Citation: Hua-feng Shao, Zhi-lu Li, Ai-hua He, Chen-guang Liu, Wei Yao. Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism[J]. Chinese Journal of Polymer Science, ;2016, 34(7): 797-804. doi: 10.1007/s10118-016-1797-1 shu

Fabrication of Trans-1,4-polyisoprene Nanofibers by Electrospinning and Its Crystallization Behavior and Mechanism

Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, China

Corresponding author: Ai-hua He, aihuahe@iccas.ac.cn;ahhe@qust.edu.cn
Received Date: 8 December 2015
Revised Date: 18 February 2016
Accepted Date: 23 February 2016

Trans-1,4-polyisoprene (TPI) nanofibers have been fabricated successfully through electrospinning technology. Through the control of electrospinning parameters, highly crystallized TPI fresh fibers composed mainly of b phase were produced. Morphology and diameter of TPI nanofibers can be controlled by adjusting the electrospinning conditions. The in situ observations of FTIR spectra revealed that the crystallinity of the TPI fibers decreased with aging. While for TPI nanofibers aging at 45 ℃ for 24 h, a decrease in crystallinity as well as b to a transformation was observed with aging and these changings happened in the first 50 h during aging. The mechanism for b-TPI formation during electrospinning process and the reduced crystallinity with aging were proposed.
- Electrospinning,
- Trans-1,4-polyisoprene,
- Crystallization,
- Transformation,
- b phase
1. [1]
  Mandelkern, L., Quinn, J.F. and Roberts, A.D., J. Am. Chem. Soc., 1956, 78: 926
2. [2]
  Ratri, P.J., Tashiro, K. and Iguchi, M., Polymer, 2012, 53: 3548
3. [3]
  Ratri, P.J. and Tashiro, K., Polym. J., 2013, 45: 1107
4. [4]
  Fischer, E. and Henderson, J.F., J. Polym. Sci. A, 1967, 5: 377
5. [5]
  Takahashi, Y., Sato, T. and Tadokoro, H., J. Polym. Sci. Polym. Phys. Ed., 1973, 11: 233
6. [6]
  Lovering, E.G. and Wooden, D.C., J. Polym. Sci., Part A: Polym. Chem., 1969, 7: 1639
7. [7]
  Boochathum, P., Tanaka, Y. and Okuyama, K., Polymer, 1993, 34: 3694
8. [8]
  Nikitin, V.N. and Volchek, B.Z., Zhurnal Prikladnoi Spektroskopii, 1966, 4: 546
9. [9]
  Weng, G.S., Wu, J.R. and Xu, Y.C., J. Polym. Res., 2014, 21: 576
10. [10]
  Weng, G.S., Bao, J.B., Xu, Y.C. and Chen, Z.R., J. Polym. Res., 2013, 20: 1
11. [11]
  Fisher, D., Proc. Roy. Soc. London Set A, 1953, 66: 7
12. [12]
  Bunn, C.W., Proc. Roy. Soc. London Set A, 1942, 180: 40
13. [13]
  Keller, A. and Martuscelli, E., Makromol. Chem. Phys., 1972, 151: 189
14. [14]
  Anandakumaran, K., Herman, W. and Woodward, A.E., Macromolecules, 1983, 16: 563
15. [15]
  Anandakumaran, K., Kuo, C.C., Mukherji, S. and Woodward, A.E., J. Polym. Sci., Part B: Polym. Phys., 1982, 20: 1669
16. [16]
  Flanagan, R.D. and Rijke, A.M., J. Polym. Sci., Part B: Polym. Phys., 1972, 10: 1207
17. [17]
  Kuo, C. and Woodward, A.E., Macromolecules, 1984, 17: 1034
18. [18]
  Leeper, H.M. and Schlesinger, W., J. Polym. Sci., 1953, 11: 307
19. [19]
  Xu, J.R. and Woodward, A.E., Macromolecules, 1986, 19: 1114
20. [20]
  Balta, C.F. and Vonk, C.G., “X-ray scattering of synthetic polymers”, Elsevier, Amsterdam, Holland, 1989, p.175
21. [21]
  Ali, A., Mohamed, M.N., Matsuura, T. and Reza, F., Chinese J. Polym. Sci., 2014, 32(6): 793
22. [22]
  Gavish, M., Corrigan, J. and Woodward, A.E., Macromolecules, 1988, 21: 2079
23. [23]
  Cao, Y.L., Hao, F.L., Li, J.Y. and Han, S.H., China Elastomer, 1993, 3: 34
24. [24]
  Su, F.M., Li, X.Y., Zhou, W.M. and Chen, W., Polymer, 2013, 54: 3408
25. [25]
  Sun, X.H. and Ni, X.Y., J. Appl. Polym. Sci., 2004, 94: 2286
26. [26]
  Cao, L., Su, D.F., Su, Z.Q. and Chen, X.N., Chinese J. Polym. Sci., 2014, 32(9): 1167
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