Citation: Gui-Qiu Ma, Guan-Kai Sun, Zhe Ma, Jing-Qing Li, Jing Sheng. In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene[J]. Chinese Journal of Polymer Science, ;2018, 36(8): 979-983. doi: 10.1007/s10118-018-2023-0 shu

In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene

Department of Polymer Material Science and Engineering, Institute of Advanced Polymer Materials, School of Material Science and Engineering, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300350, China

Corresponding author: Gui-Qiu Ma, magq@tju.edu.cn
Received Date: 9 November 2017
Accepted Date: 9 December 2017
Available Online: 6 March 2018

Pentaerythritol triacrylate (PETA) was successfully grafted onto the plasma-treated isotactic polypropylene (iPP) via the in situ melt processing. The X-ray photoelectron spectroscopy (XPS) results showed that the hydroxyl and carbonyl groups, and peroxides could be generated via plasma treatment. The content of free radical in plasma-treated iPP (PiPP) was measured by 2,2-diphenyl-1-picrylhydrazyl (DPPH). It was found that the resulting peroxides induced the grafting copolymerization of PETA onto iPP, and the grafted PETA promoted the formation of β-crystal in PiPP, which was evidenced by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD) measurements, respectively.
- Plasma treatment,
- Melt processing,
- Graft copolymerization,
- Pentaerythritol triacrylate
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