Citation: Xiu-bo Jiang, Qing-fei Zhang, Ai-hua He. Synthesis and Characterization of Trans-1,4-butadiene/Isoprene Copolymers: Determination of Sequence Distribution and Thermal Properties[J]. Chinese Journal of Polymer Science, ;2015, 33(6): 815-822. doi: 10.1007/s10118-015-1626-y shu

Synthesis and Characterization of Trans-1,4-butadiene/Isoprene Copolymers: Determination of Sequence Distribution and Thermal Properties

1.
Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-Plastics, School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

Received Date: 17 September 2014
Revised Date: 16 October 2014

Fund Project: This work was financially supported by the National Basic Research Program of China (No. 2015CB654700 (2015CB654706)), Shandong Province Natural Science Fund for Distinguished Young Scholars (No. JQ201213) and the National Natural Science Foundation of China (No. 51473083).

Two series of trans-1,4-poly(butadiene-co-isoprene) copolymers (TBIR) were prepared using the catalyst system TiCl4/MgTCl2-Al(i-Bu)3 at different reaction temperatures. All dyad and triads sequence distributions, the number-average sequence length and the sequence concentration of the copolymers were calculated according to 13C-NMR spectra. The influences of temperature and initial molar ratio of butadiene to isoprene (Bd to Ip) on the distribution of the chain segments in the TBIR copolymers were discussed. The correlation of copolymer compositions and thermal properties were also evaluated, which facilitated the understanding of controlling the degree of crystallinity and the transition temperature by changing Bd content and temperature.
- Trans-1,4-,
- Isoprene,
- Butadiene,
- Copolymer,
- Thermal properties
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
1. [1]
  Wendi Dou , Guangying Wan , Tiefeng Liu , Lin Han , Wu Zhang , Chuang Sun , Rensheng Song , Jianhui Zheng , Yujing Liu , Xinyong Tao . Conductive composite binder for recyclable LiFePO₄ cathode. Chinese Chemical Letters, 2024, 35(11): 109389-. doi: 10.1016/j.cclet.2023.109389
2. [2]
  Zihe SONG , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Crystal structure, thermal analysis, and luminescence properties of six heterocyclic lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 181-192. doi: 10.11862/CJIC.20250126
3. [3]
  Yiwen Lin , Yijie Chen , Chunhui Deng , Nianrong Sun . Integration of resol/block-copolymer carbonization and machine learning: A convenient approach for precise monitoring of glycan-associated disorders. Chinese Chemical Letters, 2024, 35(12): 109813-. doi: 10.1016/j.cclet.2024.109813
4. [4]
  Changlin Su , Wensheng Cai , Xueguang Shao . Water as a probe for the temperature-induced self-assembly transition of an amphiphilic copolymer. Chinese Chemical Letters, 2025, 36(4): 110095-. doi: 10.1016/j.cclet.2024.110095
5. [5]
  Qian Wang , Ting Gao , Xiwen Lu , Hangchao Wang , Minggui Xu , Longtao Ren , Zheng Chang , Wen Liu . Nanophase separated, grafted alternate copolymer styrene-maleic anhydride as an efficient room temperature solid state lithium ion conductor. Chinese Chemical Letters, 2024, 35(7): 108887-. doi: 10.1016/j.cclet.2023.108887
6. [6]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
7. [7]
  Yifan Liu , Jiazuo Zhou , Ziyao Wang , Lei Qiao , Yudong Li , Yuan Yu , Cong Li , Jinliang Zhu , Yuehe Gu , Xiaohan Sun , Haiyue Yang , Chengyu Wang . Hydrated salt hydrogel with switchable stiffness and tunable thermal performance for environmental low-grade thermal management. Chinese Chemical Letters, 2026, 37(7): 112196-. doi: 10.1016/j.cclet.2025.112196
8. [8]
  Jinrui Qian , Yue Sun , Feixiang Long , Yiqing Liu , Guozhen Chang , Yuzhu Song , Naike Shi , Andrea Sanson , Xiuzhu Han , Chang Zhou , Jun Chen . Significantly improving the performances of thermal conductivity and thermal expansion in aluminum matrix composites through a multiphase design strategy. Chinese Chemical Letters, 2026, 37(7): 111849-. doi: 10.1016/j.cclet.2025.111849
9. [9]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
10. [10]
  Yunxi Shi , Dongjie Cheng , Yi Liu , Xinyi Huang , Pan Wang , Zhenguo Li , Jizhou Jiang . Non-thermal plasma synergistic regeneration for Pt catalyst performance reconstruction. Chinese Chemical Letters, 2026, 37(8): 112246-. doi: 10.1016/j.cclet.2025.112246
11. [11]
  Qianwei Liu , Xinhong Xiong , Numan Ahmed , Peisong Tang , Jiaxi Cui . Crystal hydrogels: Strategies, properties, and applications. Chinese Chemical Letters, 2026, 37(5): 111707-. doi: 10.1016/j.cclet.2025.111707
12. [12]
  Xiaoyu Chen , Jiahao Hu , Jingyi Lin , Haiyang Huang , Changqing Ye , Hongli Bao . Biisoindolylidene solvatochromic fluorophores: Synthesis and photophysical properties. Chinese Chemical Letters, 2025, 36(2): 109923-. doi: 10.1016/j.cclet.2024.109923
13. [13]
  Bowen Song , Chenxu Shi , Yinghao Qu , Hongjun Liu , Hui Yang , Xiaoming Wu , Xijun Liu . The electrical properties and charge transport mechanism of MXenes. Chinese Chemical Letters, 2025, 36(6): 110823-. doi: 10.1016/j.cclet.2025.110823
14. [14]
  Ruizhi Yang , Xia Li , Weiping Guo , Zixuan Chen , Hongwei Ming , Zhong-Zhen Luo , Zhigang Zou . New thermoelectric semiconductors Pb5Sb12+xBi6-xSe32 with ultralow thermal conductivity. Chinese Journal of Structural Chemistry, 2024, 43(3): 100268-100268. doi: 10.1016/j.cjsc.2024.100268
15. [15]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
16. [16]
  Zhiqing Ge , Zuxiong Pan , Shuo Yan , Baoying Zhang , Xiangyu Shen , Mozhen Wang , Xuewu Ge . Novel high-temperature thermochromic polydiacetylene material and its application as thermal indicator. Chinese Chemical Letters, 2024, 35(11): 109850-. doi: 10.1016/j.cclet.2024.109850
17. [17]
  Guizhi Zhu , Junrui Tan , Longfei Tan , Qiong Wu , Xiangling Ren , Changhui Fu , Zhihui Chen , Xianwei Meng . Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber. Chinese Chemical Letters, 2025, 36(1): 109669-. doi: 10.1016/j.cclet.2024.109669
18. [18]
  Shuai Liang , Wen-Jing Jiang , Ji-Xiang Hu . Achieving colossal anisotropic thermal expansion via synergism of spin crossover and rhombus deformation. Chinese Journal of Structural Chemistry, 2025, 44(2): 100430-100430. doi: 10.1016/j.cjsc.2024.100430
19. [19]
  Shi Li , Wenshuai Zhao , Yong Qi , Wenbin Niu , Wei Ma , Bingtao Tang , Shufen Zhang . Hydrogen bonding induced ultra-highly thermal stability of azo dyes for color films. Chinese Chemical Letters, 2025, 36(9): 110653-. doi: 10.1016/j.cclet.2024.110653
20. [20]
  Jaeheon Lee , Jung Hyeun Kim . Effect of thermal annealing on cold crystallization ability of thermoset polyurethane elastomer synthesized from fully bio-derived polyol. Chinese Journal of Structural Chemistry, 2025, 44(5): 100568-100568. doi: 10.1016/j.cjsc.2025.100568

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(2016)
HTML views(55)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return