Citation: Zhong-chuan Peng, Qian Li, Hua-yi Li, You-liang Hu. Layered Nanoparticles Modified by Chain End Functional PE and Their Nanocomposites with PE[J]. Chinese Journal of Polymer Science, ;2017, 35(7): 897-908. doi: 10.1007/s10118-017-1931-8 shu

Layered Nanoparticles Modified by Chain End Functional PE and Their Nanocomposites with PE

Zhong-chuan Peng ^a,b ,
Qian Li ^a,, ,
Hua-yi Li ^a,, ,
You-liang Hu ^a

a.
Beijing National Laboratory of Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Qian Li, liqian2010@iccas.ac.cn Hua-yi Li, lihuayi@iccas.ac.cn
Received Date: 6 December 2016
Revised Date: 30 December 2017
Accepted Date: 3 January 2017

Fund Project: the National Natural Science Foundation of China No. 51403216

Layered materials (MMT, LDH) were successfully modified by chain end functionalized polyethylene via an ion exchange method. The samples were characterized by using elemental analysis, Fourier transform infrared (FTIR) spectrum, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and thermogravimetric analysis (TGA). The XRD results demonstrated that MMT was successfully exfoliated with the disappearance of [001] peak. For the LDH, the peak[003] moved to a low angle and greatly weakened, indicating that LDH was successfully functionalized and completely intercalated or exfoliated. HDPE/layered nanocomposites were obtained between HDPE and different content of functional layered materials. The SEM and TEM results of nanocomposites showed the layered materials were well dispersed in the HDPE matrix, with a particle size of 100-200 nm.
- MMT,
- LDH,
- Polyethylene,
- Modify,
- Nanocomposites
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