Citation: S. Rafiei, B. Noroozi, Sh. Arbab, A.K. Haghi. Characteristic Assessment of Stabilized Polyacrylonitrile Nanowebs for the Production of Activated Carbon Nano-Sorbents[J]. Chinese Journal of Polymer Science, ;2014, 32(4): 449-457. doi: 10.1007/s10118-014-1410-4 shu

Characteristic Assessment of Stabilized Polyacrylonitrile Nanowebs for the Production of Activated Carbon Nano-Sorbents

S. Rafiei ¹ ,
B. Noroozi ^1,, ,
Sh. Arbab ¹ ,
A.K. Haghi ¹

1.
Department of Textile Engineering, University of Guilan, P.O. Box 41635-3756, Rasht, Iran

Corresponding author: B. Noroozi,
Received Date: 4 July 2013
Revised Date: 2 September 2013

Polyacrylonitrile (PAN) nanofibers with average diameter of 300 nm were produced by electro-spinning. The nanofibers were stabilized at different temperatures in the range of 180-270 ℃ in several duration times and heating rates. Fourier transforms infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analyzing techniques were employed to measure the extent of stabilization reaction. By all procedures, the ranges of temperature and duration time recommended were about 250-270 ℃ and 1-2 h, respectively. Increasing the activation temperature from 800 ℃ to 1200 ℃ caused porosity and pore volume development up to 60% and 0.532 cm3/g, respectively. Pore width of all samples was calculated to be about 0.7 nm confirming micro-pore structure of the produced PAN based activated carbon nanofibers. Comparing dye adsorption for different adsorbents including chitin and granular activated carbon (GAC) showed the highest efficiency for the produced activated carbon nanofibers (ACNFs).
- Polyacrylonitrile,
- Electro-spinning,
- Stabilization,
- Activated carbon nanofibers,
- Adsorbent
1. [1]
1. [1]
  Xiaojuan Sun , Ke Kong , Jun Liang , Dan Wang , Beibei Dong , Ruihu Wang . Periodic Janus structure based on ionic covalent organic framework for selective removal of perfluoroalkyl substances. Chinese Journal of Structural Chemistry, 2025, 44(9): 100652-100652. doi: 10.1016/j.cjsc.2025.100652
2. [2]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
3. [3]
  Rui Wang , Yang Liang , Julius Rebek Jr. , Yang Yu . Stabilization and detection of labile reaction intermediates in supramolecular containers. Chinese Chemical Letters, 2024, 35(6): 109228-. doi: 10.1016/j.cclet.2023.109228
4. [4]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
5. [5]
  Wenfeng Shao , Chuanlin Li , Chenggang Wang , Guangsen Du , Shunshun Zhao , Guangmeng Qu , Yupeng Xing , Tianshuo Guo , Hongfei Li , Xijin Xu . Stabilization of zinc anode by trace organic corrosion inhibitors for long lifespan. Chinese Chemical Letters, 2025, 36(3): 109531-. doi: 10.1016/j.cclet.2024.109531
6. [6]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
7. [7]
  Hui Li , Yanxing Qi , Jia Chen , Juanjuan Wang , Min Yang , Hongdeng Qiu . Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄. Chinese Chemical Letters, 2024, 35(11): 109659-. doi: 10.1016/j.cclet.2024.109659
8. [8]
  Xingqun Pu , Rongrong Liu , Yuting Xie , Chenjing Yang , Jingyi Chen , Baoling Guo , Chun-Xia Zhao , Peng Zhao , Jian Ruan , Fangfu Ye , David A Weitz , Dong Chen . One-step preparation of biocompatible amphiphilic dimer nanoparticles with tunable particle morphology and surface property for interface stabilization and drug delivery. Chinese Chemical Letters, 2025, 36(3): 109820-. doi: 10.1016/j.cclet.2024.109820
9. [9]
  Wenhui Tu , Yuanpeng Cao , Xianshu Wang , Bo Liao , Xiaoyu Ding , Junru Wu , Xiangshao Yin , Zhuo Zhou , Yuanyuan Huang , Runlin Li , Xinyu Zhang , Chao Zhao , Peng Dong , Yingjie Zhang , Ding Wang , Xuerui Yang , Jianguo Duan . Multifunctional silane additive realizing electrolyte stabilization and hierarchic interface formation for LiMn_0.60Fe_0.40PO₄ cathode materials. Chinese Chemical Letters, 2026, 37(10): 111594-. doi: 10.1016/j.cclet.2025.111594
10. [10]
  Hao Liu , Qiang Xu , Yun Zhang , Na Han , Haihui Liu , Xingxiang Zhang . Multifunctional heterostructure CoS₂/FeS₂ catalysts for enhancing high-performance lithium–sulfurized polyacrylonitrile batteries through intrinsic electric fields. Chinese Chemical Letters, 2026, 37(8): 111084-. doi: 10.1016/j.cclet.2025.111084
11. [11]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
12. [12]
  Man Zhao , Liwu Qiang , Zonghang Liu , Wei Wen , Ze Wang , Qilin Guo , Yanxia Zhang , Aiqin Hao , Yuhong Chang , Junming Zhang , Baoliang Lv , Xiaofang Ma , He Xiao , Jianfeng Jia . Programming selective formation of epoxy bond: Carbon dots as multifunctional mediators for steering propylene electro oxidation pathways on Ag-graphene hybrids. Chinese Chemical Letters, 2026, 37(10): 112843-. doi: 10.1016/j.cclet.2026.112843
13. [13]
  Qianqing Xu , Qu Jiang , Haoyue Zhang , Fang Song . Deciphering the active species of anodically activated carbon-based electrocatalysts for oxygen evolution reaction. Chinese Chemical Letters, 2025, 36(11): 111417-. doi: 10.1016/j.cclet.2025.111417
14. [14]
  Sijia Zhang , Guangyu Bi , Wen-Qiang Li , Yang Wang , Xian-Yang Shi . Activated energy transfer pathway in carbon nitride nanosheets promotes molecular oxygen activation for robust and efficient water decontamination. Chinese Chemical Letters, 2026, 37(4): 111463-. doi: 10.1016/j.cclet.2025.111463
15. [15]
  Yue Liu , Linhong Wen , Mengyan Wang , Jianxiao Yang , Xin Zhang . Plasma-engineered activated carbon fibers for boosting sulfate selectivity and regeneration performance in room-temperature malodorous H₂S catalytic oxidation. Chinese Chemical Letters, 2026, 37(7): 112153-. doi: 10.1016/j.cclet.2025.112153
16. [16]
  Xinyu Zeng , Zhuofan Zeng , Qingqing Hu , Kejun Liu , Lei Ming , Bei Cheng , Wang Wang , Guoqiang Luo , Shaowen Cao . Hierarchical Pt/NiO hollow nanofibers for catalytic oxidation of HCHO at room temperature. Chinese Journal of Structural Chemistry, 2025, 44(6): 100575-100575. doi: 10.1016/j.cjsc.2025.100575
17. [17]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
18. [18]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
19. [19]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176
20. [20]
  Li Li , Zhi-Xin Yan , Chuan-Kun Ran , Yi Liu , Shuo Zhang , Tian-Yu Gao , Long-Fei Dai , Li-Li Liao , Jian-Heng Ye , Da-Gang Yu . Electro-reductive carboxylation of CCl bonds in unactivated alkyl chlorides and polyvinyl chloride with CO₂. Chinese Chemical Letters, 2024, 35(12): 110104-. doi: 10.1016/j.cclet.2024.110104

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(2422)
HTML views(237)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return