Citation: Phetwarotai Worasak, Tanrattanakul Varaporn, Phusunti Neeranuch. Synergistic Effect of Nucleation and Compatibilization on the Polylactide and Poly(butylene adipate-co-terephthalate) Blend Films[J]. Chinese Journal of Polymer Science, ;2016, 34(9): 1129-1140. doi: 10.1007/s10118-016-1834-0 shu

Synergistic Effect of Nucleation and Compatibilization on the Polylactide and Poly(butylene adipate-co-terephthalate) Blend Films

a.
Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hatyai, Songkhla 90112, Thailand
b.
Bioplastic Research Unit, Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hatyai, Songkhla 90112, Thailand
c.
Department of Chemistry, Faculty of Science, Prince of Songkla University, Hatyai, Songkhla 90112, Thailand

Corresponding author: Phetwarotai Worasak, w.phetwarotai@hotmail.com;worasak.ph@psu.ac.th
Received Date: 13 March 2016
Revised Date: 19 April 2016
Accepted Date: 19 April 2016

Fund Project: the Prince of Songkla University No. SCI570376S

Polylactide (PLA) films blended with 10 wt% poly(butylene adipate-co-terephthalate) (PBAT) were prepared by using a twin screw extruder in the presence of the nucleating agent of titanium dioxide (TiO₂) and the compatibilizers of toluene diisocyanate (TDI) and PLA-grafted-maleic anhydride (PLA-g-MA). The synergistic effect of the nucleation and compatibilization on the properties and crystallization behavior of the PLA/PBAT (PLB) films was explored. The results showed that the addition of TiO₂ significantly enhanced the tensile strength and the impact tensile resistance of the PLB films while slightly decreased its thermal stability. In addition, the compatibilizers of TDI and PLA-g-MA in the system not only affected the crystallinity and cold crystallization process of the PLB films, but also increased the mechanical properties of them due to the improvement of the interfacial interaction between PLA and PBAT revealed by the morphological measurement. The synergistic effects of the nucleating agent and the compatibilizer afforded the blend films with increased tensile strength and impact tensile toughness, improved cold crystallization property and c_c.
- Nucleation,
- Film,
- Compatibilization,
- Blend,
- Crystallization
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