Citation: Hong-mei Zhang, Shu-hua Zhang, Polite Stewart, Chen-hui Zhu, Wei-jun Liu, Alexander Hexemer, Eric Schaible, Cheng Wang. Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites[J]. Chinese Journal of Polymer Science, ;2016, 34(5): 542-551. doi: 10.1007/s10118-016-1778-4 shu

Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites

a.
College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
b.
Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley 94720, USA
c.
College of Mechanical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

Corresponding author: Shu-hua Zhang, zhangsh@sues.edu.cn Cheng Wang, cwang2@lbl.gov
Received Date: 28 October 2015
Revised Date: 30 November 2015
Accepted Date: 27 December 2015

Fund Project: This work was financially supported by the Shanghai Municipal Education Commission with “Twelfth Five” scientific connotation construction project nhky-2012-05foreign visiting scholar fellowship program B-8938-12-0406

MgAl-LDH (layered double hydroxides) were prepared with CO(NH₂)₂, NH₄Cl and NH₃·H₂O by the co-precipitation method, respectively. Corresponding composite membranes were prepared by the coating method. LDHs were characterized by WAXS, CO₂-TPD and SEM. The morphology of the PVC/LDHs composite membranes were characterized by means of SEM. The thermal stability of the membranes was analyzed by air aging box and TGA-FTIR. The SEM results show that nano-particles can be compatible with poly(vinyl chloride) (PVC) matrix homogeneously by the stirring-ultrasound blend method with two steps. Furthermore, the air aging box results proved that MgAl-CO(NH₂)₂-LDH has the best effect on thermal stability of PVC. TGA-FTIR results show that MgAl-CO(NH₂)₂-LDH could adsorb more HCl that resulted from the degradation of PVC and improve the pyrolysis temperature of the first degradation stage by 15 K compared with PVC.
- Poly(vinyl chloride),
- Layered double hydroxide,
- Thermal stability,
- TGA-FTIR
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1.
沈阳化工大学材料科学与工程学院沈阳 110142