Citation: Lin Tang, Fu-xin Liang, Qian Wang, Xiao-zhong Qu, Bing-yin Jiang, Zhen-zhong Yang. Polymer/Metal Segmental Janus Nanoparticles[J]. Chinese Journal of Polymer Science, ;2017, 35(7): 799-808. doi: 10.1007/s10118-017-1946-1 shu

Polymer/Metal Segmental Janus Nanoparticles

a.
State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Zhen-zhong Yang, rgliu@iccas.ac.cn
Received Date: 26 January 2017
Revised Date: 24 February 2017
Accepted Date: 1 March 2017

Fund Project: the National Natural Science Foundation of China 51233007the National Natural Science Foundation of China 51622308

Polymer/metal composite segmental Janus nanoparticles (NPs) are synthesized by sequential growth against poly(4-vinylpyridine) (P4VP) crosslinked cP4VP-PS Janus NPs. A Janus cluster of poly(4-vinylpyridine)-block-polystyrene (P4VP-b-PS) diblock copolymer is self-organized after absorption onto a silica patchy sphere via hydrogen bonding. Selective crosslinking of P4VP leads to the formation of robust cP4VP-PS Janus NPs. Within the cP4VP domain, functional species such as metals are preferentially grown by in situ reduction. Other thiol-capped polymers, for example, thiol-capped poly(N-isopropylacrylamide) (PNIPAM-SH), can be conjugated onto the opposite side to form polymer/metal triple segmental Janus NPs. The hyperthermia effect of Au NP of PNIPAM-Au@cP4VP-PS by near infrared (NIR) irradiation can trigger a fast transition from amphiphilic to hydrophobic of the Janus NPs at low surrounding temperature. De-stabilization of the emulsion is NIR triggered although the system temperature is below LCST (~32℃).
- Janus,
- Polymer,
- Composite,
- Nanoparticle,
- Interactive performance
1. [1]
  de Gennes, P.G., Rev. Mod. Phys., 1992, 64: 645 doi: 10.1103/RevModPhys.64.645
2. [2]
  Jiang, S. and Granick, S. , "Janus particles synthesis, self-assembly and applications" Royal Society of Chemistry, Cambridge, 2012
3. [3]
  Walther, A. and Müller, A.H.E., Chem. Rev., 2013, 113: 5194 doi: 10.1021/cr300089t
4. [4]
  Liang, F.X., Zhang, C.L. and Yang, Z.Z., Adv. Mater., 2014, 26: 6944 doi: 10.1002/adma.v26.40
5. [5]
  Lattuada, M. and Hatton, T.A., J. Am. Chem. Soc., 2007, 129: 12878 doi: 10.1021/ja0740521
6. [6]
  Song, Y., Liu, K. and Chen, S.W., Langmuir, 2012, 28: 17143 doi: 10.1021/la303513x
7. [7]
  Wang, Q.G., Liang, F.X., Wang, Q., Qu, X.Z. and Yang, Z.Z., Chinese J. Polym. Sci., 2015, 33(10): 1462 doi: 10.1007/s10118-015-1691-2
8. [8]
  Lv, D.M., Ni, W., Liang, F.X., Wang, Q., Qu, X.Z. and Yang, Z.Z., Chinese J. Polym. Sci., 2015, 33(9): 1344 doi: 10.1007/s10118-015-1683-2
9. [9]
  Wurm, F. and Kilbinger, A.F.M., Angew. Chem. Int. Ed., 2009, 48: 8412 doi: 10.1002/anie.v48:45
10. [10]
  Du, J.Z. and O'Reilly, R.K., Chem. Soc. Rev., 2011, 40: 2402 doi: 10.1039/c0cs00216j
11. [11]
  Isojima, T., Lattuada, M., Sande, J.B.V. and Hatton, T.A., ACS Nano, 2008, 2: 1799 doi: 10.1021/nn800089z
12. [12]
  Glotzer, S.C. and Solomon, M.J., Nat. Mater., 2007, 6: 557 doi: 10.1038/nmat1949
13. [13]
  Huang, Z.H., Dong, B.J., Chen, P.Y., Yang, Y., Zhu, G.L. and Yan, L.T., Acta Polymerica Sinica (in Chinese), 2016, (8): 979
14. [14]
  Zubarev, E.R., Xu, J., Sayyad, A. and Gibson, J.D., J. Am. Chem. Soc., 2006, 128: 15098 doi: 10.1021/ja066708g
15. [15]
  Hu, J.M., Wu, T., Zhang, G.Y. and Liu, S.Y., J. Am. Chem. Soc., 2012, 134: 7624 doi: 10.1021/ja302019q
16. [16]
  Jackson, A., Myerson, J.W. and Stellacci, F., Nat. Mater., 2004, 5: 330
17. [17]
  Kim, H., Carney, R.P., Reguera, J., Ong, Q.K., Liu, X. and Stellacci, F., Adv. Mater., 2012, 24: 3857 doi: 10.1002/adma.v24.28
18. [18]
  Kim, B.J., Bang, J., Hawker, C.J., Chiu, J.J., Pine, D.J., Jang, S.G., Yang, S.M. and Kramer, E.J., Langmuir, 2007, 23: 12693 doi: 10.1021/la701906n
19. [19]
  Glogowski, E., He, J., Russell T.P. and Emrick, T., Chem. Commun., 2005, 32: 4050
20. [20]
  Andala, D.M., Shin, S.H.R., Lee, H.Y. and Bishop, K.J.M., ACS Nano, 2012, 6: 1044 doi: 10.1021/nn202556b
21. [21]
  Wang, B.B., Li, B., Zhao, B. and Li, C.Y., J. Am. Chem. Soc., 2008, 130: 11594 doi: 10.1021/ja804192e
22. [22]
  Nie, L., Liu, S.Y., Shen, W.M., Chen, D.Y. and Jiang, M., Angew. Chem. Int. Ed., 2007, 46: 6321 doi: 10.1002/anie.v46:33
23. [23]
  Jiao, Y. and Akcora, P., Macromolecules, 2012, 45, 3463 doi: 10.1021/ma3000576
24. [24]
  Yao, X.H., Jing, J.Y., Liang, F.X. and Yang, Z.Z., Macromolecules, 2016, 49: 9618 doi: 10.1021/acs.macromol.6b02004
25. [25]
  Mavila, S., Eivgi, O., Berkovich, I. and Lemcoff, N.G., Chem. Rev., 2016, 116: 878 doi: 10.1021/acs.chemrev.5b00290
26. [26]
  Liu, Y.F., Abetz, V. and Müller, A.H.E., Macromolecules, 2003, 36: 7894 doi: 10.1021/ma0345551
27. [27]
  Erhardt, R., Bölker, A., Zettl, H., Kaya, H., Pyckhout-Hintzen, W., Krausch, G., Abetz, V. and Müller, A.H.E., Macromolecules, 2001, 34: 1069 doi: 10.1021/ma000670p
28. [28]
  Zhou, P., Liang, F.X., Liu, Y.J., Deng, R.H., Yang, H.L., Wang, Q., Qu, X.Z. and Yang, Z.Z., Sci. China Mater., 2015, 58: 961 doi: 10.1007/s40843-015-0103-9
29. [29]
  Stöber, W., Fink, A. and Bohn, E., J. Colloid Interface Sci., 1968, 26: 62 doi: 10.1016/0021-9797(68)90272-5
30. [30]
  Kim, K., Kim, H.S. and Park, H.K., Langmuir, 2006, 22: 8083 doi: 10.1021/la0612015
31. [31]
  Burtovyy, R. and Luzinov, I., Langmuir, 2008, 24: 5903 doi: 10.1021/la703545t
32. [32]
  Ruokolainen, J., ten Brinke, G., Ikkala, O., Torkkeli, M. and Serimaa, R., Macromolecules, 1996, 29: 3409 doi: 10.1021/ma9516504
33. [33]
  Ruokolainen, J., Tanner. J., ten Brinke, G., Ikkala, O., Torkkeli, M. and Serimaa, R, Macromolecules, 1995, 28: 7779 doi: 10.1021/ma00127a027
34. [34]
  Malynych, S., Luzinov, I. and Chumanov, G., J. Phys. Chem. B, 2002, 106: 1280 doi: 10.1021/jp013236d
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