Citation: Wang Jian, Zhong Li, Yuan Yan, Xiao Wang, Yun-chuan Xie, Zhi-cheng Zhang. Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures[J]. Chinese Journal of Polymer Science, ;2016, 34(5): 649-658. doi: 10.1007/s10118-016-1782-8 shu

Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures

Wang Jian ^a ,
Zhong Li ^a,b ,
Yuan Yan ^c ,
Xiao Wang ^a ,
Yun-chuan Xie ^a,, ,
Zhi-cheng Zhang ^a,,

a.
Department of Applied Chemistry, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Science, Xi'an Jiaotong University, Xi'an 710049, China
b.
College of Material Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
c.
School of Electronic and Information Engineering, Xi'an Jiaotong University, Xi'an 710049, China

Corresponding author: Yun-chuan Xie, ycxie@mail.xjtu.edu.cn Zhi-cheng Zhang, zhichengzhang@mail.xjtu.edu.cn
Received Date: 27 November 2015
Revised Date: 4 January 2016
Accepted Date: 4 January 2016

Fund Project: Fundamental Research Funds for the Central Universities XJJ2013075Natural Science Basic Research Plan in Shaanxi Province of China 2015JZ009Fundamental Research Funds for the Central Universities cxtd2015003the National Natural Science Foundation of China 51573146the National Natural Science Foundation of China 51103115the National Natural Science Foundation of China 50903065International Science & Technology Cooperation Program of China 2013DFR50470National Basic Research Program of China 973 6132620101Natural Science Basic Research Plan in Shaanxi Province of China 2013JZ003

After annealing the solution cast P(VDF-TrFE) films at elevated temperatures, which were synthesized via a full hydrogenation process from P(VDF-CTFE) with a composition of VDF/TrFE=80/20 (mol%), a series of P(VDF-TrFE) films were fabricated in present work. The crystalline and ferroelectric phases of the films were carefully characterized and their dielectric, ferroelectric and piezoelectric properties were systematically investigated. The improved crystalline and ferroelectric phases in the films induced by annealing at elevated temperatures are responsible for the significant improved electric properties of the films. The optimized annealing temperature is found to be 130 ℃ and the best performance including the highest dielectric constant of 12.5 at 1 kHz, the largest maximum polarization of 11.21 μC/cm² and remnant polarization of 7.22 μC/cm², the lowest coercive electric field of 56 MV/m, and the highest piezoelectric coefficient of-25 pC/N is observed.
- P(VDF-TrFE),
- P(VDF-CTFE),
- Hydrogenation,
- Annealing,
- Electrical properties
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