Citation: Wei Zhu, Zhou Tian, Rui-hua Cheng, Xue-lian He, Zhen Liu, Ning Zhao, Bo-ping Liu. Exploring Si/Mg Composite Supported Ziegler-Natta Ti-based Catalysts for Propylene Polymerization[J]. Chinese Journal of Polymer Science, ;2017, 35(12): 1474-1487. doi: 10.1007/s10118-017-1999-1 shu

Exploring Si/Mg Composite Supported Ziegler-Natta Ti-based Catalysts for Propylene Polymerization

Wei Zhu ^a ,
Zhou Tian ^b,, ,
Rui-hua Cheng ^a ,
Xue-lian He ^a ,
Zhen Liu ^a ,
Ning Zhao ^a ,
Bo-ping Liu ^a,,

a.
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
b.
Key Laboratory of Advanced Control and Optimization for Chemical Processes, Ministry of Education, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: Zhou Tian, tianzhou@ecust.edu.cn Bo-ping Liu, boping@ecust.edu.cn
Received Date: 22 April 2017
Revised Date: 22 June 2017
Accepted Date: 23 June 2017

Fund Project: the National Natural Science Foundation of China 21406061the National Natural Science Foundation of China 21674036the Major State Basic Research Development Program of China 2014CB239503

A series of (SiO₂/MgO/ID/MgCl₂)·TiCl_x Ziegler-Natta catalysts for propylene polymerization has been prepared with a new method. These catalysts were synthesized using soluble Mg-compounds as the Mg-source and the preparation progress was relatively simple. The catalyst could copy the spherical shape of the carrier very well. The propylene polymerization results showed that the catalyst revealed the best activity with 9, 9-di(methoxymethyl)fluorene (BMMF) as internal donor at 50 ℃ with the optimal molar ratio Al/Ti=5, which was much lower than what the industrial polypropylene catalyst used (at least molar ratio Al/Ti=100), resulting in great cost saving. Additionally, the polymerization kinetics of the catalyst exhibited very stable property after achieving a relatively high value. These catalysts possessed rather high activity and good hydrogen response. The isotactic index (Ⅱ) value of the PP products could be higher than 98% in the presence of both internal and external electron donors. Moreover, temperature rising elution fractionation method was used to understand the influence of donors and H₂ on the properties of the PP products.
- Polypropylene,
- Ziegler-Natta catalyst,
- External donor,
- Internal donor,
- Kinetic curves
1. [1]
  Klapper, M., Joe, D., Nietzel, S., Krumpfer, J.W. and Muellen, K., Chem. Mater., 2014, 26:802 doi: 10.1021/cm402309z
2. [2]
  Gahleitner, M., Resconi, L. and Doshev, P., MRS Bulletin, 2013, 38:229 doi: 10.1557/mrs.2013.47
3. [3]
  Pater, J.T.M., Weickert, G., and Swaaij, W.P.M., Chem. Eng. Sci., 2002, 57:3461 doi: 10.1016/S0009-2509(02)00213-0
4. [4]
  Kim, K.S., Lee, Y.J., Kim, H.Y., Kang, S.S. and Kwon, S.Y., Org. & Biomol. Chem., 2004, 2:2408
5. [5]
  Morini, G., Balbontin, G., Baruzzi, G. and Cristofori, A. B., 2006, U. S. Pat., 7, 049, 377
6. [6]
  Potapov, A. and Politanskaya, L., J. Mol. Catal. A:Chem., 2013, 368:159
7. [7]
  Song, B.G. and Ihm, S.K., J. Appl. Polym. Sci., 2014:131
8. [8]
  Morini, G., Gulevich, Y. ; Kelder, R., Duijghuisen, H. K. P. and Korndorffer, F., 2006, Eur. Pat. 1, 088, 009
9. [9]
  Tanase, S., Katayama, K., Yabunouchi, N., Sadashima, T., Tomotsu, N. and Ishihara, N., J. Mol. Catal. A:Chem., 2007, 273:211 doi: 10.1016/j.molcata.2007.04.002
10. [10]
  Morini, G. and Giotto, V., 2000, WO 055, 215
11. [11]
  Xu, D., Wang, J., Liu, Z., Ke, Y. and Hu, Y., Macromol. Chem. Phys., 2001, 202:1817 doi: 10.1002/(ISSN)1521-3935
12. [12]
  Zahedi, R., Taromi, F.A., Mirjahanmardi, S.H., Haghighi, M.N., Jadidi, K. and Jamjah, R., Chinese J. Polym. Sci., 2016, 34:268 doi: 10.1007/s10118-016-1751-2
13. [13]
  Potapov, A., Bukatov, G. and Zakharov, V., J. Mol. Catal. A:Chem., 2009, 301:18 doi: 10.1016/j.molcata.2008.11.002
14. [14]
  Böhm, L.L., Angew. Chem. Int. Ed., 2003, 42:5010 doi: 10.1002/(ISSN)1521-3773
15. [15]
  Kimura, K. Terano, M., and Soga, H., 1988, Eur. Pat. 268, 685
16. [16]
  Kimura, K. Terano, M., Murai, A., Inoue, M. and Miyoshi, K., 1987, JP Pat., S62, 158, 704
17. [17]
  Udoo, H. T. Y. and Kurausuudeiitaa, K., 1994, JP Pat., 6, 087, 773
18. [18]
  Wang, J.W., Cheng, R.H., He, X.L., Liu, Z., Tian, Z. and Liu, B.P, Macromol. Chem. Phys., 2015, 216:1472 doi: 10.1002/macp.v216.13
19. [19]
  Wang, J.W., Cheng, R.H., He, X.L., Liu, Z. and Liu, B.P, J. Organomet. Chem., 2015, 798:299 doi: 10.1016/j.jorganchem.2015.09.012
20. [20]
  Huang, F., Wang, J.W., Cheng, R.H., He, X.L., Liu, Z., Zhao, N. and Liu, B.P., Macromol. React. Eng., 2016, 10:10
21. [21]
  Wang, J.W., Cheng, R.H., He, X.L., Liu, Z. and Liu, B.P, Macromol. React. Eng., 2016, 10:246 doi: 10.1002/mren.201500056
22. [22]
  Cheng, R.H., Luo, J., Liu, Z., Sun, J.W., Huang, W.H., Zhang, M.G., Yi, J.J. and Liu, B.P., Chinese J. Polym. Sci., 2013, 31:591 doi: 10.1007/s10118-013-1252-5
23. [23]
  Terano, M., Kataoka, T. and Keii, T., Makromol. Chem., 1987, 188:1477 doi: 10.1002/macp.1987.021880622
24. [24]
  Mori, H., Hasebe, K. and Terano, M., J. Mol. Catal. A:Chem., 1999, 140:165 doi: 10.1016/S1381-1169(98)00225-8
25. [25]
  Correa, A., Piemontesi, F., Morini, G. and Cavallo, L., Macromolecules, 2007, 40:9181 doi: 10.1021/ma071294c
26. [26]
  Correa, A., Credendino, R., Pater, J.T.M., Morini, G. and Cavallo, L., Macromolecules, 2012, 45:3695 doi: 10.1021/ma3001862
27. [27]
  Taniike, T. and Terano, M., J. Catal., 2012, 293:39 doi: 10.1016/j.jcat.2012.06.001
28. [28]
  Credendino, R., Liguori, D., Morini, G. and Cavallo, L., J. Phys. Chem., 2014, 118:8050 doi: 10.1021/jp406540p
29. [29]
  Hu, J., Han, B., Shen, X.R., Fu, Z.S. and Fan, Z.Q., Chinese J. Polym. Sci., 2013, 31:583 doi: 10.1007/s10118-013-1260-5
30. [30]
  Abedi, S., Daftari-Besheli, M. and Shafiei, S., J. Appl. Polym. Sci., 2005, 97:1744 doi: 10.1002/(ISSN)1097-4628
31. [31]
  Andoni, A., Chadwick, J.C., Niemantsverdriet, H.J.W. and Thüne, P.C., Macromol. Rapid Commun., 2007, 28:1437 doi: 10.1002/(ISSN)1521-3927
32. [32]
  Shen, X.R., Fu, Z.S., Hu, J., Wang, Q. and Fan, Z.Q., J. Phys. Chem. C, 2013, 117:15174 doi: 10.1021/jp404416n
33. [33]
  Stukalov, D.V., Zakharov, V.A., Potapov, A.G. and Bukatov, G.D., J. Catal., 2009:266:39
34. [34]
  Zhang, B., Dong, Q., Fu, Z.S. and Fan, Z.Q., Polymer, 2014, 55:4865 doi: 10.1016/j.polymer.2014.08.019
35. [35]
  Zhang, B., Zhang, L., Fu, Z.S. and Fan, Z.Q., Catal. Commun., 2015, 69:147 doi: 10.1016/j.catcom.2015.06.011
36. [36]
  Chadwick, J.C., van Kessel, G.M.M. and Sudmeijer, O., Macromol. Chem. Phys., 1995, 196:1431 doi: 10.1002/macp.1995.021960506
37. [37]
  Chadwick, J. C., van der Burgt, F.P.T.J., Rastogi, S., Busico, V., Cipullo, R., Talarico, G. and Heere, J.J.R., Macromolecules, 2004, 37:9722 doi: 10.1021/ma048108c
38. [38]
  Chadwick, J.C., Morini, G., Albizzati, E., Balbontin, G., Mingozzi, I., Cristofori, A., Sudmeijer, O. and van Kessel, G.M.M, Macromol. Chem. Phys., 1996, 197:2501 doi: 10.1002/macp.1996.021970814
39. [39]
  Busico, V., Cipullo, R. and Corradini, P., Makromol. Chem. Rapid Commun., 1992, 13:15 doi: 10.1002/marc.1992.030130103
40. [40]
  Forte, M.C. and Coutinho, F.M.M., Eur. Polym. J., 1996, 32:605 doi: 10.1016/0014-3057(95)00176-X
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