Citation: Qi Chen, Min Zuo, Yi-hu Song, Qiang Zheng. Molecular Dynamics and Phase Behavior of Polystyrene/Poly(vinyl methyl ether) Blend in the Presence of Nanosilica[J]. Chinese Journal of Polymer Science, ;2017, 35(12): 1524-1539. doi: 10.1007/s10118-017-1980-z shu

Molecular Dynamics and Phase Behavior of Polystyrene/Poly(vinyl methyl ether) Blend in the Presence of Nanosilica

Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Min Zuo, kezuomin@zju.edu.cn
Received Date: 20 March 2017
Revised Date: 30 April 2017
Accepted Date: 17 May 2017

Fund Project: Zhejiang Natural Science Foundation LY16E030001the Fundamental Research Funds for the Central Universities 2017QNA4038the National Natural Science Foundation of China 51273173

The variation of phase morphology, critical temperature of demixing, and molecular dynamics for polystyrene/poly(vinyl methyl ether) (PS/PVME) blends induced by hydrophilic nanosilica (A200) or hydrophobic nanosilica (R974) was investigated. With the phase separation of blend matrix, A200 migrated into PVME-rich phase due to strong interaction between A200 and PVME, while R974 moved into PS-rich phase. The thermodynamic miscibility and concentration fluctuation during phase separation of blend matrix were remarkably retarded by A200 nanoparticles due to the surface adsorption of PVME on A200, verified by the correlation length ξ near the critical region from rheological measurement and the weakened increment of reversing heat capacity (ΔC_p) during glass transition via modulated differential scanning calorimetry (MDSC). The restricted chain diffusion induced by nanosilica still occurred despite no influence of A200 and R974 on the segmental dynamics of homogenous blend matrix. The interactions between nanosilica and polymer components could restrict the terminal relaxation of blend matrix and further manipulate their phase behavior.
- Phase separation,
- Nanoparticles,
- Rheology,
- Molecular dynamics
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