Citation: Wu-cheng Fang, Ran Zhang, Ye-feng Yao, Hua-ji Liu, Yu Chen. Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water[J]. Chinese Journal of Polymer Science, ;2017, 35(8): 1035-1042. doi: 10.1007/s10118-017-1950-5 shu

Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water

Wu-cheng Fang ^a ,
Ran Zhang ^b ,
Ye-feng Yao ^b ,
Hua-ji Liu ^a,, ,
Yu Chen ^a,,

a.
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Sciences, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300354, China
b.
Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, Shanghai 200062, China

Corresponding author: Hua-ji Liu, liuhuaji@tju.edu.cn Yu Chen, chenyu@tju.edu.cn
Received Date: 14 February 2017
Revised Date: 22 March 2017
Accepted Date: 27 March 2017

Fund Project: the National Natural Science Foundation of China 20804027the National Natural Science Foundation of China 21274106

Optically active and inactive hyperbranched polymers with specific thermoresponsive behaviours in water were reported. Through two steps hyperbranched polyethylenimine (HPEI) polymers terminated with different amount of D-phenylalanine (D-Phe), L-phenylalanine (L-Phe) or DL-phenylalanine (DL-Phe) were prepared and characterized. The analyses on the solution properties by turbidimetry, dynamic light scattering, fluorescence probe and ¹H-NMR demonstrated that all the polymers exhibited specific thermoresponsive behaviours in water, including:(1) In the dilute polymer concentration region, increasing the polymer concentration led to the increase of phase transition temperature; (2) The optically inactive thermoresponsive hyperbranched polymers showed a higher cloud-point temperature (T_cp) than their corresponding optically active ones in a relatively higher polymer concentration; (3) At the same polymer concentration the hydrophobic groups of the optically inactive HPEI-DL-Phe formed more perfect hydrophobic domain than those of the optically active HPEI-L-Phe and HPEI-D-Phe.
- Hyperbranched,
- Polyethylenimine,
- Thermoresponsive,
- Phenylalanine,
- Optically active
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