Citation: Qian Wu, Bing Xu, Jun-jie Wei, Qing Wang, Qi-gang Wang, Wen-guang Liu. A Mechanically Strong Conductive Hydrogel Reinforced by Diaminotriazine Hydrogen Bonding[J]. Chinese Journal of Polymer Science, ;2017, 35(10): 1222-1230. doi: 10.1007/s10118-017-1960-3 shu

A Mechanically Strong Conductive Hydrogel Reinforced by Diaminotriazine Hydrogen Bonding

Qian Wu ^a ,
Bing Xu ^a ,
Jun-jie Wei ^b ,
Qing Wang ^a ,
Qi-gang Wang ^b ,
Wen-guang Liu ^a,,

a.
School of Materials Science and Engineering, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300350, China
b.
School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China

Corresponding author: Wen-guang Liu, dcwu@iccas.ac.cn
Received Date: 21 March 2017
Revised Date: 7 April 2017
Accepted Date: 11 April 2017

Fund Project: the National Natural Science Foundation of China 51325305the National Natural Science Foundation of China 51473117National Key Research and Development Program 2016YFC1101301the National Natural Science Foundation of China 21274105

Over the past decades, the urgent need for high strength conductive hydrogels in diverse applications has motivated an unremitting effort to combine the improved mechanical properties of hydrogels with conductive performances. In this work, high strength conductive hydrogels intensified with intermolecular hydrogen bonding are fabricated by in situ mixing poly(2-vinyl-4, 6-diamino-1, 3, 5-triazine-co-polyethylene glycol diacrylates) (PVDT-PEGDA) hydrogels with poly(3, 4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT/PSS). The conductive hydrogels in deionized water exhibit high mechanical performances with compressive strength and tensile strength in the range of 7.58-9.52 MPa and 0.48-1.20 MPa respectively, which are ascribed to the intermolecular hydrogen bonding interactions of diaminotriazinediaminotriazine (DAT-DAT) in the network. Meanwhile, adding PEDOT/PSS can significantly increase both the specific conductivities and equilibrium water contents of the hydrogels. These cytocompatible conductive hydrogels may have a great potential to be used as electrical stimuli responsive soft biomaterials.
- Conductive hydrogels,
- High strength,
- PEDOT/PSS,
- Hydrogen bonding
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