Citation: Chun-Wei Zhuo, Yu-Sheng Qin, Xian-Hong Wang, Fo-Song Wang. Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide[J]. Chinese Journal of Polymer Science, ;2018, 36(2): 252-260. doi: 10.1007/s10118-018-2093-z shu

Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide

a.
Key Laboratory of Polymer Ecomaterial, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Science and Technology of China, Hefei 230026, China

Corresponding author: Yu-Sheng Qin, ysqin@ciac.ac.cn Xian-Hong Wang, xhwang@ciac.ac.cn
Received Date: 6 November 2017
Accepted Date: 15 November 2017
Available Online: 29 November 2017

Aluminum porphyrin complexes are heavy-metal-free and soil-tolerant green catalysts for the copolymerization of CO₂ and propylene oxide (PO), but they suffer from relatively poor poly(propylene carbonate) (PPC) selectivity. Herein, steric hindrance porphyrin ligand was used to enhance the PPC selectivity. Typically, a bulky anthracene-like group was incorporated into the porphyrin ring to form 5, 10, 15, 20-tetra(1, 2, 3, 4, 5, 6, 7, 8-octahydro-1, 4:5, 8-dimethanoanthracen-9-yl) porphyrin, the aluminum porphyrin complex with this ligand, in combination with bis(triphenylphosphine) iminium chloride as a co-catalyst, produced completely alternate PPC. Additionally, the obtained PPC showed high regioselectivity, with a head-to-tail linkage content (HT) of 92%. Therefore, we demonstrated that introduction of bulky steric ligand into the porphyrin ring could reduce the propylene oxide homopolymerization activity leading to excellent PPC selectivity, and improve regioselectivity for the PO ring-opening during the copolymerization.
- Carbon dioxide,
- Propylene oxide,
- Porphyrin,
- Aluminum,
- Steric hindrance
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沈阳化工大学材料科学与工程学院沈阳 110142

Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO2 and Propylene Oxide

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通讯作者: 陈斌, bchen63@163.com

Steric Hindrance Ligand Strategy to Aluminum Porphyrin Catalyst for Completely Alternative Copolymerization of CO₂ and Propylene Oxide