Citation: Li Zhou, Zhi-qiang Jiang, Na Xu, Na Liu, Zong-quan Wu. Polythiophene-block-poly(phenyl isocyanide) Copolymers:One-pot Synthesis, Properties and Applications[J]. Chinese Journal of Polymer Science, ;2017, 35(12): 1447-1456. doi: 10.1007/s10118-017-2003-9 shu

Polythiophene-block-poly(phenyl isocyanide) Copolymers:One-pot Synthesis, Properties and Applications

Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, and Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, Hefei University of Technology, Hefei 230009, China

Corresponding author: Na Liu, liuna@hfut.edu.cn Zong-quan Wu, zqwu@hfut.edu.cn
Received Date: 14 July 2017
Revised Date: 9 August 2017
Accepted Date: 17 August 2017

Fund Project: the National Natural Science Foundation of China 51673057the National Natural Science Foundation of China 21622402the National Natural Science Foundation of China 21574036

Conjugated block copolymers have gained increasing interests in recent years. Development of a novel method for facile synthesis of conjugated block copolymers with desired structures and functions is greatly desired. In this mini review, we summarized the recent advances in one-pot synthesis of conjugated block copolymers containing π-conjugated polythiophene and helical polyisocyanide segments by using a nickel(Ⅱ) complex as single catalyst. The sequential living polymerization of the two monomers proceeded in a controlled manner, affording expected block copolymers in high yields with controlled molecular weights (M_ns) and narrow molecular weight distributions (M_w/M_ns). By using this method, a family of block copolymers with expected structure and tunable compositions can be facilely prepared. Introducing functional groups onto the pendant, these block copolymers can exhibit interesting self-assembly property, tunable light emission and multi-responsiveness.
- Conjugated polymer,
- Helical polymer,
- Polyisocyanide,
- Block copolymer,
- Living polymerization
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