Citation: Jing-jing Shen, Dong-ge Zhang, Xing Liu, Yu-chang Tang, Yu Lin, Guo-zhang Wu. Facile Fabrication of High-performance Polyimide Nanocomposites with in situ Formed “Impurity-free” Dispersants[J]. Chinese Journal of Polymer Science, ;2016, 34(5): 532-541. doi: 10.1007/s10118-016-1771-y shu

Facile Fabrication of High-performance Polyimide Nanocomposites with in situ Formed “Impurity-free” Dispersants

Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: Yu Lin, linyu@ecust.edu.cn Guo-zhang Wu, wgz@ecust.edu.cn
Received Date: 28 October 2015
Revised Date: 19 December 2015
Accepted Date: 22 December 2015

Fund Project: This work was financially supported by the National Basic Research Program of China 2013CB035505Shanghai Sailing Program 14YF1404900China Postdoctoral Science Foundation 2015M571502the National Natural Science Foundation of China 51503066

Polyimide/carbon black (PI/CB) nanocomposite films were fabricated via the direct ball-milling method with poly(amic acid) (PAA), the precursor of PI, as an in situ formed impurity-free dispersant. FTIR and Raman spectral results reveal that, besides physical adsorption, chemical grafting of PAA chains onto the CB surface occurs during the ball-milling process. Comparative studies show that introduction of various commercial dispersants improves the dispersion of CB. However, the mixtures exhibit poor reproducibility, unstable electrical properties, and decreased tensile strength; these issues may be attributed to interfacial pollution brought about by differences in the chemical structures of the dispersant and the matrix. The impurity-free dispersant is effective not only in ensuring the uniform dispersion of CB particles but also in enhancing filler-matrix interfacial adhesion. High-molecular weight PAA chains are effective reagents for impurity-free modification and can therefore be used to improve the electrical and mechanical properties of the resultant composite.
- Nanocomposites,
- Impurity-free,
- Polyimide,
- Electrical resistivity,
- Mechanical properties
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