Citation: Lv Wei, Wang Wen, Zhang Chun-lei, Zhao Yan, Zhen Hong-yu, Ling Qi-dan. Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit[J]. Chinese Journal of Polymer Science, ;2017, 35(3): 342-353. doi: 10.1007/s10118-017-1909-6 shu

Synthesis and Photoelectric Properties of New Pr-bonded Polymers by Coordination of Isopropyloxide and Bipyridine Unit

College of Chemistry and Chemical Engineering, College of Materials Science and Engineering, Fujian Normal University, Fujian Key Laboratory of Polymer Materials, Fuzhou 350007, China

Corresponding author: Wang Wen, wangwen@fjnu.edu.cn Ling Qi-dan, qdling@fjnu.edu.cn
Received Date: 29 July 2016
Revised Date: 28 September 2016
Accepted Date: 28 September 2016

Fund Project: the Program for Innovative Research Team in Science and Technology in Fujian Province (IRTSTFJ) and the Program of the Education Department of Fujian Province JA14078the National Natural Science Foundation of China 21574021 and 51573026the Natural Science Foundation of Fujian Province 2015J01189

A series of novel praseodymium (Pr)-bonded polymers were successfully synthesized via the coordination reaction and palladium-catalyzed Suzuki coupling reaction of 2,7-dibromo-9,9'-dioctylfluorene and different amounts of 5,5'-dibromo-2,2'-bipyridine. The resulting polymers were characterized by ¹H-NMR and GPC. The photoluminescence (PL) and electroluminescence (EL) properties of the resulting polymers were studied to explore the effects of the Pr triisopropyloxide. The results showed that the incorporation of Pr into the polymers caused better coplanarity and effective intermolecular or intramolecular interaction, leading to the higher emission intensity at long-wavelength. Further, it was also found that the emission light color could be tuned from blue to green by introduction of a small amount of Pr into the polymer main chain. A single-layer green emitting EL device based on PF(BipyPr)₆ with 6 mol% Pr content was fabricated. The device had a low turn-on voltage of 6 V, a brightness of 705.3 cd·m^-2, the maximum luminous efficiency of 1.53 cd·A^-1 and the maximum power efficiency of 0.69 lm·W^-1.
- Polyfluorene,
- Praseodymium,
- Light-emitting polymers,
- Bipyridine
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