Citation: Zhao Yong, Li Guo-min, Liu Fang-fang, Dai Xue-min, Dong Zhi-xin, Qiu Xue-peng. Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)[J]. Chinese Journal of Polymer Science, ;2017, 35(3): 372-385. doi: 10.1007/s10118-017-1896-7 shu

Synthesis and Properties of Novel Polyimide Fibers Containing Phosphorus Groups in the Side Chain (DATPPO)

a.
Polymer Composites Engineering Laboratory, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Dong Zhi-xin, zxdong@ciac.ac.cn Qiu Xue-peng, xp_q@ciac.ac.cn
Received Date: 15 July 2016
Revised Date: 23 August 2016
Accepted Date: 11 September 2016

Fund Project: the National Natural Science Foundation of China 51373164the National Basic Research Program of China 2014CB643604

A series of polyamic acid copolymers (co-PAAs) containing phosphorous groups in the side chains were synthesized from[2,5-bis(4-aminophenoxy) phenyl] diphenylphosphine oxide (DATPPO) and 4,4'-oxydianiline (ODA) with 3,3',4,4'-biphenyltetracarboxylic dianhydride (s-BPDA) through the polycondensation in N,N'-dimethyacetamide (DMAc). The co-PAA solutions were spun into fibers by a dry-jet wet spinning process followed by thermal imidization to obtain co-polyimide (co-PI) fibers. FTIR spectra and elemental analysis confirmed the chemical structure of PI fibers. SEM results indicated that the resulting PI fibers had a smooth and dense surface, a uniform and circle-shape diameter. The thermogravimetric measurements showed that with the increase of DATPPO content, the resulting PI fibers possessed high decomposition temperature and residual char yield, indicating that the PI fibers had good thermal stability. The corresponding limiting oxygen index (LOI) values from the experiment results showed that the co-PI fibers possessed good flame-retardant property. Furthermore, the mechanical properties of the co-PI fibers were investigated systematically. When the DATPPO content increased, the tensile strength and initial modulus of the co-PI fibers decreased. However, the mechanical properties were improved by increasing the draw ratio of the fibers. When the draw ratio was up to 2.5, the tensile strength and initial modulus of the co-PI fibers reached up to 0.64 and 10.02 GPa, respectively. The WAXD results showed that the order degree of amorphous matter increased with increased stretching. In addition, the SAXS results displayed that valuably drawing the fibers could eliminate the voids inside and lead to better mechanical property. WAXD revealed that the orientation of the amorphous polymer influenced the mechanical properties of the fibers.
- [2,5-Bis(4-aminophenoxy) phenyl] diphenylphosphine oxide,
- Dry-jet wet spinning process,
- Phosphorous,
- Polyimide fibers
1. [1]
  1 Samuel, I.R. and Edgar, S.C., 1968, U.S. Pat., 3,415,782
2. [2]
  Cheng, S.Z.D., Wu, Z., Eashoo, M., Hsu, S.L.C. and Harris, F.W., Polymer, 1991, 32(10): 1803
3. [3]
  Eashoo, M., Shen, D., Wu, Z., Lee, C.J., Harris, F.W. and Cheng, S.Z.D., Polymer, 1993, 34(15): 3209 doi: 10.1016/0032-3861(93)90392-N
4. [4]
  Koontz, S.L., Leger, L.J., Visentine, J.T., Hunton, D.E., Cross, J.B. and Hakes, C.L., J. Spacecraft Rockets, 1995, 32(3): 483 doi: 10.2514/3.26641
5. [5]
  Grossman, E., Lifshitz, Y., Wolan, J.T., Mount, C.K. and Hoflund, G.B., J. Spacecraft Rockets, 1999, 36(1): 75 doi: 10.2514/2.3435
6. [6]
  Dong, J., Yin, C., Luo, W. and Zhang, Q., J. Mater. Sci., 2013, 48(21): 7594
7. [7]
  Fang, G., Li, H., Liu, J., Ni, H., Yang, H. and Yang, S., Chem. Lett., 2015, 44(8): 1083 doi: 10.1246/cl.150396
8. [8]
  Eashoo, M., Wu, Z., Zhang, A., Shen, D., Tse, C., Harris, F.W., Cheng, S.Z.D., Gardner, K.H. and Hsiao, B.S., Macromol. Chem. Phys., 1994, 195(6): 2207
9. [9]
  Yin, C., Dong, J., Li, Z., Zhang, Z. and Zhang, Q., Compos. Part B-Eng., 2014, 58: 430 doi: 10.1016/j.compositesb.2013.10.074
10. [10]
  10 Shen, Z., Mu, Y., Ding, Y., Liu, Y. and Zhao, C., Study on the mechanical property of polyimide film in space radiation environments; proceedings of the Selected Proceedings of the Chinese Society for Optical Engineering Conferences held November 2015, International Society for Optics and Photonics, 2016.
11. [11]
  Yokota, K., Abe, S., Tagawa, M., Iwata, M., Miyazaki, E., Ishizawa, J.I., Kimoto, Y. and Yokota, R., High. Perform. Polym., 2010, 22: 237 doi: 10.1177/0954008308101535
12. [12]
  Duo, S.W., Song, M.M., Liu, T.Z., Hu, C.Y. and Li, M.S., Key Eng. Mater., 2012, 492: 521
13. [13]
  Liu, R. and Ma, J.D., Sichuan Text Technology (in Chinese), 2004, 4: 47
14. [14]
  Ding, X., Qiu, X., Ma, X., Li, G. and Gao, L., Chemistry Journal of Chinese Universities (in Chinese), 2013, 34: 2650
15. [15]
  Zhao, Y., Feng, T., Li, G., Liu, F., Dai, X., Dong, Z. and Qiu, X., RSC Adv., 2016, 6(48): 42482 doi: 10.1039/C6RA02344D
16. [16]
  Hergenrother, P.M., Watson, K.A., Smith, J.G., Connell, J.W. and Yokota, R., Polymer, 2002, 43(19): 5077
17. [17]
  17 Connell, J.W., Smith, J.G., Hergenrother, P.M., Watson, K.A. and Thompson, C.M., 2003, U.S. Pat., 7,109,287
18. [18]
  18 Hergenrother, P.M., Smith, J.G., Connell, J.W. and Watson, K.A., 2005, U.S. Pat., 6,958,192
19. [19]
  van Krevelen, D.W., Polymer, 1975, 16(8): 615 doi: 10.1016/0032-3861(75)90157-3
20. [20]
  Zhang, M., Niu, H., Lin, Z., Qi, S., Chang, J., Ge, Q. and Wu, D., Macromol. Mater. Eng., 2015, 300(11): 1096 doi: 10.1002/mame.v300.11
21. [21]
  Chang, J., Niu, H., He, M., Sun, M. and Wu, D., J. Appl. Polym. Sci., 2015, 132(34): 42474
22. [22]
  Vickers, M.E., Briggs, N.P., Ibbett, R.N., Payne, J.J. and Smith, S.B., Polymer, 2001, 42(19): 8241
23. [23]
  Dong, J., Yin, C., Zhang, Z., Wang, X., Li, H. and Zhang, Q., Macromol. Mater. Eng., 2014, 299(10): 1170 doi: 10.1002/mame.v299.10
24. [24]
  Yin, C., Dong, J., Zhang, D., Lin, J. and Zhang, Q., Eur. Polym. J., 2015, 67: 88 doi: 10.1016/j.eurpolymj.2015.03.028
25. [25]
  Yin, C., Dong, J., Zhang, Z., Zhang, Q. and Lin, J., J. Polym. Sci., Part B: Polym. Phys., 2015, 53(3): 183 doi: 10.1002/polb.v53.3
26. [26]
  26 Dong, J., Yin, C., Lin, J., Zhang, D. and Zhang, Q., RSC Adv., 2014, 4(84): 44666
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