Citation: Mohsen Hajibeygi, Meisam Shabanian. Organosoluble Aliphatic-Aromatic Poly(ether-amide)s Based on Pyridine Moiety in the Main Chain：Synthesis, Characterization and Thermal Studies[J]. Chinese Journal of Polymer Science, ;2014, 32(6): 758-767. doi: 10.1007/s10118-014-1449-2 shu

Organosoluble Aliphatic-Aromatic Poly(ether-amide)s Based on Pyridine Moiety in the Main Chain：Synthesis, Characterization and Thermal Studies

Mohsen Hajibeygi ^1,, ,
Meisam Shabanian ²

1.
Young Researchers Club, Varamin Pishva Branch, Islamic Azad University, Varamin, Iran
2.
Department of Chemistry, Farahan Branch, Islamic azad University, Farahan, Iran

Corresponding author: Mohsen Hajibeygi, mhajibeygi@gmail.com
Received Date: 9 September 2013
Revised Date: 20 December 2013

A series organosoluble and heterocyclic poly(ether-amide)s (PEA)s were synthesized from a new diamine containing pyridine moiety and four aliphatic-aromatic dicarboxylic acids by direct polycondensation reactions. Dicarboxilic acids 4a-4d containing ether groups were synthesized in two steps reactions. At first, dialdehydes 3a-3d were synthesized from four dibromo alkanes 1a-1d and 4-hydroxybenzaldehyde 2, then dicarboxilic acids 4a-4d were synthesized from dialdehydes 3a-3d and malonic acid in a solvent free reaction. On the other hand, the new diamine 8 containing pyridine ring was synthesized in two step reactions. The structures of synthesized monomers and polymers were provn by FTIR, NMR spectroscopy and elemental analysis. Also all of the above polymers were fully characterized by inherent viscosity, solubility tests, gel permeation chromatography (GPC), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The resulted PEAs have shown good inherent viscosities, solubility and thermal properties.
- Poly(ether-amide),
- Organosoluble,
- Aliphatic-aromatic,
- Polycondensation,
- Malonic acid
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