Citation: Jian-hua Li, De-bin Zhang, Xing-xing Ni, Hui Zheng, Qi-qing Zhang. Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush[J]. Chinese Journal of Polymer Science, ;2017, 35(7): 809-822. doi: 10.1007/s10118-017-1944-3 shu

Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush

Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou 350001, China

Corresponding author: Jian-hua Li, jhli_2005@163.com; zhangqiq@126.com Qi-qing Zhang, zhangqiq@126.com
Received Date: 15 December 2016
Revised Date: 13 February 2017
Accepted Date: 2 March 2017

Fund Project: the National Natural Science Foundation of China 51303028the National Natural Science Foundation of China 31401609

A silver nanoparticles-poly(carboxybetaine methacrylate) (AgNPs-PCBMA) nanocomposite was prepared on poly(vinylidene fluoride) (PVDF) membrane surface to improve its hydrophilicity and antifouling properties. Firstly, the PVDF membranes were grafted by PCBMA via physisorbed free radical grafting technique. Then Ag⁺ coordinated to the carbonyl group on PCBMA and subsequently was reduced to silver nanoparticles. The hydrophilicity of the PVDF-g-PCBMA/Ag membrane was enhanced with the increasing fixed degree (FD) of AgNPs, and the original water contact angle of membrane was reduced to 33.97°. Additionally, water flux recovery ratio (FRR) and bovine serum albumin (BSA) rejection ratio of PVDF-g-PCBMA/AgNPs membrane were improved from 52% to 93.32% and 28.12% to 91.12%, respectively. Further, the PVDF-g-PCBMA/AgNPs membranes exhibited the more pronounced inhibition zone. The study demonstrated that compared with pure AgNPs or the PCBMA polymer brush, the synergistic effect of PCBMA and AgNPs made PVDF membranes have better hydrophilicity and anti-bacterial performances.
- PVDF membrane,
- Zwitterionic monomer CBMA,
- Silver nanoparticle,
- Antifouling performance,
- Antibacterial ability
1. [1]
  Li, J.H., Wang, S.S., Zhang, D.B., Ni, X.X. and Zhang, Q.Q., Chinese J. Polym. Sci., 2016, 34(7): 805 doi: 10.1007/s10118-016-1808-2
2. [2]
  Wang, H.J., Feng, H.P., Wang, X.C., Du, Q.C. and Yan, C., Chinese J. Polym. Sci., 2015, 33(6): 823 doi: 10.1007/s10118-015-1627-x
3. [3]
  Lee, J.S., Lee, H.H., Seo, J.A., Park, H.S., Park, J. and Min, B.R., Appl. Surf. Sci., 2015, 356: 1207 doi: 10.1016/j.apsusc.2015.08.226
4. [4]
  Gomez-Coma, L., Garea, A., Rouch, J.C., Savart, T., Lahitte, J.F., Remigy, J.C. and Irabien, A., J. Membr. Sci., 2016, 498: 218 doi: 10.1016/j.memsci.2015.10.023
5. [5]
  Zhang, X., Lang, W.Z., Yan, X., Lou, Z.Y. and Chen, X.F., J. Membr. Sci., 2016, 499: 179 doi: 10.1016/j.memsci.2015.10.034
6. [6]
  Meng, N., Priestley, R.C.E., Zhang, Y.Q., Wang, H.T. and Zhang, X.W., J. Membr. Sci., 2016, 501: 169 doi: 10.1016/j.memsci.2015.12.004
7. [7]
  Liu, D.P., Li, D., Du, D., Zhao, X.Z., Qin, A., Li, X. and He, C.J., J. Membr. Sci., 2015, 493: 243 doi: 10.1016/j.memsci.2015.07.005
8. [8]
  Qin, A., Li, X., Zhao, X., Liu, D. and He, C., ACS Appl. Mater. Interfaces, 2015, 7: 8427 doi: 10.1021/acsami.5b00978
9. [9]
  Zhao, X.Z., Xuan, H.X., Chen, Y.L. and He, C.J., J. Membr. Sci., 2015, 494: 48 doi: 10.1016/j.memsci.2015.07.052
10. [10]
  Wang, L., Pan, K., Li, L. and Cao, B., Ind. Eng. Chem. Res., 2014, 53: 6401 doi: 10.1021/ie4042388
11. [11]
  Yang, X., He, Y., Zeng, G.Y., Zhan, Y.Q., Pan, Y., Shi, H. and Chen, Q., J. Membr. Sci., 2016, 51: 8965
12. [12]
  Xiao, Y., Liu, X.D., Wang, D.X., Lin., Y.K., Han, Y.P. and Wang, X.L., Desalination, 2013, 313: 16
13. [13]
  Baghbanzadeh, M., Rana, D., Matsuura, T. and Lan, C.Q., Desalination, 2015, 369: 75 doi: 10.1016/j.desal.2015.04.032
14. [14]
  Zhang, Y., Chen, Y., Zhang, H., Zhang, B. and Liu. J., J. Inorg. Biochem, 2013, 118: 59 doi: 10.1016/j.jinorgbio.2012.07.025
15. [15]
  Huang, L.C., Zhao, S., Wang, Z., Wu, J.H., Wang, J.X. and Wang, S.C., J. Membr. Sci., 2016, 499: 269 doi: 10.1016/j.memsci.2015.10.055
16. [16]
  Zhang, M., Zhang, K.S., Gusseme, B.D. and Verstraete, W., Water Res., 2012, 46: 2077 doi: 10.1016/j.watres.2012.01.015
17. [17]
  Sawada, I., Fachrul, R., Ito, T., Ohmukai, Y., Maruyama, T. and Matsuyama, H., J. Membr. Sci., 2012, 387: 1
18. [18]
  Liu, Y.L., Rosenfield, E., Hu, M. and Mi, B.X., Water Res., 2013, 47: 2949 doi: 10.1016/j.watres.2013.03.005
19. [19]
  Shi, H.Y., Liu, F. and Xue, L.X., J. Membr. Sci., 2013, 437: 205 doi: 10.1016/j.memsci.2013.03.009
20. [20]
  Chen, Y.F, Zhang, Y.T., Zhang, H.Q., Liu, J.D. and Song, C.H., Chem. Eng. J., 2013, 228: 12 doi: 10.1016/j.cej.2013.05.015
21. [21]
  Wang, P.P., Ma, J., Wang, Z.H., Shi, F.G. and Liu, Q.L., Langmuir, 2012, 28: 4776 doi: 10.1021/la203494z
22. [22]
  Zhang, G.L., Lu, S.F., Zhang, L., Meng, Q., Shen, C. and Zhang, J.W., J. Membr. Sci., 2013, 436: 163 doi: 10.1016/j.memsci.2013.02.009
23. [23]
  Li, J.H., Shao, X.S., Zhou, Q., Li, M.Z. and Zhang, Q.Q., Appl. Surf. Sci., 2013, 265: 663 doi: 10.1016/j.apsusc.2012.11.072
24. [24]
  Yin, J., Yang, Y., Hu, Z.Q. and Deng, B.L., J. Membr. Sci., 2013, 441: 73 doi: 10.1016/j.memsci.2013.03.060
25. [25]
  Zhao, Y.F., Zhu, L.P., Yi, Z., Zhu, B.K. and Xu, Y.Y., J. Membr. Sci., 2013, 440: 40 doi: 10.1016/j.memsci.2013.03.064
26. [26]
  Huang, C.J., Li, Y.T. and Jiang, S.Y., Anal. Chem., 2012, 84: 3440 doi: 10.1021/ac3003769
27. [27]
  Cheng, G., Li, G.Z., Xue, H., Chen, S.F., Bryers, J.D. and Jiang, S.Y., Biomaterials, 2009, 30: 5234 doi: 10.1016/j.biomaterials.2009.05.058
28. [28]
  Hu, R., Li, G.Z., Jiang, Y.J., Zou, J.J., Wang, L. and Zhang, X.W., Langmuir, 2013, 29: 3773 doi: 10.1021/la304708b
29. [29]
  Li, M.Z., Li, J.H., Shao, X.S., Miao, J., Wang, J.B., Zhang, Q.Q. and Xu, X.P., J. Membr. Sci., 2012, 405: 141
30. [30]
  Zhang, Z., Chen, S.F. and Jiang, S.Y., Biomacromolecules, 2006, 7: 3311 doi: 10.1021/bm060750m
31. [31]
  Maximous, N., Nakhla, G., Wan, W. and Wong, K., J. Membr. Sci., 2010, 352: 222 doi: 10.1016/j.memsci.2010.02.021
32. [32]
  Zhang, J.G., Xu, Z.W., Mai, W., Min, C.Y., Zhou, B.M., Shan, M.J., Li, Y.L., Yang, C.Y., Wang, Z. and Qian, X.M., J. Mater. Chem. A., 2013, 1: 3101 doi: 10.1039/c2ta01415g
33. [33]
  Liu, X., Qi, S., Li, Y., Yang, Y., Cao, B. and Tang, Y.Y., Water Res., 2013, 47: 3081 doi: 10.1016/j.watres.2013.03.018
34. [34]
  Enomoto, R., Sato, M., Fujii, S., Hirai, T., Takahara, A. and Ishihara, K.S., J. Polym. Sci., Part A: Polym. Chem., 2014, 52: 2822 doi: 10.1002/pola.v52.19
35. [35]
  Kumar, M. and Ulbricht, M., RSC Adv., 2013, 3: 12190 doi: 10.1039/c3ra41483c
36. [36]
  Liu, J.Y. and Hurt, R.H., Int. J. Environ. Sci. Technol., 2010, 44: 2169 doi: 10.1021/es9035557
37. [37]
  Zhou, Q., Li, J.H., Yan, B.F., Wu, D. and Zhang, Q.Q., Chinese J. Polym. Sci., 2014, 32(7): 892 doi: 10.1007/s10118-014-1457-2
38. [38]
  Qin, J.X., Lin, S.S., Song, S.Q., Zhang, L. and Chen, H.L., ACS. Appl. Mater. Interfaces, 2013, 5: 6649 doi: 10.1021/am401345y
39. [39]
  Sinha, M.K. and Purkait, M.K., J. Membr. Sci., 2013, 437: 7 doi: 10.1016/j.memsci.2013.03.003
40. [40]
  Meng, J., Song, L., Xu, H., Kong, H., Wang, C., Guo, X. and Xie, S., Nanomedicine, 2005, 1: 136 doi: 10.1016/j.nano.2005.03.003
41. [41]
  Mijnendonckx, K., Leys, N., Mahillon, J., Silver, S. and Houdt. R.V., BioMetals, 2013, 26: 609 doi: 10.1007/s10534-013-9645-z
42. [42]
  Zhu, X., Bai, R., Wee, K., Liu, C. and Tang, S., J. Membr. Sci., 2010, 363: 278 doi: 10.1016/j.memsci.2010.07.041
1. [1]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
2. [2]
  Yixin Zhang , Ting Wang , Jixiang Zhang , Pengyu Lu , Neng Shi , Liqiang Zhang , Weiran Zhu , Nongyue He . Formation mechanism for stable system of nanoparticle/protein corona and phospholipid membrane. Chinese Chemical Letters, 2024, 35(4): 108619-. doi: 10.1016/j.cclet.2023.108619
3. [3]
  Lingna Wang , Chenxin Tian , Ruobin Dai , Zhiwei Wang . Eco-friendly regeneration of end-of-life PVDF membrane with triethyl phosphate: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(9): 109356-. doi: 10.1016/j.cclet.2023.109356
4. [4]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406
5. [5]
  Kexin Yuan , Yulei Liu , Haoran Feng , Yi Liu , Jun Cheng , Beiyang Luo , Qinglian Wu , Xinyu Zhang , Ying Wang , Xian Bao , Wanqian Guo , Jun Ma . Unlocking the potential of thin-film composite reverse osmosis membrane performance: Insights from mass transfer modeling. Chinese Chemical Letters, 2024, 35(5): 109022-. doi: 10.1016/j.cclet.2023.109022
6. [6]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
7. [7]
  Biao Fang , Runwei Mo . PVDF-based solid-state battery. Chinese Journal of Structural Chemistry, 2024, 43(8): 100347-100347. doi: 10.1016/j.cjsc.2024.100347
8. [8]
  Yu Mao , Yilin Liu , Xiaochen Wang , Shengyang Ni , Yi Pan , Yi Wang . Acylfluorination of enynes via phosphine and silver catalysis. Chinese Chemical Letters, 2024, 35(8): 109443-. doi: 10.1016/j.cclet.2023.109443
9. [9]
  Jing Wang , Zenghui Li , Xiaoyang Liu , Bochao Su , Honghong Gong , Chao Feng , Guoping Li , Gang He , Bin Rao . Fine-tuning redox ability of arylene-bridged bis(benzimidazolium) for electrochromism and visible-light photocatalysis. Chinese Chemical Letters, 2024, 35(9): 109473-. doi: 10.1016/j.cclet.2023.109473
10. [10]
  Hongxia Li , Xiyang Wang , Du Qiao , Jiahao Li , Weiping Zhu , Honglin Li . Mechanism of nanoparticle aggregation in gas-liquid microfluidic mixing. Chinese Chemical Letters, 2024, 35(4): 108747-. doi: 10.1016/j.cclet.2023.108747
11. [11]
  Wenlong Li , Feishi Shan , Qingdong Bao , Qinghua Li , Hua Gao , Leyong Wang . Supramolecular assembly nanoparticle for trans-epithelial treatment of keratoconus. Chinese Chemical Letters, 2024, 35(10): 110060-. doi: 10.1016/j.cclet.2024.110060
12. [12]
  Wenya Jiang , Jianyu Wei , Kuan-Guan Liu . Atomically precise superatomic silver nanoclusters stabilized by O-donor ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100371-100371. doi: 10.1016/j.cjsc.2024.100371
13. [13]
  Xingyu Chen , Sihui Zhuang , Weiyao Yan , Zhengli Zeng , Jianguo Feng , Hongen Cao , Lei Yu . Synthesis, antibacterial evaluation, and safety assessment of Se@PLA as a potent bactericide against Xanthomonas oryzae pv. oryzae. Chinese Chemical Letters, 2024, 35(10): 109635-. doi: 10.1016/j.cclet.2024.109635
14. [14]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
15. [15]
  Botao QU , Qian WANG , Xiaogang NING , Yuxin ZHOU , Ruiping ZHANG . Deeply penetrating photoacoustic imaging in tumor tissues based on dual-targeted melanin nanoparticle. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1025-1032. doi: 10.11862/CJIC.20230416
16. [16]
  Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, 2024, 35(9): 109350-. doi: 10.1016/j.cclet.2023.109350
17. [17]
  Ya-Wen Zhang , Ming-Ming Gan , Li-Ying Sun , Ying-Feng Han . Supramolecular dinuclear silver(I) and gold(I) tetracarbene metallacycles and fluorescence sensing of penicillamine. Chinese Journal of Structural Chemistry, 2024, 43(9): 100356-100356. doi: 10.1016/j.cjsc.2024.100356
18. [18]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
19. [19]
  Yan Zou , Yin-Shuang Hu , Deng-Hui Tian , Hong Wu , Xiaoshu Lv , Guangming Jiang , Yu-Xi Huang . Tuning the membrane rejection behavior by surface wettability engineering for an effective water-in-oil emulsion separation. Chinese Chemical Letters, 2024, 35(6): 109090-. doi: 10.1016/j.cclet.2023.109090
20. [20]
  Xubin Qian , Lei Xu , Xu Ge , Zhun Liu , Cheng Fang , Jianbing Wang , Junfeng Niu . Can perfluorooctanoic acid be effectively degraded using β-PbO₂ reactive electrochemical membrane?. Chinese Chemical Letters, 2024, 35(7): 109218-. doi: 10.1016/j.cclet.2023.109218

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(625)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142