
  Bal, J. K.;Beuvier, T.; Unni, A. B.; Chavez Panduro, E. A.; Vignaud, G.; Delorme, N.; Gibaud, A. Stability of polymer ultrathin films (< 7 nm) made by a top-down approach. ACS Nano 2015, 9(8), 8184−8193 doi: 10.1021/acsnano.5b02381
27. [27]
  Xu, L.; Yu, X. F.; Shi, T. F.; An, L. J. Investigation of the dewetting inhibition mechanism of thin polymer films. Soft Matter 2009, 5(10), 2109−2116 doi: 10.1039/b818824f
28. [28]
  Glynos, E.; Frieberg, B.; Green, P. F. Wetting of a multiarm star-shaped molecule. Phys. Rev. Lett. 2011, 107(11), 118303 doi: 10.1103/PhysRevLett.107.118303
29. [29]
  Glynos, E.; Chremos, A.; Frieberg, B.; Sakellariou, G.; Green, P. F. Wetting of macromolecules: from linear chain to soft colloid-like behavior. Macromolecules 2014, 47(3), 1137−1143 doi: 10.1021/ma4024119
30. [30]
  Granick, S.; Zhu, Y. X.; Lee, H. Slippery questions about complex fluids flowing past solids. Nat. Mater. 2003, 2(4), 221−227 doi: 10.1038/nmat854
31. [31]
  Zhu, Y.; Granick, S. Apparent slip of Newtonian fluids past adsorbed polymer layers. Macromolecules 2002, 35(12), 4658−4663 doi: 10.1021/ma020043v
32. [32]
  Lauga, E.; Brenner, M. P. Dynamic mechanisms for apparent slip on hydrophobic surfaces. Phys. Rev. E 2004, 70(2), 026311 doi: 10.1103/PhysRevE.70.026311
33. [33]
  Jenkel, E. Adsorption of high polymers from solution. Z. Elektrochem 1951, 55, 612−618
34. [34]
  Tan, H. Y.; Xu, D. H.; Wan, D.; Wang, Y. J.; Wang, L.; Zheng, J.; Liu, F.; Ma, L.; Tang, T. Melt viscosity behavior of C60 containing star polystyrene composites. Soft Matter 2013, 9(27), 6282−6290 doi: 10.1039/c3sm00103b
35. [35]
  Liu, B.; Wang, H.; Zhang, L.; Yang, G.; Liu, X.; Kim, I. A facile approach for the synthesis of cyclic poly(N-isopropylacrylamide) based on an anthracene-thiol click reaction. Polym. Chem. 2013, 4(8), 2428−2431 doi: 10.1039/c3py00184a
36. [36]
  Xu, L.; Sharma, A.; Joo, S. W. Substrate heterogeneity induced instability and slip in polymer thin films: dewetting on silanized surfaces with variable grafting density. Macromolecules 2010, 43(18), 7759−7762 doi: 10.1021/ma1010028
37. [37]
  Weeks, J. D.; Chandler, D.; Andersen, H. C. Role of repulsive forces in determining the equilibrium structure of simple liquids. J. Chem. Phys. 1971, 54(12), 5237−5247 doi: 10.1063/1.1674820
38. [38]
  Grest, G. S.; Kremer, K. Molecular dynamics simulation for polymers in the presence of a heat bath. Phys. Rev. A 1986, 33(5), 3628 doi: 10.1103/PhysRevA.33.3628
39. [39]
  Sides, S. W.; Grest, G. S.; Stevens, M. J. Large-scale simulation of adhesion dynamics for end-grafted polymers. Macromolecules 2002, 35(2), 566−573 doi: 10.1021/ma0114739
40. [40]
  Ermak, D.; McCammon, J. Brownian dynamics with hydrodynamic interactions. J. Chem. Phys. 1978, 69(4), 1352−1360 doi: 10.1063/1.436761
41. [41]
  Kosmas, M. K. Ideal polymer chains of various architectures at a surface. Macromolecules 1990, 23(7), 2061−2065 doi: 10.1021/ma00209a031
42. [42]
  Reiter, G.; Akhrass, S.; Hamieh, M.; Damman, P.; Gabriele, S.; Vilmin, T.; Raphaël, E. Dewetting as an investigative tool for studying properties of thin polymer films. Eur. Phys. J. Spec. Top. 2009, 166(1), 165−172 doi: 10.1140/epjst/e2009-00900-5
1. [1]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
2. [2]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
3. [3]
  Linshan Peng , Qihang Peng , Tianxiang Jin , Zhirong Liu , Yong Qian . Highly efficient capture of thorium ion by citric acid-modified chitosan gels from aqueous solution. Chinese Chemical Letters, 2024, 35(5): 108891-. doi: 10.1016/j.cclet.2023.108891
4. [4]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
5. [5]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
6. [6]
  Dan Luo , Jinya Tian , Jianqiao Zhou , Xiaodong Chi . Anthracene-bridged "Texas-sized" box for the simultaneous detection and uptake of tryptophan. Chinese Chemical Letters, 2024, 35(9): 109444-. doi: 10.1016/j.cclet.2023.109444
7. [7]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
8. [8]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
9. [9]
  Kexin Yuan , Yulei Liu , Haoran Feng , Yi Liu , Jun Cheng , Beiyang Luo , Qinglian Wu , Xinyu Zhang , Ying Wang , Xian Bao , Wanqian Guo , Jun Ma . Unlocking the potential of thin-film composite reverse osmosis membrane performance: Insights from mass transfer modeling. Chinese Chemical Letters, 2024, 35(5): 109022-. doi: 10.1016/j.cclet.2023.109022
10. [10]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
11. [11]
  Wenhao Chen , Muxuan Wu , Han Chen , Lue Mo , Yirong Zhu . Cu₂Se@C thin film with three-dimensional braided structure as a cathode material for enhanced Cu²⁺ storage. Chinese Chemical Letters, 2024, 35(5): 108698-. doi: 10.1016/j.cclet.2023.108698
12. [12]
  Zihao Wang , Jing Xue , Zhicui Song , Jianxiong Xing , Aijun Zhou , Jianmin Ma , Jingze Li . Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode. Chinese Chemical Letters, 2024, 35(10): 109489-. doi: 10.1016/j.cclet.2024.109489
13. [13]
  Cunjun Li , Wencong Liu , Xianlei Chen , Liang Li , Shenyu Lan , Mingshan Zhu . Adsorption and activation of peroxymonosulfate on BiOCl for carbamazepine degradation: The role of piezoelectric effect. Chinese Chemical Letters, 2024, 35(10): 109652-. doi: 10.1016/j.cclet.2024.109652
14. [14]
  Panke Zhou , Hong Yu , Mun Yin Chee , Tao Zeng , Tianli Jin , Hongling Yu , Shuo Wu , Wen Siang Lew , Xiong Chen . Electron push-pull effects induced performance promotion in covalent organic polymer thin films-based memristor for neuromorphic application. Chinese Chemical Letters, 2024, 35(5): 109279-. doi: 10.1016/j.cclet.2023.109279
15. [15]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
16. [16]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
17. [17]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
18. [18]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
19. [19]
  Yu-Hang Li , Shuai Gao , Lu Zhang , Hanchun Chen , Chong-Chen Wang , Haodong Ji . Insights on selective Pb adsorption via O 2p orbit in UiO-66 containing rich-zirconium vacancies. Chinese Chemical Letters, 2024, 35(8): 109894-. doi: 10.1016/j.cclet.2024.109894
20. [20]
  Yan Wang , Huixin Chen , Fuda Yu , Shanyue Wei , Jinhui Song , Qianfeng He , Yiming Xie , Miaoliang Huang , Canzhong Lu . Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(7): 109001-. doi: 10.1016/j.cclet.2023.109001

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(641)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142