Citation: Zhuo-ye Chai, Zhong Xie, Peng Zhang, Xiao Ouyang, Rui Li, Shan Gao, Hao Wei, Lian-he Liu, Zhi-jun Shuai. High Impact Resistance Epoxy Resins by Incorporation of Quadruply Hydrogen Bonded Supramolecular Polymers[J]. Chinese Journal of Polymer Science, ;2016, 34(7): 850-857. doi: 10.1007/s10118-016-1809-1 shu

High Impact Resistance Epoxy Resins by Incorporation of Quadruply Hydrogen Bonded Supramolecular Polymers

Zhuo-ye Chai ^a ,
Zhong Xie ^b,, ,
Peng Zhang ^b ,
Xiao Ouyang ^b ,
Rui Li ^b ,
Shan Gao ^b ,
Hao Wei ^a,b,, ,
Lian-he Liu ^b ,
Zhi-jun Shuai ^a

a.
College of Power and Energy Engineering, Harbin Engineering University, Harbin 150001, China
b.
Key Laboratory of Superlight Material and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China

Corresponding author: Zhong Xie, xiezhong1984@163.com Hao Wei, weihao7512@126.com
Received Date: 14 January 2016
Revised Date: 22 February 2016
Accepted Date: 22 February 2016

A bisphenol A based epoxy was incorporated with a quadruply hydrogen bonded supramolecular polymer as a toughening agent to prepare a composite epoxy resin with higher impact resistance. The supramolecular polymer comprising poly-(propylene glycol) bis(2-aminopropyl) ether chains and 2-ureido-4[1H]-pyrimidinone moieties (UPy) self-assembled into spherical domains with sizes of 300 nm to 600 nm in diameter by micro phase separation in bulk epoxy matrixes. A significant improvement of 300% in impact resistance of the supramolecular polymer incorporated epoxy resin was obtained when the content of supramolecular polymer was 10 wt%. Tensile tests showed that the mechanical properties of the modified epoxy resin containing the hydrogen-bonded supramolecular polymers are also improved compared with those of the neat epoxy resin.
- Supramolecular polymer,
- Epoxy resin,
- Hydrogen bond,
- Impact resistance
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