Citation: Wei Song, Yang You, Tian-Jing Li, Juan Li, Liang Ding. Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis (ADMET) Polymerization[J]. Chinese Journal of Polymer Science, ;2018, 36(6): 703-711. doi: 10.1007/s10118-018-2067-1 shu

Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis (ADMET) Polymerization

Wei Song ^a,, ,
Yang You ^a ,
Tian-Jing Li ^c ,
Juan Li ^a ,
Liang Ding ^a,b,,

a.
Department of Polymer and Composite Material, School of Materials Engineering, Yancheng Institute of Technology, Yancheng 224051, China
b.
Roy & Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia 19104-6323, PA, USA
c.
School of Automotive Engineering, Yancheng Vocational Institute of Industry Technology, Yancheng 224005, China

Corresponding author: Wei Song, sw121092@ycit.cn Liang Ding, dl1984911@ycit.edu.cn
Received Date: 16 September 2017
Accepted Date: 17 October 2017
Available Online: 13 February 2018

A novel perylene tetracarboxylic acid bisimide (PTCBI) in-chain polyethylene (PE) was first prepared via acyclic diene metathesis (ADMET) polymerization of PTCBI-functionalized α, ω-diene monomer. The polymers could spontaneously self-assemble into hollow cylindrical structures in which the π-π interaction between adjacent PTCBI moieties was enhanced and the electron mobility was possibly promoted. The hydrogenation of as-obtained polymer was readily accomplished, affording the desired precision PTCBI in-chain PE with a saturated backbone, which showed high glass transition temperature (T_g=63℃), relatively wide range of light absorption (λ=200-575 nm), and higher LUMO level (-3.62 eV). It can therefore serve as a superior model for facile construction of functional polyolefin and soluble PTCBI polymer with ordered architecture.
- Acyclic diene metathesis polymerization,
- Hydrogenation,
- Polyethylene,
- Perylene bisimide
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