Citation: Jia-min Cao, Liu Qian, Dan He, Zuo Xiao, Li-ming Ding. D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3, 3'-Difluoro-2, 2'-bithiophene for Solar Cells[J]. Chinese Journal of Polymer Science, ;2017, 35(12): 1457-1462. doi: 10.1007/s10118-017-1996-4 shu

D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3, 3'-Difluoro-2, 2'-bithiophene for Solar Cells

Center for Excellence in Nanoscience(Chinese Academy of Sciences), Key Laboratory of Nanosystem and Hierarchical Fabrication(Chinese Academy of Sciences), National Center for Nanoscience and Technology, Beijing 100190, China

Corresponding author: Li-ming Ding, ding@nanoctr.cn

^†

Received Date: 3 May 2017
Revised Date: 12 June 2017
Accepted Date: 16 June 2017

Fund Project: the National Natural Science Foundation of China 21572041the National Natural Science Foundation of China 21372053the National Natural Science Foundation of China 21374025State Key Laboratory of Luminescent Materials and Devices 2016-skllmd-05the National Natural Science Foundation of China 51503050the National Natural Science Foundation of China U1401244

A D-A copolymer, P2FBTTPTI, was developed by copolymerizing a pentacyclic acceptor unit, thieno[2', 3':5, 6]pyrido[3, 4-g]thieno[3, 2-c]isoquinoline-5, 11(4H, 10H)-dione (TPTI), with 3, 3'-difluoro-2, 2'-bithiophene (2FBT). P2FBTTPTI possessed a low highest occupied molecular orbital (HOMO) energy level (-5.50 eV) and a good hole mobility (4.14×10^-4 cm²·V^-1·s^-1). P2FBTTPTI:PC₇₁BM solar cells gave a decent power conversion efficiency (PCE) of 7.64% and a high open-circuit voltage (V_oc) of 0.95 V.
- D-A copolymers,
- Fluorination,
- Open-circuit voltage,
- Polymer solar cells
1. [1]
  Zhao, W., Li, S., Zhang, S., Liu, X. and Hou, J., Adv. Mater., 2016, DOI:10.1002/adma.201604059 doi: 10.1002/adma.201604059
2. [2]
  Zhao, F., Dai, S., Wu, Y., Zhang, Q., Wang, J., Jiang, L., Ling, Q., Wei, Z., Ma, W., You, W., Wang, C. and Zhan, X., Adv. Mater., 2017, DOI:10.1002/adma.201700144 doi: 10.1002/adma.201700144
3. [3]
  Wu, J.S., Cheng, S.W., Cheng, Y.J. and Hsu, C.S., Chem. Soc. Rev., 2015, 44:1113 doi: 10.1039/C4CS00250D
4. [4]
  Guo, X., Facchetti, A. and Marks, T.J., Chem. Rev., 2014, 114:8943 doi: 10.1021/cr500225d
5. [5]
  Chen, H.Y., Hou, J., Zhang, S., Liang, Y., Yang, G., Yang, Y., Yu, L., Wu, Y. and Li, G., Nat. Photon., 2009, 3:649 doi: 10.1038/nphoton.2009.192
6. [6]
  6 Price, S.C., Stuart, A.C., Yang, L., Zhou, H. and You, W., J. Am. Chem. Soc., 2011, 133:4625 doi: 10.1021/ja1112595
7. [7]
  Carsten, B., Szarko, J.M., Son, H.J., Wang, W., Lu, L., He, F., Rolczynski, B.S., Lou, S.J., Chen, L.X. and Yu, L., J. Am. Chem. Soc., 2011, 133:20468 doi: 10.1021/ja208642b
8. [8]
  Jo, J.W., Jung, J.W., Wang, H.W., Kim, P., Russell, T.P. and Jo, W.H., Chem. Mater., 2014, 26:4214 doi: 10.1021/cm502229k
9. [9]
  Liu, Y., Zhao, J., Li, Z., Mu, C., Ma, W., Hu, H., Jiang, K., Lin, H., Ade, H. and Yan, H., Nat. Commun., 2014, 5:5293 doi: 10.1038/ncomms6293
10. [10]
  Zhang, S., Qin, Y., Uddin, M.A., Jang, B., Zhao, W., Liu, D., Woo, H.Y. and Hou, J., Macromolecules, 2016, 49:2993 doi: 10.1021/acs.macromol.6b00248
11. [11]
  11 Fan, Q., Su, W., Guo, X., Guo, B., Li, W., Zhang, Y., Wang, K., Zhang, M. and Li, Y., Adv. Energy Mater., 2016, 6:1600430 doi: 10.1002/aenm.201600430
12. [12]
  Jiao, N., He, D., Qian, L., Lei, Z. and Ding, L., Sci. China Chem., 2017, 60:251 doi: 10.1007/s11426-016-0244-3
13. [13]
  Cao, J., Liao, Q., Du, X., Chen, J., Xiao, Z., Zuo, Q. and Ding, L., Energy Environ. Sci., 2013, 6:3224 doi: 10.1039/c3ee41948g
14. [14]
  Li, H., Cao, J., Zhou, Q., Ding, L. and Wang, J., Nano Energy, 2015, 15:125 doi: 10.1016/j.nanoen.2015.04.016
15. [15]
  Zuo, C., Cao, J. and Ding, L., Macromol. Rapid Commun., 2014, 35:1362 doi: 10.1002/marc.v35.15
16. [16]
  Cao, J., Qian, L., Lu, F., Zhang, J., Feng, Y., Qiu, X., Yip, H.L. and Ding, L., Chem. Commun., 2015, 51:11830 doi: 10.1039/C5CC03620H
17. [17]
  Li, H., He, D., Mao, P., Wei, Y., Ding, L. and Wang, J., Adv. Energy Mater., 2017, DOI:10.1002/aenm.201602663 doi: 10.1002/aenm.201602663
18. [18]
  18 Du, X., Lytken, O., Killian, M.S., Cao, J., Stubhan, T., Turbiez, M., Schmuki, P., Steinrück, H.P., Ding, L., Fink, R.H., Li, N. and Brabec, C.J., Adv. Energy Mater., 2017, 7:1601959 doi: 10.1002/aenm.201601959
19. [19]
  Zhang, K., Gao, K., Xia, R., Wu, Z., Sun, C., Cao, J., Qian, L., Li, W., Liu, S., Huang, F., Peng, X., Ding, L., Yip, H.L. and Cao, Y., Adv. Mater., 2016, 28:4817 doi: 10.1002/adma.v28.24
20. [20]
  Cao, J., Zuo, C., Du, B., Qiu, X. and Ding, L., Chem. Commun., 2015, 51:12122 doi: 10.1039/C5CC04375A
21. [21]
  Qian, L., Cao, J. and Ding, L., J. Mater. Chem. A, 2015, 3:24211 doi: 10.1039/C5TA07942J
22. [22]
  Cao, J., Qian, L. and Ding, L., Polym. Chem., 2016, 7:1027 doi: 10.1039/C5PY01761K
23. [23]
  Sun, Y., Seo, J.H., Takacs, C.J., Seifter, J. and Heeger, A.J., Adv. Mater., 2011, 23:1679 doi: 10.1002/adma.201004301
24. [24]
  Xu, X., Zhang, G., Zhao, Y., Liu, J., Li, Y. and Peng, Q., Chinese J. Polym. Sci., 2017, 35(2):249 doi: 10.1007/s10118-017-1877-x
25. [25]
  Islam, A., Liu, Z., Peng, R., Jiang, W., Lei, T., Li, W., Zhang, L., Yang, R., Guan, Q. and Ge, Z., Chinese J. Polym. Sci., 2017, 35(2):171 doi: 10.1007/s10118-017-1886-9
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