Citation: Houluo Cong, Sen Xu, Sixun Zheng. Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains[J]. Chinese Journal of Polymer Science, ;2017, 35(12): 1572-1586. doi: 10.1007/s10118-017-2001-y shu

Synthesis and Microphase Separation Behavior of Random, Mixed Cylindrical Brush Copolymers Bearing Polystyrene and Poly(ε-caprolactone) Side Chains

Department of Polymer Science and Engineering and the State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Sixun Zheng, szheng@sjtu.edu.cn
Received Date: 16 May 2017
Revised Date: 25 June 2017
Accepted Date: 28 June 2017

Fund Project: the Shanghai Synchrotron Radiation Facility under the projects 10sr0126the National Natural Science Foundation of China 21774078the National Natural Science Foundation of China 21274091the Shanghai Synchrotron Radiation Facility under the projects 10sr0260the National Natural Science Foundation of China 51133003

A series of mixed, random cylindrical brush copolymers bearing polystyrene (PS) and poly(ε-caprolactone) (PCL) side chains were synthesized via the combination of ring-opening polymerization (ROP) and atom transfer radical polymerization (ATRP). These novel cylindrical brush copolymers have been characterized by means of nuclear magnetic resonance (NMR) spectroscopy, gel permeation chromatography (GPC) and differential scanning calorimetry (DSC). It was found that the mikto-armed cylindrical brush copolymers were microphase-separated in bulks and that the morphologies were dependent on the mass ratios of PS to PCL side chains. One of the cylindrical brush copolymers was employed to incorporate into epoxy thermoset to investigate effect of the mikto-armed cylindrical brush architecture on the reaction-induced microphase separation behavior. Depending on the concentration of the cylindrical brush in epoxy, the thermosets can display the morphologies with the spherical, worm-like and lamellar PS microdomains dispersing in continuous thermosetting matrices.
- Cylindrical brush copolymers,
- Block copolymer,
- Epoxy,
- Reaction-induced microphase separation
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