Citation: Chen Bin, Chen Jia, Li Jing-yu, Tong Xin, Zhao Hai-chao, Wang Li-ping. Oligoaniline Assisted Dispersion of Carbon Nanotubes in Epoxy Matrix for Achieving the Nanocomposites with Enhanced Mechanical, Thermal and Tribological Properties[J]. Chinese Journal of Polymer Science, ;2017, 35(3): 446-454. doi: 10.1007/s10118-017-1911-z shu

Oligoaniline Assisted Dispersion of Carbon Nanotubes in Epoxy Matrix for Achieving the Nanocomposites with Enhanced Mechanical, Thermal and Tribological Properties

Chen Bin ^a ,
Chen Jia ^a,b ,
Li Jing-yu ^a ,
Tong Xin ^b ,
Zhao Hai-chao ^b,, ,
Wang Li-ping ^b,,

a.
School of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
b.
Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

Corresponding author: Zhao Hai-chao, zhaohaichao@nimte.ac.cn Wang Li-ping, wangliping@nimte.ac.cn
Received Date: 25 August 2016
Revised Date: 8 September 2016
Accepted Date: 15 September 2016

Fund Project: National Basic Research Program 2015CB654705Natural Science Foundation of Zhejiang Province LY16B040004"One Hundred Talented People" of the Chinese Academy of Sciences Y60707WR04

A critical challenge for initiating many applications of the carbon nanotubes (CNTs) is their dispersion in organic solvent or in polymer melt. In the present study, we described a novel strategy for fabricating carbon nanotubes (CNTs)-reinforced epoxy nanocomposite by utilizing aniline trimer (AT) as the noncovalent dispersant. Tensile testing showed that the tensile modulus of the CNTs-reinforced epoxy composites was considerably improved by adding a small amount of AT functionalized CNTs. Additionally, the as-prepared CNTs-epoxy nanocomposites exhibited superior tribological properties with much lower frictional coefficients and wear rates compared to those of neat epoxy resin. The well dispersed AT-functionalized CNTs in epoxy matrix played an important role in enhancing the mechanical properties, as well as acting as a solid lubricant for improving the tribological performance of epoxy/CNTs nanocomposite.
- Carbon nanotubes,
- Epoxy,
- Mechanical,
- Tribological,
- Nanocomposites
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