Citation: Petra Peer, Martina Polaskova, Pavol Suly. Rheology of Poly(vinyl butyral) Solution Containing Fumed Silica in Correlation with Electrospinning[J]. Chinese Journal of Polymer Science, ;2018, 36(6): 742-748. doi: 10.1007/s10118-018-2077-z shu

Rheology of Poly(vinyl butyral) Solution Containing Fumed Silica in Correlation with Electrospinning

a.
Institute of Hydrodynamics of the Czech Academy of Sciences, Pod Patankou 5, 166 12 Prague 6, Czech Republic
b.
Centre of Polymer Systems, Tomas Bata University in Zlín, trida Tomase Bati 5678, 760 01 Zlín, Czech Republic
c.
Department of Polymer Engineering, Faculty of Technology, Tomas Bata University in Zlín, Vavreckova 275, 760 01 Zlín, Czech Republic

Corresponding author: Petra Peer, peer@ih.cas.cz
Received Date: 28 August 2017
Accepted Date: 24 October 2017
Available Online: 6 February 2018

The rheological properties in question are influenced by many factors, ranging from the characteristics of the given polymer or solvent to the flowing conditions. The primary focus of this study is to analyse the rheological behaviour of poly(vinyl butyral)-Mowital B 60H-(PVB) solutions dissolved in methanol and a blend of these with fumed silica nanoparticles. The preparation of the nanofibrous web and the quality of nanofibres were correlated with the rheology of the polymer solution. It was discerned that drastically intensifying shear viscosity and the elasticity of the solution exerted a negligible effect on the formation of fibres, a finding which has rarely been discussed in the literature. The morphologies and structures of the PVB/silica nanofibrous membranes were investigated by scanning electron microscopy, thermogravimetric analysis and Fourier transform infrared spectroscopy.
- Electrospinning,
- Nanofibres,
- Poly (vinyl butyral),
- Fumed silica,
- Rheology
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1.
沈阳化工大学材料科学与工程学院沈阳 110142