Citation: Di-zheng Liu, Wei-lin Sun, Rong Ren, Yan-hua Wang, Zhi-quan Shen. Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)[J]. Chinese Journal of Polymer Science, ;2016, 34(7): 910-918. doi: 10.1007/s10118-016-1804-6 shu

Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)

MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Zhi-quan Shen, opl_sunwl@zju.edu.cn
Received Date: 31 January 2016
Revised Date: 9 March 2016
Accepted Date: 14 March 2016

Fund Project: This work was financially supported by the National Natural Science Foundation of China 21174129

Homopolymer (PBIP) containing 2, 6-bis(1'-methylbenzimidazolyl)pyridine (MeBIP) ligands in the side chain was synthesized by RAFT polymerization and its kinetics was studied. Polymeric complex PBIP-Nd³⁺ was prepared by chelating PBIP with lanthanide ion Nd³⁺. The homopolymers and PBIP-Nd³⁺ complex were investigated by NMR, FTIR, GPC and TGA. The optical property of PBIP-Nd³⁺ complex was characterized by UV-Vis spectroscopy. The magnetic property of PBIP-Nd³⁺ complex was measured as a function of temperature (5 K to 300 K) and as a function of field (-3.98 × 10⁶ A/m to 3.98 × 10⁶ A/m). These results indicated that PBIP-Nd³⁺ complex is paramagnetic.
- 2, 6-Bis(1'-methylbenzimidazolyl)pyridine,
- Magnetic,
- RAFT,
- Polymeric complex,
- Neodymium
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd3+)

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)