Citation: Qian Wu, Bing Xu, Jun-jie Wei, Qing Wang, Qi-gang Wang, Wen-guang Liu. A Mechanically Strong Conductive Hydrogel Reinforced by Diaminotriazine Hydrogen Bonding[J]. Chinese Journal of Polymer Science, ;2017, 35(10): 1222-1230. doi: 10.1007/s10118-017-1960-3 shu

A Mechanically Strong Conductive Hydrogel Reinforced by Diaminotriazine Hydrogen Bonding

Qian Wu ^a ,
Bing Xu ^a ,
Jun-jie Wei ^b ,
Qing Wang ^a ,
Qi-gang Wang ^b ,
Wen-guang Liu ^a,,

a.
School of Materials Science and Engineering, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300350, China
b.
School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China

Corresponding author: Wen-guang Liu, dcwu@iccas.ac.cn
Received Date: 21 March 2017
Revised Date: 7 April 2017
Accepted Date: 11 April 2017

Fund Project: the National Natural Science Foundation of China 51325305the National Natural Science Foundation of China 51473117National Key Research and Development Program 2016YFC1101301the National Natural Science Foundation of China 21274105

Over the past decades, the urgent need for high strength conductive hydrogels in diverse applications has motivated an unremitting effort to combine the improved mechanical properties of hydrogels with conductive performances. In this work, high strength conductive hydrogels intensified with intermolecular hydrogen bonding are fabricated by in situ mixing poly(2-vinyl-4, 6-diamino-1, 3, 5-triazine-co-polyethylene glycol diacrylates) (PVDT-PEGDA) hydrogels with poly(3, 4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT/PSS). The conductive hydrogels in deionized water exhibit high mechanical performances with compressive strength and tensile strength in the range of 7.58-9.52 MPa and 0.48-1.20 MPa respectively, which are ascribed to the intermolecular hydrogen bonding interactions of diaminotriazinediaminotriazine (DAT-DAT) in the network. Meanwhile, adding PEDOT/PSS can significantly increase both the specific conductivities and equilibrium water contents of the hydrogels. These cytocompatible conductive hydrogels may have a great potential to be used as electrical stimuli responsive soft biomaterials.
- Conductive hydrogels,
- High strength,
- PEDOT/PSS,
- Hydrogen bonding
1. [1]
  Hur, J., Im, K., Kim, S.W., Kim, J., Chung, D.Y., Kim, T.H., Jo, K.H., Hahn, J.H., Bao, Z., Hwang, S. and Park, N., ACS Nano, 2014, 8(10):10066 doi: 10.1021/nn502704g
2. [2]
  Green, R.A., Baek, S., Poole-Warren, L.A. and Martens, P.J., Sci. Technol. Adv. Mater., 2010, 11(1):014107 doi: 10.1088/1468-6996/11/1/014107
3. [3]
  Guiseppi-Elie, A., Biomaterials, 2010, 31(10):2701 doi: 10.1016/j.biomaterials.2009.12.052
4. [4]
  Cheong, G.L.M., Lim, K.S., Jakubowicz, A., Martens, P.J., Poole-Warren, L.A. and Green, R.A., Acta Biomaterialia, 2014, 10(3):1216 doi: 10.1016/j.actbio.2013.12.032
5. [5]
  Hao, G.P., Hippauf, F., Oschatz, M., Wisser, F.M., Leifert, A., Nickel, W., Mohamed-Noriega, N., Zheng, Z. and Kaskel, S., ACS Nano, 2014, 8(7):7138 doi: 10.1021/nn502065u
6. [6]
  Kumar, G.G., Hashmi, S., Karthikeyan, C., Nejad, A.G., Varnoosfaderani, M.V. and Stadler, F.J., Macromol. Rapid Commun., 2014, 35(21):1861
7. [7]
  Wu, H., Yu, G., Pan, L., Liu, N., McDowell, M.T., Bao, Z. and Cui, Y., Nat. Commun., 2013, 4(3):1943
8. [8]
  Li, L., Wang, Y., Pan, L., Shi, Y., Cheng, W., Shi, Y. and Yu, G., Nano Lett., 2015, 15(2):1146 doi: 10.1021/nl504217p
9. [9]
  Wang, E., Desai, M.S. and Lee, S.W., Nano Lett., 2013, 13(6):2826 doi: 10.1021/nl401088b
10. [10]
  Ahadian, S., Ramónazcón, J., Estili, M., Liang, X., Ostrovidov, S., Shiku, H., Ramalingam, M., Nakajima, K., Sakka, Y., Bae, H., Matsue, T. and Khademhosseini, A., Scientific Reports, 2014, 4(3):4271
11. [11]
  Dai, T., Qing, X., Lu, Y. and Xia, Y., Polymer, 2009, 50(22):5236 doi: 10.1016/j.polymer.2009.09.025
12. [12]
  Shi, Y., Ma, C., Peng, L. and Yu, G., Adv. Funct. Mater., 2015, 25(8):1219 doi: 10.1002/adfm.v25.8
13. [13]
  Xia, Y. and Zhu, H., Soft Matter, 2011, 7(19):9388 doi: 10.1039/c1sm05890h
14. [14]
  Ramónazcón, J., Ahadian, S., Estili, M., Liang, X., Ostrovidov, S., Kaji, H., Shiku, H., Ramalingam, M., Nakajima, K., Sakka, Y., Khademhosseini, A. and Matsue, T., Adv. Mater., 2013, 25(29):4028 doi: 10.1002/adma.v25.29
15. [15]
  Zhang, L. and Shi, G., J. Phys. Chem. C, 2011, 115(34):17206 doi: 10.1021/jp204036a
16. [16]
  Bai, H., Sheng, K., Zhang, P., Li, C. and Shi, G., J. Mater. Chem., 2011, 21(46):18653 doi: 10.1039/c1jm13918e
17. [17]
  Kishi, R., Kubota, K., Miura, T., Yamaguchi, T., Okuzaki, H. and Osada, Y., J. Mater. Chem. C, 2014, 2(4):736 doi: 10.1039/C3TC31999G
18. [18]
  Kishi, R., Hiroki, K., Tominaga, T., Sano, K.I., Okuzaki, H., Martinez, J.G., Otero, T.F. and Osada, Y., J. Polym. Sci., Part B:Polym. Phys., 2012, 50(11):790 doi: 10.1002/polb.v50.11
19. [19]
  Ding, H., Zhong, M., Kim, Y.J., Pholpabu, P., Balasubramanian, A., Hui, C.M., He, H., Yang, H., Matyjaszewski, K. and Bettinger, C.J., ACS Nano, 2014, 8(5):4348 doi: 10.1021/nn406019m
20. [20]
  Dispenza, C., Lo Presti, C., Belfiore, C., Spadaro, G. and Piazza, S., Polymer, 2006, 47(4):961 doi: 10.1016/j.polymer.2005.12.071
21. [21]
  Phuchaduek, W., Jamnongkan, T., Rattanasak, U., Boonsang, S. and Kaewpirom, S., J. Appl. Polym. Sci., 2015, 132(28):42234
22. [22]
  Zhang, Y., Li, Y. and Liu, W., Adv. Funct. Mater., 2015, 25(3):471 doi: 10.1002/adfm.201401989
23. [23]
  Zhang, J., Wang, N., Liu, W., Zhao, X. and Lu, W., Soft Matter, 2013, 9(27):6331 doi: 10.1039/c3sm50866h
24. [24]
  Tang, L., Liu, W. and Liu, G., Adv. Mater., 2010, 22(24):2652 doi: 10.1002/adma.v22:24
25. [25]
  Bai, T., Zhang, P., Han, Y., Liu, Y., Liu, W., Zhao, X. and Lu, W., Soft Matter, 2011, 7(6):2825 doi: 10.1039/c0sm01108h
26. [26]
  Crispin, X., Marciniak, S., Osikowicz, W., Zotti, G., Denier van der Gon, A.W., Louwet, F., Fahlman, M., Groenendaal, L., de Schryver, F. and Salaneck, W.R., J. Polym. Sci., Part B:Polym. Phys., 2003, 41(21):2561 doi: 10.1002/(ISSN)1099-0488
27. [27]
  Lin, P., Yan, F., Yu, J., Chan, H.L.W. and Yang, M., Adv. Mater., 2010, 22(33):3655 doi: 10.1002/adma.201000971
28. [28]
  Ghosh, S. and Inganäs, O., Adv. Mater., 1999, 11(14):1214 doi: 10.1002/(ISSN)1521-4095
29. [29]
  Huang, H., Zeng, X., Li, W., Wang, H., Wang, Q. and Yang, Y., J. Mater. Chem. A, 2014, 2(39):16516 doi: 10.1039/C4TA03332A
30. [30]
  Ren, Z., Zhang, Y., Li, Y., Xu, B. and Liu, W., J. Mater. Chem. B, 2015, 3(30):6347 doi: 10.1039/C5TB00781J
31. [31]
  Tang, L., Yang, Y., Bai, T. and Liu, W., Biomaterials, 2011, 32(7):1943 doi: 10.1016/j.biomaterials.2010.11.019
32. [32]
  Teng, C., Lu, X., Ren, G., Zhu, Y., Wan, M. and Jiang, L., Adv. Mater. Interfaces, 2014, 1(6):1400099 doi: 10.1002/admi.201400099
33. [33]
  Du, G., Gao, G., Hou, R., Cheng, Y., Chen, T. and Fu, J., Chem. Mater., 2014, 26(11):3522 doi: 10.1021/cm501095s
34. [34]
  Huang, H., Li, W., Wang, H., Zeng, X., Wang, Q. and Yang, Y., ACS Appl. Mater. Interfaces, 2014, 6(3):1595 doi: 10.1021/am4043799
35. [35]
  Siddhanta, S.K. and Gangopadhyay, R., Polymer, 2005, 46(9):2993 doi: 10.1016/j.polymer.2005.01.084
1. [1]
  Meng Shan , Yongmei Yu , Mengli Sun , Shuping Yang , Mengqi Wang , Bo Zhu , Junbiao Chang . Bifunctional organocatalyst-catalyzed dynamic kinetic resolution of hemiketals for synthesis of chiral ketals via hydrogen bonding control. Chinese Chemical Letters, 2025, 36(1): 109781-. doi: 10.1016/j.cclet.2024.109781
2. [2]
  Binhan Zhao , Zheng Li , Lan Zheng , Zhichao Ye , Yuyang Yuan , Shanshan Zhang , Bo Liang , Tianyu Li . Recent progress in the biomedical application of PEDOT:PSS hydrogels. Chinese Chemical Letters, 2024, 35(10): 109810-. doi: 10.1016/j.cclet.2024.109810
3. [3]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
4. [4]
  Songtao Cai , Liuying Wu , Yuan Li , Soham Samanta , Jinying Wang , Bing Liu , Feihu Wu , Kaitao Lai , Yingchao Liu , Junle Qu , Zhigang Yang . Intermolecular hydrogen-bonding as a robust tool toward significantly improving the photothermal conversion efficiency of a NIR-II squaraine dye. Chinese Chemical Letters, 2024, 35(4): 108599-. doi: 10.1016/j.cclet.2023.108599
5. [5]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
6. [6]
  Yunfa Dong , Shijie Zhong , Yuhui He , Zhezhi Liu , Shengyu Zhou , Qun Li , Yashuai Pang , Haodong Xie , Yuanpeng Ji , Yuanpeng Liu , Jiecai Han , Weidong He . Modification strategies for non-aqueous, highly proton-conductive benzimidazole-based high-temperature proton exchange membranes. Chinese Chemical Letters, 2024, 35(4): 109261-. doi: 10.1016/j.cclet.2023.109261
7. [7]
  Huanyan Liu , Jiajun Long , Hua Yu , Shichao Zhang , Wenbo Liu . Rational design of highly conductive and stable 3D flexible composite current collector for high performance lithium-ion battery electrodes. Chinese Chemical Letters, 2025, 36(3): 109712-. doi: 10.1016/j.cclet.2024.109712
8. [8]
  Jia Fu , Shilong Zhang , Lirong Liang , Chunyu Du , Zhenqiang Ye , Guangming Chen . PEDOT-based thermoelectric composites: Preparation, mechanism and applications. Chinese Chemical Letters, 2024, 35(9): 109804-. doi: 10.1016/j.cclet.2024.109804
9. [9]
  Lanfang Wang , Jiangnan Lv , Yujia Li , Yanqing Hao , Wenjiao Liu , Hui Zhang , Xiaohong Xu . One-step synthesis of nanowoven ball-like NiS-WS₂ for high-efficiency hydrogen evolution. Chinese Chemical Letters, 2025, 36(1): 109597-. doi: 10.1016/j.cclet.2024.109597
10. [10]
  Zikang Hu , Hengjie Zhang , Zhengqiu Li , Tianbao Zhao , Zhipeng Gu , Qijuan Yuan , Baoshu Chen . Multifunctional photothermal hydrogels: Design principles, various functions, and promising biological applications. Chinese Chemical Letters, 2024, 35(10): 109527-. doi: 10.1016/j.cclet.2024.109527
11. [11]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2024.100463
12. [12]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254
13. [13]
  Xu-Hui Yue , Xiang-Wen Zhang , Hui-Min He , Lei Qiao , Zhong-Ming Sun . Synthesis, chemical bonding and reactivity of new medium-sized polyarsenides. Chinese Chemical Letters, 2024, 35(7): 108907-. doi: 10.1016/j.cclet.2023.108907
14. [14]
  Haohao Sun , Wenxuan Wang , Yuli Xiong , Zelang Jian , Wen Chen . Boosting the electrochromic properties by large V₂O₅ nanobelts interlayer spacing tuned via PEDOT. Chinese Chemical Letters, 2024, 35(9): 109213-. doi: 10.1016/j.cclet.2023.109213
15. [15]
  Manman Ou , Yunjian Zhu , Jiahao Liu , Zhaoxuan Liu , Jianjun Wang , Jun Sun , Chuanxiang Qin , Lixing Dai . Polyvinyl alcohol fiber with enhanced strength and modulus and intense cyan fluorescence based on covalently functionalized graphene quantum dots. Chinese Chemical Letters, 2025, 36(2): 110510-. doi: 10.1016/j.cclet.2024.110510
16. [16]
  Kang Wang , Qinglin Zhou , Weijin Li . Conductive metal-organic frameworks for electromagnetic wave absorption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100325-100325. doi: 10.1016/j.cjsc.2024.100325
17. [17]
  Wendi Dou , Guangying Wan , Tiefeng Liu , Lin Han , Wu Zhang , Chuang Sun , Rensheng Song , Jianhui Zheng , Yujing Liu , Xinyong Tao . Conductive composite binder for recyclable LiFePO₄ cathode. Chinese Chemical Letters, 2024, 35(11): 109389-. doi: 10.1016/j.cclet.2023.109389
18. [18]
  Salim Ullah , Jianliang Shen , Hong-Tao Xu . Innovative self-healing conductive organogel: Pioneering the future of electronics. Chinese Chemical Letters, 2025, 36(3): 110553-. doi: 10.1016/j.cclet.2024.110553
19. [19]
  Zhe-Han Yang , Jie Yin , Lei Xin , Yuanfang Li , Yijie Huang , Ruo Yuan , Ying Zhuo . Research advancement of DNA-based intelligent hydrogels: Manufacture, characteristics, application of disease diagnosis and treatment. Chinese Chemical Letters, 2024, 35(10): 109558-. doi: 10.1016/j.cclet.2024.109558
20. [20]
  Yue Sun , Yingnan Zhu , Jiahang Si , Ruikang Zhang , Yalan Ji , Jinjie Fan , Yuze Dong . Glucose-activated nanozyme hydrogels for microenvironment modulation via cascade reaction in diabetic wound. Chinese Chemical Letters, 2025, 36(4): 110012-. doi: 10.1016/j.cclet.2024.110012

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(723)
HTML views(44)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142