Citation: De-sheng Li, Jing-fa Yang, Jiang Zhao. Detection of Site-dependent Segmental Mobility of Polymer by Fluorescent Defocused Imaging[J]. Chinese Journal of Polymer Science, ;2017, 35(12): 1488-1496. doi: 10.1007/s10118-017-1976-8 shu

Detection of Site-dependent Segmental Mobility of Polymer by Fluorescent Defocused Imaging

De-sheng Li ^a,b ,
Jing-fa Yang ^a,b ,
Jiang Zhao ^a,b,,

a.
Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
The University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Jiang Zhao, jzhao@iccas.ac.cn
Received Date: 8 April 2017
Revised Date: 9 May 2017
Accepted Date: 10 May 2017

Fund Project: National Basic Research Program of China 2014CB643601

Polymer chain ends play an important role in the glassy dynamics of polymeric materials. In this study, a combination of single molecule defocus fluorescence microscopy and well-controlled atom transfer radical polymerization was used to investigate site-dependent segmental mobility of poly(n-butyl methacrylate). As the temperature increased, the rotation of fluorophores, which were selectively labelled in chain end and chain middle, was gradually activated. The power spectra of rotation trajectories, the distribution of angular displacement as well as the population of rotating fluorophores demonstrated that the local dynamics was more activated at the chain ends than the middles, showing the unique contribution of the chain end to the dynamics of the system.
- Glass transition,
- Segmental mobility,
- Chain end effect,
- Fluorescent defocused imaging
1. [1]
  Xia, Y., Li, Y., Burts, A.O., Ottaviani, M.F., Tirrell, D.A., Johnson, J.A., Turro, N.J. and Grubbs, R.H., J. Am. Chem. Soc., 2011, 133(49):19953 doi: 10.1021/ja2085349
2. [2]
  Das, S., Dubsky, P., van den Berg, A. and Eijkel, J.C.T., Phys. Rev. Lett., 2012, 108(13):138101 doi: 10.1103/PhysRevLett.108.138101
3. [3]
  Luo, K., Ala-Nissila, T. and Ying, S.C., J. Chem. Phys., 2006, 124(3):034714 doi: 10.1063/1.2161189
4. [4]
  Kong, C.Y. and Muthukumar, M., J. Chem. Phys., 2004, 120(7):3460 doi: 10.1063/1.1642588
5. [5]
  Kumar, R. and Muthukumar, M., J. Chem. Phys., 2009, 131(19):194903 doi: 10.1063/1.3264632
6. [6]
  Gennes, P.G.D., J. Chem. Phys., 1971, 55(2):572 doi: 10.1063/1.1675789
7. [7]
  Ye, S., Tang, Q., Yang, J., Zhang, K. and Zhao, J., Soft Matter, 2016, 12(47):9520 doi: 10.1039/C6SM02103D
8. [8]
  Ediger, M.D., Annu. Rev. Phys. Chem., 2000, 51:99 doi: 10.1146/annurev.physchem.51.1.99
9. [9]
  Paeng, K. and Kaufman, L.J., Chem. Soc. Rev., 2014, 43(4):977 doi: 10.1039/C3CS60186B
10. [10]
  Berthier, L. and Biroli, G., Rev. Mod. Phys., 2011, 83(2):587 doi: 10.1103/RevModPhys.83.587
11. [11]
  Fox, J.T.G. and Flory, P.J., J. Appl. Phys., 1950, 21(6):581 doi: 10.1063/1.1699711
12. [12]
  Angell, C.A., J. Phys. Chem. Solids, 1988, 49(8):863 doi: 10.1016/0022-3697(88)90002-9
13. [13]
  Robertson, C.G. and Roland, C.M., J. Polym. Sci., Part B:Polym. Phys., 2004, 42(13):2604 doi: 10.1002/(ISSN)1099-0488
14. [14]
  Tanaka, K., Jiang, X.Q., Nakamura, K., Takahara, A., Kajiyama, T., Ishizone, T., Hirao, A. and Nakahama, S., Macromolecules, 1998, 31(15):5148 doi: 10.1021/ma9712561
15. [15]
  Ellison, C.J., Mundra, M.K. and Torkelson, J.M., Macromolecules, 2005, 38(5):1767 doi: 10.1021/ma047846y
16. [16]
  Satomi, N., Tanaka, K., Takahara, A., Kajiyama, T., Ishizone, T. and Nakahama, S., Macromolecules, 2001, 34(25):8761 doi: 10.1021/ma010126w
17. [17]
  Xie, F., Zhang, H.F., Lee, F.K., Du, B., Tsui, O.K.C., Yokoe, Y., Tanaka, K., Takahara, A., Kajiyama, T. and He, T., Macromolecules, 2002, 35(5):1491 doi: 10.1021/ma011689a
18. [18]
  Zhang, L. and Torkelson, J.M., Polymer, 2015, 65:105 doi: 10.1016/j.polymer.2015.03.056
19. [19]
  Miwa, Y., Shimada, S., Urakawa, O. and Nobukawa, S., Macromolecules, 2010, 43(17):7192 doi: 10.1021/ma1013644
20. [20]
  Miwa, Y., Yamamoto, K., Sakaguchi, M., Sakai, M., Makita, S. and Shimada, S., Macromolecules, 2005, 38(3):832 doi: 10.1021/ma048287y
21. [21]
  Plaza-García, S., Lund, R., Alegría, A., Colmenero, J., Janoski, J. and Quirk, R.P., Macromolecules, 2011, 44(19):7810 doi: 10.1021/ma2014436
22. [22]
  Simpson, A.J., McNally, D.J. and Simpson, M.J., Prog. Nucl. Magn. Reson. Spectrosc., 2011, 58(3-4):97 doi: 10.1016/j.pnmrs.2010.09.001
23. [23]
  Zheng, Z.L., Kuang, F.Y. and Zhao, J., Macromolecules, 2010, 43(7):3165 doi: 10.1021/ma902569n
24. [24]
  Zhang, H., Tao, K., Liu, D., Wu, K., Wang, F., Yang, J. and Zhao, J., Soft Matter, 2016, 12(35):7299 doi: 10.1039/C6SM01447J
25. [25]
  Deres, A., Floudas, G.A., Müllen, K., van der Auweraer, M., de Schryver, F., Enderlein, J., Uji-i, H. and Hofkens, J., Macromolecules, 2011, 44(24):9703 doi: 10.1021/ma201449p
26. [26]
  Uji-i, H., Melnikov, S.M., Deres, A., Bergamini, G., de Schryver, F., Herrmann, A., Müllen, K., Enderlein, J. and Hofkens, J., Polymer, 2006, 47(7):2511 doi: 10.1016/j.polymer.2005.11.094
27. [27]
  Enderlein, J., Phys. Rev. Lett., 2012, 108(10):108101 doi: 10.1103/PhysRevLett.108.108101
28. [28]
  Matyjaszewski, K., Macromolecules, 2012, 45(10):4015 doi: 10.1021/ma3001719
29. [29]
  Braeken, E., de Cremer, G., Marsal, P., Pèpe, G., Müllen, K. and Vallée, R.A.L., J. Am. Chem. Soc., 2009, 131(34):12201 doi: 10.1021/ja901636v
30. [30]
  Schroeyers, W., Vallée, R., Patra, D., Hofkens, J., Habuchi, S., Vosch, T., Cotlet, M., Müllen, K., Enderlein, J. and de Schryver, F.C., J. Am. Chem. Soc., 2004, 126(44):14310 doi: 10.1021/ja0474603
31. [31]
  Dorfschmid, M., Müllen, K., Zumbusch, A. and Wöll, D., Macromolecules, 2010, 43(14):6174 doi: 10.1021/ma100888s
32. [32]
  Bailey, N.P., Schrøder, T.B. and Dyre, J.C., Phys. Rev. Lett., 2009, 102(5):055701 doi: 10.1103/PhysRevLett.102.055701
33. [33]
  Chaudhuri, P., Berthier, L. and Kob, W., Phys. Rev. Lett., 2007, 99(6):060604 doi: 10.1103/PhysRevLett.99.060604
34. [34]
  Adam, G. and Gibbs, J.H., J. Chem. Phys., 1965, 43(1):139 doi: 10.1063/1.1696442
35. [35]
  Gibbs, J.H. and DiMarzio, E.A., J. Chem. Phys., 1958, 28(3):373 doi: 10.1063/1.1744141
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