Citation: Liu Heng, Yang Shi-ze, Wang Feng, Bai Chen-xi, Hu Yan-ming, Zhang Xue-quan. Polymerization of 1,3-Butadiene Catalyzed by Cobalt(II)and Nickel(II) Complexes Bearing Pyridine-2-imidate Ligands[J]. Chinese Journal of Polymer Science, ;2016, 34(9): 1060-1069. doi: 10.1007/s10118-016-1825-1 shu

Polymerization of 1,3-Butadiene Catalyzed by Cobalt(II)and Nickel(II) Complexes Bearing Pyridine-2-imidate Ligands

a.
Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
Panjin Northern Asphalt Co., Ltd, Norinco Group, Panjin 124000, China

Corresponding author: Hu Yan-ming, ymhu@ciac.ac.cn Zhang Xue-quan, xqzhang@ciac.ac.cn
Received Date: 26 March 2016
Revised Date: 29 April 2016
Accepted Date: 29 April 2016

Fund Project: the 973 Program No. 2015CB654700 or 2015654702the National Natural Science Foundation of China Nos. 51473156 and 51203147

Cobalt and nickel complexes (1a-1d and 2a-2d, respectively) supported by 2-imidate-pyridine ligands were synthesized and used for 1,3-butadiene polymerization. The complexes were characterized by IR and element analysis, and complex 1a was further characterized by single-crystal X-ray diffraction. The solid state structure of complex 1a displayed a distorted tetrahedral geometry. Upon activation with ethylaluminum sesquichloride (EASC), all the complexes showed high activities toward 1,3-butadiene polymerization. The cobalt complexes produced polymers with high cis-1,4 contents and high molecular weights, while the nickel complexes displayed low cis-1,4 selectivity and the resulting polymers had low molecular weights. The catalytic activities of the complexes highly depended on the ligand structure. With the increment of polymerization temperature, the cis-1,4 content and the molecular weight of the resulting polymer decreased.
- 1,3-Butadiene,
- Late-transition metal,
- Cis-1,4-polybutadiene,
- Pyridine-2-imidate
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